Polylactic acid-containing aqueous dispersion
Provided is a polylactic-acid-containing aqueous dispersion capable of forming a transparent film at room temperature. A polylactic-acid-containing aqueous dispersion contains (1) polylactic acid; (2) at least one plasticizer selected from the group consisting of dimethyl adipate, diethyl adipate, dipropyl adipate, diisopropyl adipate, dibutyl adipate, diallyl adipate, bis(2-butoxyethyl) adipate, bis(2-methoxyethyl) adipate, dimethyl succinate, dimethyl glutarate, diethyl sebacate, diisopropyl sebacate, and mixtures thereof; (3) at least one dispersion stabilizer selected from the group consisting of cationic polymers, anionic polymers, polyvinyl alcohols, and non-ionic surfactants; and (4) water.
1. A cosmetic material comprising a polylactic-acid-containing aqueous dispersion comprising
(1) a polylactic acid,
(2) at least one plasticizer selected from the group consisting of dimethyl adipate, diethyl adipate, dipropyl adipate, diisopropyl adipate, dibutyl adipate, diallyl adipate, bis(2-butoxyethyl) adipate, bis(2-methoxyethyl) adipate, dimethyl succinate, dimethyl glutarate, diethyl sebacate, diisopropyl sebacate, and mixtures thereof,
(3) at least one dispersion stabilizer that is a cationic polymer comprising at least one monomer selected from the group consisting of acrylamide, dimethylaminoethyl methacrylate, a neutralized product of acrylamide, a neutralized product of dimethylaminoethyl methacrylate, a quaternary salt of acrylamide, and a quaternary salt of dimethylaminoethyl methacrylate, and
(4) water,
wherein
the polylactic-acid-containing aqueous dispersion comprises the polylactic acid in a range of 30 to 70 wt %,
the polylactic-acid-containing aqueous dispersion has a viscosity in a range of 150 mPa·s or more and 400 mPa·s or less, and
the cosmetic material forms a transparent film at room temperature within three minutes.
2. The cosmetic material according to claim 1 , wherein the polylactic acid satisfies at least one of the following physical properties (A) to (D):
(A) 80 to 100 mol % of the total monomer molecules forming the polylactic acid are a lactic acid monomer;
(B) the molar ratio of L-lactic acid to D-lactic acid that form the polylactic acid (L-lactic acid/D-lactic acid) is in the range of 1:1 to 7:1;
(C) when 0.1 g of the polylactic acid is dissolved in 25 mL of a mixture of phenol/tetrachloroethane in a mass ratio of 6/4, and a reduced viscosity is measured at 30° C., the reduced viscosity is 0.3 to 1.5 dl/g; and
(D) the number average molecular weight is 10,000 to 90,000.
3. The cosmetic material according to claim 2 , wherein the polylactic-acid-containing aqueous dispersion comprises the at least one plasticizer in an amount of 3 to 40 parts by weight per 100 parts by weight of the polylactic acid.
4. The cosmetic material according to claim 2 , wherein the polylactic acid satisfies the physical property (A).
5. The cosmetic material according to claim 2 , wherein the polylactic acid satisfies the physical property (B).
6. The cosmetic material according to claim 2 , wherein the polylactic acid satisfies the physical property (C).
7. The cosmetic material according to claim 2 , wherein the polylactic acid satisfies the physical property (D).
8. The cosmetic material according to claim 2 , wherein the polylactic acid satisfies the physical properties (A) and (B).
9. The cosmetic material according to claim 2 , wherein the polylactic acid satisfies the physical properties (A) and (C).
10. The cosmetic material according to claim 2 , wherein the polylactic acid satisfies the physical properties (A) and (D).
11. The cosmetic material according to claim 2 , wherein the polylactic acid satisfies the physical properties (A), (B), and (C).
12. The cosmetic material according to claim 2 , wherein the polylactic acid satisfies the physical properties (A), (B), and (D).
13. The cosmetic material according to claim 2 , wherein the polylactic acid satisfies the physical properties (A), (B), (C), and (D).
14. The cosmetic material according to claim 13 , wherein the polylactic-acid-containing aqueous dispersion comprises the at least one plasticizer in an amount of 3 to 40 parts by weight per 100 parts by weight of the polylactic acid.
15. The cosmetic material according to claim 14 , wherein the at least one plasticizer is selected from the group consisting of diethyl adipate, dipropyl adipate, diisopropyl adipate, diallyl adipate, bis(2-butoxyethyl) adipate, bis(2-methoxyethyl) adipate, dimethyl succinate, dimethyl glutarate, diethyl sebacate, diisopropyl sebacate, and mixtures thereof.
16. The cosmetic material according to claim 2 , wherein the polylactic acid satisfies the physical property (D), wherein the number average molecular weight is 10,000 to 70,000.
17. The cosmetic material according to claim 1 , wherein the polylactic-acid-containing aqueous dispersion comprises the at least one plasticizer in an amount of 3 to 40 parts by weight per 100 parts by weight of the polylactic acid.
18. The cosmetic material according to claim 1 , wherein the at least one plasticizer is selected from the group consisting of diethyl adipate, dipropyl adipate, diisopropyl adipate, diallyl adipate, bis(2-butoxyethyl) adipate, bis(2-methoxyethyl) adipate, dimethyl succinate, dimethyl glutarate, diethyl sebacate, diisopropyl sebacate, and mixtures thereof.
19. The cosmetic material according to claim 1 , wherein the polylactic acid is in the form of particles with a mean particle size of less than 1.0 μm.