IP Library › Granted Patent US 11,123,590
Granted Patent B1
US 11,123,590 · App. 16/509,523 · Granted Sep 21, 2021

Abatement of asbestos using fluorinated metal compounds

Inventors: Ferdinando F Bruno (Reading, MA); Manuele Bernabei (Rome, IT); LTC Andrea Chiappa (Rome, IT); David Ziegler (Clinton, MA); Nicole F Farhadi (Plymouth, MA)
Assignee: U.S. Government as Represented by the Secretary of the Army
A62D3/33G01N21/3577A62D2101/41G01N2021/3595
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Quick Facts
Patent No.
US 11,123,590
App. No.
16/509,523
Granted
Sep 21, 2021
Kind
B1
Abstract

The disclosed subject matter relates to a method of treating of asbestos or asbestos-containing material, comprising applying to the asbestos or asbestos-containing material a composition including a treatment compound comprising at least one of hexafluoro titanium di-ammonium, potassium hexafluoro zirconate. ammonium hexafluoro phosphate. ammonium hexafluoro stannate, ammonium hexafluoro germanate, ammonium tetrafluoro borate or ammonium heptafluoro tantalite; and a fluorine scavenger compound.

Claims (16)

1. A method of treating of asbestos or asbestos-containing material, comprising:

applying to the asbestos or asbestos-containing material a composition including a treatment compound comprising at least one of hexafluoro titanium di-ammonium, potassium hexafluoro zirconate, ammonium hexafluoro phosphate, ammonium hexafluoro stannate, ammonium hexafluoro germanate, ammonium tetrafluoro borate or ammonium heptafluoro tantalite; and a fluorine scavenger compound.

2. The method according to claim 1 , wherein the fluorine scavenger compound is boric acid.

3. The method according to claim 1 , wherein the treatment compound is hexafluoro titanium di-ammonium.

4. The method according to claim 1 , wherein the asbestos or asbestos-containing material includes asbestos fibers and applying the treatment compound results in crosslinked asbestos fibers, coated asbestos fibers or both.

5. The method according to claim 1 , wherein the applying step is conducted at room temperature and ambient pressure.

6. The method according to claim 1 , wherein the amount of treatment compound is greater than the molar amount of asbestos.

7. The method according to claim 1 , wherein the amount of fluorine scavenger compound provides greater than one hydrogen for each fluorine in the treatment compound.

8. A method of treating of asbestos or asbestos-containing material including chrysotile, comprising:

applying to the asbestos or asbestos-containing material a composition including a treatment compound comprising hexafluoro titanium di-ammonium; and

a fluorine scavenger compound comprising boric acid.

9. The method according to claim 8 , wherein the concentration of hexafluoro titanium di-ammonium is in molar excess to the concentration of chrysotile in the asbestos or asbestos-containing material to which it is applied.

10. The method according to claim 8 , wherein the asbestos or asbestos-containing material includes asbestos fibers and applying the treatment compound results in crosslinked asbestos fibers, coated asbestos fibers or both.

11. The method according to claim 8 , wherein the applying step is conducted at room temperature and ambient pressure.

12. The method according to claim 8 , wherein the amount of treatment compound is greater than the molar amount of chrysotile.

13. The method according to claim 8 , wherein the amount of fluorine scavenger compound provides at least one hydrogen for each fluorine in the treatment compound.

Assignments (1)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jul 12, 2019
From: BRUNO, FERDINANDO; ZIEGLER, DAVID; FARHADI, NICOLE; BERNABEI, MANUELE, COL; CHIAPPA, ANDREA, LTC
To: U.S. GOVERNMENT AS REPRESENTED BY THE SECRETARY OF THE ARMY
Reel/Frame 049732/0237 →