Methods and systems for syngas production and for efficient, flexible energy generation
Methods for producing syngas (e.g., H 2 and CO) include introducing a stream comprising H 2 O and CO 2 to a high-temperature co-electrolysis (HTCE) unit. A CO 2 sweep gas is also introduced to the HTCE unit. Both H 2 O and CO 2 are reduced in the HTCE unit to form the syngas and to form O 2 that is swept away from the HTCE unit by the CO 2 sweep gas, and the O 2 and CO 2 are then introduced to a combustion device (e.g., a gasifier), which may be configured to generate electrical power, as a result of combusting a carbonaceous fuel in the presence of the O 2 and CO 2 . The HTCE unit is powered at least in part by power from an electricity-generating sub-system (e.g., at least one nuclear power plant). Related systems are also disclosed.
1. A method for producing syngas comprising hydrogen (H 2 ) and carbon monoxide (CO), the method comprising:
introducing a gasifier input stream to a gasifier, the gasifier input stream comprising oxygen (O 2 ) and carbon dioxide (CO 2 );
in the gasifier, gasifying a carbonaceous fuel in the presence of the oxygen (O 2 ) and the carbon dioxide (CO 2 ) to produce a combustible gas;
combusting the gas to generate exhaust gases;
passing the exhaust gases through at least one turbine to generate power and to produce an output stream comprising carbon dioxide (CO 2 );
supplying, to a high-temperature co-electrolysis (HTCE) unit, a first input stream comprising water (H 2 O) and a portion of the carbon dioxide (CO 2 ) of the output stream;
supplying, to the HTCE unit, a second input stream comprising another portion of the carbon dioxide (CO 2 ) of the output stream;
in the HTCE unit, reducing, by co-electrolysis, both the water (H 2 O) and the portion of the carbon dioxide (CO 2 ) to produce the oxygen (O 2 ) and the syngas comprising the hydrogen (H 2 ) and the carbon monoxide (CO); and
transporting the oxygen (O 2 ) and excess carbon dioxide (CO 2 ) from the HTCE unit to the gasifier as the gasifier input stream.
2. The method of claim 1 , further comprising powering the HTCE unit using electrical power generated by at least one nuclear reactor.
3. The method of claim 2 , further comprising supplying the water (H 2 O) of the first input stream from the at least one nuclear reactor.
4. The method of claim 2 , further comprising providing at least a portion of the electrical power generated by the at least one nuclear reactor to a power grid.
5. The method of claim 2 , wherein the at least one nuclear reactor comprises a plurality of small modular reactors (SMRs).
6. The method of claim 1 , further comprising providing the power generated by the at least one turbine to a power grid.
7. The method of claim 1 , wherein all heat for operation of the HTCE unit is supplied by the water (H 2 O) and the carbon dioxide (CO 2 ) introduced to the HTCE unit.
8. The method of claim 1 , wherein all the oxygen (O 2 ) introduced to the gasifier is the oxygen (O 2 ) produced from the HTCE unit.
9. The method of claim 1 , further comprising:
powering the HTCE unit using electrical power generated by at least one nuclear reactor; and
providing, to a power grid, at least a portion of the power generated by the at least one turbine and at least a portion of the electrical power generated by the at least one nuclear reactor.
10. The method of claim 1 , further comprising powering the HTCE unit with electrical power supplied by an electricity-generating sub-system.
11. The method of claim 10 , wherein the first input stream comprising the water (H 2 O) and the portion of the carbon dioxide (CO 2 ) comprises water output from the electricity-generating sub-system.
12. The method of claim 1 , further comprising supplying the syngas to a metal reduction reactor.
13. The method of claim 1 , wherein gasifying a carbonaceous fuel comprises gasifying coal.
14. A system for producing syngas comprising hydrogen (H 2 ) and carbon monoxide (CO) and for generating electrical power, the system comprising:
a high-temperature co-electrolysis (HTCE) unit;
at least one nuclear reactor configured to provide electrical power to the HTCE unit and configured to provide steam (H 2 O) to the HTCE unit;
an integrated gasification combined cycle (IGCC) power plant;
an oxygen (O 2 ) and carbon dioxide (CO 2 ) stream line in communication with both the HTCE unit and the IGCC power plant; and
another carbon dioxide (CO 2 ) stream line in communication with both the HTCE unit and the IGCC power plant.
15. The system of claim 14 , further comprising a water separation unit operatively following the IGCC power plant and configured to separate carbon dioxide (CO 2 ) output by the IGCC from water output by the IGCC.
16. The system of claim 14 , wherein the oxygen (O 2 ) and carbon dioxide (CO 2 ) stream line exits the HTCE unit at an anode side of the HTCE unit.
17. The system of claim 14 , wherein the another carbon dioxide (CO 2 ) stream line enters the HTCE unit proximate a cathode side of the HTCE unit.
18. The system of claim 14 , wherein the IGCC power plant is not in operative communication with an air separation unit.
19. A method for producing syngas comprising hydrogen (H 2 ) and carbon monoxide (CO), the method comprising:
introducing an input stream comprising water (H 2 O) and carbon dioxide (CO 2 ) to a high-temperature co-electrolysis (HTCE) unit;
introducing a carbon dioxide (CO 2 ) sweep gas to the HTCE unit;
in the HTCE unit, reducing both the water (H 2 O) and the carbon dioxide (CO 2 ) of the input stream to form the syngas comprising the hydrogen (H 2 ) and the carbon monoxide and to form oxygen (O 2 );
sweeping the oxygen (O 2 ) away from the HTCE unit using the carbon dioxide (CO 2 ) sweep gas;
introducing the oxygen (O 2 ) and the carbon dioxide (CO 2 ) sweep gas to a combustion sub-system;
in the combustion sub-system, combusting a carbonaceous fuel in the presence of the oxygen (O 2 ) and the carbon dioxide (CO 2 ) sweep gas; and
power the HTCE unit with electrical power supplied by an electricity-generating sub-system.
20. The method of claim 19 , wherein:
the input stream comprising the water (H 2 O) and the carbon dioxide (CO 2 ) comprises carbon dioxide (CO 2 ) output from the combustion sub-system; and
the carbon dioxide (CO 2 ) sweep gas comprises additional carbon dioxide (CO 2 ) output from the combustion sub-system.