IP Library Granted Patent US 11,201,329
Granted Patent B2
US 11,201,329 · App. 16/382,331 · Granted Dec 14, 2021

Negative electrode for a rechargeable lithium battery and rechargeable lithium battery including the same

Inventors: Jinhyon Lee (Yongin-si, KR); Bokhyun Ka (Yongin-si, KR); Kyeuyoon Sheem (Yongin-si, KR); Soon Ho Ahn (Yongin-si, KR)
Assignee: SAMSUNG SDI CO., LTD.
H01M4/587H01M10/0525H01M2004/021H01M2004/027
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Quick Facts
Patent No.
US 11,201,329
App. No.
16/382,331
Granted
Dec 14, 2021
Kind
B2
Abstract

A negative electrode and a rechargeable lithium battery, the negative electrode including a current collector; and a negative active material layer on the current collector, the negative active material including a carbon negative active material; wherein: an electrode density of the negative electrode is in the range of about 1.0 g/cc to about 1.5 g/cc, and a DD (Degree of Divergence) value as defined by the following Equation 1 is about 24 or greater, DD (Degree of Divergence)=( I a /I total )*100  [Equation 1] wherein, in Equation 1, Ia is a sum of peak intensities at non-planar angles measured by XRD using a CuKα ray, and Itotal is a sum of peak intensities at all angles measured by XRD using a CuKα ray.

Claims (31)

1. A negative electrode for a rechargeable lithium battery, the negative electrode comprising:

a current collector; and

a negative active material layer on the current collector, the negative active material including a carbon negative active material;

wherein:

an electrode density of the negative electrode is in the range of about 1.0 g/cc to about 1.5 g/cc, and

a DD (Degree of Divergence) value as defined by the following Equation 1 is about 24 or greater,

DD (Degree of Divergence)=( I a /I total )*100  [Equation 1]

wherein, in Equation 1,

I a is a sum of peak intensities at non-planar angles measured by XRD using a CuKα ray,

I total is a sum of peak intensities at all angles measured by XRD using a CuKα ray,

the non-planar angles denote 2θ=42.4±0.2°, 43.4±0.2°, 44.6±0.2°, and 77.5±0.2°, and

all the angles denote 2θ=26.5±0.2°, 42.4±0.2°, 43.4±0.2°, 44.6±0.2°, 54.7±0.2°, and 77.5±0.2°.

2. The negative electrode for a rechargeable lithium battery as claimed in claim 1 , wherein the DD value of the negative electrode is about 24 to about 70.

3. The negative electrode for a rechargeable lithium battery as claimed in claim 1 , wherein the DD value of the negative electrode is about 24 to about 60.

4. The negative electrode for a rechargeable lithium battery as claimed in claim 1 , wherein the electrode density of the negative electrode is about 1.0 g/cc to about 1.4 g/cc.

5. The negative electrode for a rechargeable lithium battery as claimed in claim 1 , wherein the electrode density of the negative electrode is about 1.0 g/cc to about 1.2 g/cc.

6. The negative electrode for a rechargeable lithium battery as claimed in claim 1 , wherein the negative electrode has a single surface loading level (L/L) of about 6 mg/cm 2 to about 65 mg/cm 2 .

7. The negative electrode for a rechargeable lithium battery as claimed in claim 1 , wherein the negative active material layer has a thickness of a single surface except a substrate of about 40 μm to about 650 μm.

8. The negative electrode for a rechargeable lithium battery as claimed in claim 7 , wherein the negative active material layer has a thickness of a single surface except a substrate of about 40 μm to about 450 μm.

9. The negative electrode for a rechargeable lithium battery as claimed in claim 7 , wherein the negative active material layer has a thickness of a single surface except a substrate of about 40 μm to about 200 μm.

10. The negative electrode for a rechargeable lithium battery as claimed in claim 1 , wherein the peak intensities are peak integral area values.

11. The negative electrode for a rechargeable lithium battery as claimed in claim 1 , wherein the carbon negative active material is artificial graphite or a mixture of artificial graphite and natural graphite.

12. The negative electrode for a rechargeable lithium battery as claimed in claim 1 , wherein the negative active material layer further includes a Si negative active material, a Sn negative active material, a lithium vanadium oxide, or a combination thereof.

13. The negative electrode for a rechargeable lithium battery as claimed in claim 1 , wherein:

the negative electrode has an active region facing a positive electrode and an inactive region not facing the positive electrode, and

a DD value of the inactive region is about 24 or greater.

14. A rechargeable lithium battery, comprising:

the negative electrode as claimed in claim 1 ;

a positive electrode; and

an electrolyte.

15. The rechargeable lithium battery as claimed in claim 14 , wherein the rechargeable lithium battery is a high power battery.

Assignments (2)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Aug 30, 2021
From: AHN, SOO HO
To: SAMSUNG SDI CO., LTD.
Reel/Frame 057328/0047 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Apr 12, 2019
From: LEE, JINHYON; KA, BOKHYUN; SHEEM, KYEUYOON
To: SAMSUNG SDI CO., LTD.
Reel/Frame 048867/0106 →
Priority Claims (1)
KR 10-2018-0046210 · Apr 20, 2018 · national
Continuity (1)
Related Publication 20190326598A1 · Oct 24, 2019