Nonaqueous electrolyte secondary battery
View Patent ↗This nonaqueous electrolyte secondary battery is provided with a positive electrode, a negative electrode and a non-aqueous electrolyte. The non-aqueous electrolyte contains: a non-aqueous solvent that contains a fluorine-containing cyclic carbonate; an isocyanuric acid derivative such as triallyl isocyanurate; and a cyclic carboxylic acid anhydride such as diglycolic acid anhydride.
1. A non-aqueous electrolyte secondary battery comprising:
a positive electrode including a positive electrode active material that comprises a Ni-containing lithium composite oxide as a main component;
a negative electrode; and
a non-aqueous electrolyte;
wherein the non-aqueous electrolyte includes:
a non-aqueous solvent including a fluorine-containing cyclic carbonate;
an isocyanuric acid derivative represented by the formula below:
wherein R 1 to R 3 are each independently —C n H 2n —CH═CH 2 or hydrogen, provided that at least one of R 1 to R 3 is —C n H 2n —CH═CH 2 ; and n is an integer; and
a cyclic carboxylic anhydride represented by the formula below:
wherein R 4 to R 7 are each independently hydrogen, an alkyl group, an alkene group, or an aryl group.
2. The non-aqueous electrolyte secondary battery according to claim 1 , wherein the content of the fluorine-containing cyclic carbonate is 0.1 vol % or more and 30 vol % or less based on the total volume of the non-aqueous solvent.
3. The non-aqueous electrolyte secondary battery according to claim 1 , wherein the content of the cyclic carboxylic anhydride is 0.1 mass % or more and 1.5 mass % or less based on the total mass of the non-aqueous electrolyte.
4. The non-aqueous electrolyte secondary battery according to claim 1 , wherein the content of the isocyanuric acid derivative is 0.1 mass % or more and 1.5 mass % or less based on the total mass of the non-aqueous electrolyte.
5. The non-aqueous electrolyte secondary battery according to claim 1 , wherein the cyclic carboxylic anhydride includes diglycolic anhydride.
6. The non-aqueous electrolyte secondary battery according to claim 1 , wherein the isocyanuric acid derivative includes triallyl isocyanurate.