IP Library Granted Patent US 11,053,338
Granted Patent B2
US 11,053,338 · App. 16/386,978 · Granted Jul 6, 2021

Composition

Inventors: Geert Lodewijk Dries (Zonhoven, BE); Robert Allison Grigsby (Spring, TX); Ernest Lee Rister, Jr. (Round Rock, TX); Eugene P. Wiltz, Jr. (The Woodlands, TX)
Assignee: HUNTSMAN Petrochemical LLC
C08G18/14C08G18/302C08G18/3228C08G18/485C08G18/4837C08G18/6685C08G18/7664C08G18/7671C08G2110/0058C08G2110/0083
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Quick Facts
Patent No.
US 11,053,338
App. No.
16/386,978
Granted
Jul 6, 2021
Kind
B2
Abstract

An isocyanate reactive composition comprising At least one component selected from the group consisting of a polyether polyol, a polyester polyol, a polyether polyamide and a polyester polyamide; one or more amine components, each of said amine components having a given structure. In some embodiments, the average number of nitrogen atoms of said amine components is in the range of 5 to 10.

Claims (27)

1. A composition comprising

at least one isocyanate component

at least one component selected from the group consisting of a polyether polyol, a polyester polyol, a polyether polyamide and a polyester polyamide;

two or more amine components having a structure according to the formula

and

one or more amine components having a structure according to the formula

wherein R a for at least one of the amine components of formula (1) comprises 3 to 6 nitrogen atoms and R a for at least one of the amine components of formula (1) comprises 7 to 17 nitrogen atoms, Rb comprises 2 to 16 nitrogen atoms and each of R a and R b independently comprises a plurality of units selected from at least one of R1, R2, and R3, combined in a random sequence, wherein:

R1 is

R2 is

and R3 is

wherein each of R 4 , R 5 , R 6 and R 7 individually are —H or —CH 3 ; and wherein the amount of the one or more amine components in the composition is between 0.05% wt and 1% wt calculated on the total weight of the composition.

2. A composition according to claim 1 , wherein the average number of nitrogen atoms of said one or more amine components is in the range of 5 to 10.

3. A composition according to claim 2 , wherein the average number of nitrogen atoms of said one or more amine components is in the range 5 to 8.

4. A composition according to claim 1 , wherein said one or more amine components comprise at least one component comprising at least two primary amine groups and at least one secondary amine group.

5. A composition according to claim 1 , wherein R 4 , R 5 , R 6 and R 7 are each hydrogen.

6. A composition according to claim 5 , wherein said two or more amine components is a mixture comprising at least one of triethyltetramines (TETA), tetraethyl pentamines (TEPA), pentaethylhexamines (PEHA), and at least one of hexaethylheptamines (HEHA), heptaethyloctamines (HEOA) and octaethylenenonamines (OENO).

7. A composition comprising

at least one component selected from the group consisting of a polyether polyol, a polyester polyol, a polyether polyamide and a polyester polyamide;

one or more amine components having a structure according to the formula

and

one or more amine components having a structure according to the formula

wherein R a , comprises 3 to 17 nitrogen atoms, R b comprises 2 to 16 nitrogen atoms and R a comprises a plurality of units selected from at least one of R1 and R3, combined in a random sequence and Rb comprises one or more units selected from R2,

wherein:

R1 is

R2 is

and R3 is

wherein each of R 4 , R 5 , R 6 and R 7 individually are —H or —CH 3 ; and wherein the total amount of the amine components having a structure according to formulas (1) and (2) in the composition is between 0.05% wt and 1% wt calculated on the total weight of the composition.

Assignments (2)
SECURITY INTEREST Recorded May 4, 2026
From: HUNTSMAN INTERNATIONAL LLC; HUNTSMAN ADVANCED MATERIALS AMERICAS LLC; HUNTSMAN NANOCOMP LLC; HUNTSMAN PETROCHEMICAL LLC
To: CITIBANK N.A.
Reel/Frame 075498/0663 →
PATENT SECURITY AGREEMENT Recorded Mar 10, 2026
From: HUNTSMAN INTERNATIONAL LLC; HUNTSMAN ADVANCED MATERIALS AMERICAS LLC; HUNTSMAN NANOCAMP LLC; HUNTSMAN PETROCHEMICAL LLC
To: CITIBANK, N.A.
Reel/Frame 075106/0238 →
Continuity (3)
Division 14420915
Provisional Application 61683957 · Aug 16, 2012
Related Publication 20190263958A1 · Aug 29, 2019