IP Library Granted Patent US 11,142,832
Granted Patent B2
US 11,142,832 · App. 16/484,776 · Granted Oct 12, 2021

Methods and systems for syngas production and for efficient, flexible energy generation

Inventors: James E. O'Brien (Idaho Falls, ID); Carl M. Stoots (Idaho Falls, ID); Michael G. McKellar (Idaho Falls, ID); Richard D. Boardman (Idaho Falls, ID)
Assignee: Battelle Energy Alliance, LLC
C25B1/042C21B13/0073C25B1/04C25B15/08F02C3/34F02C6/10
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Quick Facts
Patent No.
US 11,142,832
App. No.
16/484,776
Granted
Oct 12, 2021
Kind
B2
Abstract

Methods for producing syngas (e.g., H 2 and CO) include introducing a stream comprising H 2 O and CO 2 to a high-temperature co-electrolysis (HTCE) unit. A CO 2 sweep gas is also introduced to the HTCE unit. Both H 2 O and CO 2 are reduced in the HTCE unit to form the syngas and to form O 2 that is swept away from the HTCE unit by the CO 2 sweep gas, and the O 2 and CO 2 are then introduced to a combustion device (e.g., a gasifier), which may be configured to generate electrical power, as a result of combusting a carbonaceous fuel in the presence of the O 2 and CO 2 . The HTCE unit is powered at least in part by power from an electricity-generating sub-system (e.g., at least one nuclear power plant). Related systems are also disclosed.

Claims (44)

1. A method for producing syngas comprising hydrogen (H 2 ) and carbon monoxide (CO), the method comprising:

introducing a gasifier input stream to a gasifier, the gasifier input stream comprising oxygen (O 2 ) and carbon dioxide (CO 2 );

in the gasifier, gasifying a carbonaceous fuel in the presence of the oxygen (O 2 ) and the carbon dioxide (CO 2 ) to produce a combustible gas;

combusting the gas to generate exhaust gases;

passing the exhaust gases through at least one turbine to generate power and to produce an output stream comprising carbon dioxide (CO 2 );

supplying, to a high-temperature co-electrolysis (HTCE) unit, a first input stream comprising water (H 2 O) and a portion of the carbon dioxide (CO 2 ) of the output stream;

supplying, to the HTCE unit, a second input stream comprising another portion of the carbon dioxide (CO 2 ) of the output stream;

in the HTCE unit, reducing, by co-electrolysis, both the water (H 2 O) and the portion of the carbon dioxide (CO 2 ) to produce the oxygen (O 2 ) and the syngas comprising the hydrogen (H 2 ) and the carbon monoxide (CO); and

transporting the oxygen (O 2 ) and excess carbon dioxide (CO 2 ) from the HTCE unit to the gasifier as the gasifier input stream.

2. The method of claim 1 , further comprising powering the HTCE unit using electrical power generated by at least one nuclear reactor.

3. The method of claim 2 , further comprising supplying the water (H 2 O) of the first input stream from the at least one nuclear reactor.

4. The method of claim 2 , further comprising providing at least a portion of the electrical power generated by the at least one nuclear reactor to a power grid.

5. The method of claim 2 , wherein the at least one nuclear reactor comprises a plurality of small modular reactors (SMRs).

6. The method of claim 1 , further comprising providing the power generated by the at least one turbine to a power grid.

7. The method of claim 1 , wherein all heat for operation of the HTCE unit is supplied by the water (H 2 O) and the carbon dioxide (CO 2 ) introduced to the HTCE unit.

8. The method of claim 1 , wherein all the oxygen (O 2 ) introduced to the gasifier is the oxygen (O 2 ) produced from the HTCE unit.

9. The method of claim 1 , further comprising:

powering the HTCE unit using electrical power generated by at least one nuclear reactor; and

providing, to a power grid, at least a portion of the power generated by the at least one turbine and at least a portion of the electrical power generated by the at least one nuclear reactor.

10. The method of claim 1 , further comprising powering the HTCE unit with electrical power supplied by an electricity-generating sub-system.

11. The method of claim 10 , wherein the first input stream comprising the water (H 2 O) and the portion of the carbon dioxide (CO 2 ) comprises water output from the electricity-generating sub-system.

12. The method of claim 1 , further comprising supplying the syngas to a metal reduction reactor.

13. The method of claim 1 , wherein gasifying a carbonaceous fuel comprises gasifying coal.

14. A system for producing syngas comprising hydrogen (H 2 ) and carbon monoxide (CO) and for generating electrical power, the system comprising:

a high-temperature co-electrolysis (HTCE) unit;

at least one nuclear reactor configured to provide electrical power to the HTCE unit and configured to provide steam (H 2 O) to the HTCE unit;

an integrated gasification combined cycle (IGCC) power plant;

an oxygen (O 2 ) and carbon dioxide (CO 2 ) stream line in communication with both the HTCE unit and the IGCC power plant; and

another carbon dioxide (CO 2 ) stream line in communication with both the HTCE unit and the IGCC power plant.

15. The system of claim 14 , further comprising a water separation unit operatively following the IGCC power plant and configured to separate carbon dioxide (CO 2 ) output by the IGCC from water output by the IGCC.

16. The system of claim 14 , wherein the oxygen (O 2 ) and carbon dioxide (CO 2 ) stream line exits the HTCE unit at an anode side of the HTCE unit.

17. The system of claim 14 , wherein the another carbon dioxide (CO 2 ) stream line enters the HTCE unit proximate a cathode side of the HTCE unit.

18. The system of claim 14 , wherein the IGCC power plant is not in operative communication with an air separation unit.

19. A method for producing syngas comprising hydrogen (H 2 ) and carbon monoxide (CO), the method comprising:

introducing an input stream comprising water (H 2 O) and carbon dioxide (CO 2 ) to a high-temperature co-electrolysis (HTCE) unit;

introducing a carbon dioxide (CO 2 ) sweep gas to the HTCE unit;

in the HTCE unit, reducing both the water (H 2 O) and the carbon dioxide (CO 2 ) of the input stream to form the syngas comprising the hydrogen (H 2 ) and the carbon monoxide and to form oxygen (O 2 );

sweeping the oxygen (O 2 ) away from the HTCE unit using the carbon dioxide (CO 2 ) sweep gas;

introducing the oxygen (O 2 ) and the carbon dioxide (CO 2 ) sweep gas to a combustion sub-system;

in the combustion sub-system, combusting a carbonaceous fuel in the presence of the oxygen (O 2 ) and the carbon dioxide (CO 2 ) sweep gas; and

power the HTCE unit with electrical power supplied by an electricity-generating sub-system.

20. The method of claim 19 , wherein:

the input stream comprising the water (H 2 O) and the carbon dioxide (CO 2 ) comprises carbon dioxide (CO 2 ) output from the combustion sub-system; and

the carbon dioxide (CO 2 ) sweep gas comprises additional carbon dioxide (CO 2 ) output from the combustion sub-system.

Assignments (1)
CONFIRMATORY LICENSE Recorded Dec 3, 2019
From: BATTELLE ENERGY ALLIANCE/IDAHO NAT'L LAB
To: UNITED STATES DEPARTMENT OF ENERGY
Reel/Frame 051167/0928 →
Continuity (2)
Provisional Application 62456963 · Feb 9, 2017
Related Publication 20190376190A1 · Dec 12, 2019
Cited By (4)
US 12,286,716 US 12,320,022 US 12,460,310 US 12,577,690