Catalyst and use of same
A catalyst comprising: a titanium oxide having an anatase-type crystal structure, and having the vertices and the ridge lines, wherein in a single titanium oxide particle, a vertex density per unit surface area is 8.0×10 −4 nm −2 or more, and a ridge line density per unit surface area is 5.0×10 −2 nm or more, or a ridge line density per unit volume is 8.0×10 −3 nm −2 or more. A complex comprising: a material having a porous structure; and said catalyst. A membrane electrode assembly comprising: an anode; cathode; and an electrolyte membrane, wherein the cathode carries said catalyst on at least a surface of the cathode.
1. A cathode comprising:
a carrier and
a layer of an electrochemical catalyst carried on at least the surface of the carrier,
wherein the carrier is formed of a material having metal conductivity and is configured that electrons supplied from the anode can be transferred to the electrochemical catalyst,
wherein the electrochemical catalyst comprises a titanium oxide having an anatase-type crystal structure, and having the vertices and the ridge lines, and
wherein in a single titanium oxide particle, a vertex density per unit surface area is 8.0×10 −4 nm −2 or more, or a vertex density per unit volume is 7.0×10 −4 nm −3 or more, and a ridge line density per unit surface area is 5.0×10 −2 nm −1 or more, or a ridge line density per unit volume is 8.0×10 −3 nm −2 or more.
2. The cathode according to claim 1 ,
wherein, in the single titanium oxide particle, the vertex density per unit surface area is 2.0×10 −3 nm −2 or more, or the vertex density per unit volume is 1.0×10 −3 nm −3 or more, and the ridge line density per unit surface area is 6.2×10 −2 nm −1 or more, or the ridge line density per unit volume is 1.3×10 −2 nm −2 or more.
3. The cathode according to claim 1 ,
wherein the electrochemical catalyst further comprises a composite oxide obtained by substituting a part of titanium in the titanium oxide with at least one selected from the group consisting of a metal element other than titanium,
an element belonging to the carbon group, an element belonging to the nitrogen group, and
an element belonging to the oxygen group other than oxygen.
4. The cathode according to claim 3 ,
wherein the metal element other than titanium is an element belonging to Group 3, Group 4, or Group 5 of the periodic table.
5. The cathode according to claim 4 ,
wherein the element belonging to Group 4 of the periodic table is zirconium or hafnium.
6. The cathode according to claim 4 ,
wherein the element belonging to Group 5 of the periodic table is niobium or tantalum.
7. The cathode according to claim 1 ,
wherein the carrier has a porous structure.
8. The cathode according to claim 7 ,
wherein the porous structure is a mesh structure or a three-dimensional network structure.
9. The cathode according to claim 1 ,
wherein the material of the carrier is a titanium.
10. The cathode according to claim 1 ,
wherein the thickness of the layer of the electrochemical catalyst is 100 nm or more and 500 μm or less.
11. A membrane electrode assembly comprising:
an anode;
a cathode of claim 1 ; and
an electrolyte membrane.
12. A method of producing alcohols comprising:
using a membrane electrode assembly of claim 11 .