Exhaust gas purification catalyst body
Provided is an exhaust gas purification catalyst body that can improve exhaust gas purification performance while maintaining favorable PM collection performance. The exhaust gas purification catalyst body includes a base of a wall flow structure having an inlet side cell, an outlet side cell, and porous partition wall, and a catalyst layer that is formed in the partition wall that is in contact with the inlet side cell or the outlet side cell. The catalyst layer is formed in a region of at least 50% of the thickness of the partition wall from a surface of the partition wall, and held on the surface of internal pores in the partition wall in the region.
1. An exhaust gas purification catalyst body which is disposed in an exhaust passage of an internal combustion engine and purifies exhaust gas discharged from the internal combustion engine, comprising:
a base of a wall flow structure having an inlet side cell in which an end on the exhaust gas inflow side is open, an outlet side cell which is adjacent to the inlet side cell and in which an end on the exhaust gas outflow side is open, and a porous partition wall that partitions the inlet side cell and the outlet side cell; and
a catalyst layer that is formed in the partition wall, wherein
the catalyst layer is formed in a region of at least 50% of the thickness of the partition wall from a surface of the partition wall that faces at least one cell of the inlet side cell and the outlet side cell, and held on the surface of internal pores in the partition wall in the region, and,
among internal pores in the partition wall, an average filling rate A of the catalyst layer held in pores having a pore diameter of 5 μm or more and less than 10 μm, an average filling rate B of the catalyst layer held in pores having a pore diameter of 10 μm or more and less than 20 μm, and an average filling rate C of the catalyst layer held in pores having a pore diameter of 20 μm or more satisfy the following relationships:
A <B<C;
A ≤40%;
B ≤40%,
and among pores having a pore diameter of 5 μm or more and less than 20 μm, a proportion of pores having a catalyst layer filling rate of 75% or more is 35% or less by number.
2. The exhaust gas purification catalyst body according to claim 1 , wherein the average filling rate C of the catalyst layer held in the pores having a pore diameter of 20 μm or more is C ≤45%.
3. The exhaust gas purification catalyst body according to claim 1 , wherein the average filling rate B of the catalyst layer held in the pores having a pore diameter of 10 μm or more and less than 20 μm is 3% or more larger than the average filling rate A of the catalyst layer held in pores having a pore diameter of 5 μm or more and less than 10 μm.
4. The exhaust gas purification catalyst body according to claim 1 , wherein the average filling rate C of the catalyst layer held in pores having a pore diameter of 20 μm or more is 1% or more larger than the average filling rate B of the catalyst layer held in pores having a pore diameter of 10 μm or more and less than 20 μm.
5. The exhaust gas purification catalyst body according to claim 1 , wherein the average filling rate A is 10%≤A ≤35%, the average filling rate B is 15%≤B ≤40%, and the average filling rate C is 20%≤C ≤45%.
6. The exhaust gas purification catalyst body according to claim 1 , wherein a sum of volumes of pores having a diameter of 10 μm or less measured in the base including the catalyst layer using a mercury injection method is larger than a sum of volumes of pores having a diameter of 10 μm or less measured in the base only (without a catalyst layer) using a mercury injection method.
7. The exhaust gas purification catalyst body according to claim 1 , wherein the internal combustion engine is a gasoline engine.