Fuel cell and method for manufacturing separator for fuel cell including conductive particles and carbon fibers buried in projecting parts
A fuel cell according to the present disclosure includes separators 11 and 12 made of metal and having projection-depression shapes, and gas diffusion layers 13 and 14 . Conductive particles 21 are buried in a projecting part on one surface of each of the separators 11 and 12 , and carbon fibers 22 are buried in a projecting part on the other surface of each of the separators 11 and 12 . The projecting parts on the one surfaces of the separators 11 and 12 abut against each other so that the conductive particles 21 buried in these projecting parts come into contact with each other. Further, the projecting parts on the other surfaces of the separators 11 and 12 abut against the gas diffusion layers 13 and 14 , respectively, so that the carbon fibers 22 buried in these projecting parts come into contact with the gas diffusion layers 13 and 14 , respectively.
1. A fuel cell comprising:
a first separator made of metal and having a projection-depression shape;
a second separator made of metal and having a projection-depression shape, the first and second separators being configured so that a projecting part on one surface of the second separator abuts against a projecting part on one surface of the first separator, and a depressed part on the one surface of the second separator is opposed to a depressed part on the one surface of the first separator, thereby forming a flow path therebetween;
a first gas diffusion layer configured to abut against a projecting part on another surface of the first separator, and configured to diffuse a first gas flowing through a depressed part on the another surface of the first separator; and
a second gas diffusion layer configured to abut against a projecting part on another surface of the second separator, and configured to diffuse a second gas flowing through a depressed part on the another surface of the second separator, wherein
conductive particles are buried in the projecting part on the one surface of each of the first and second separators, and carbon fibers are buried in the projecting part on the another surface of each of the first and second separators,
the projecting parts on the one surfaces of the first and second separators abut against each other so that the conductive particles buried in these projecting parts come into contact with each other,
the projecting parts on the another surfaces of the first and second separators abut against the first and second gas diffusion layers, respectively, so that the carbon fibers buried in these projecting parts come into contact with the first and second gas diffusion layers, respectively,
the conductive particles are buried at corners of the projecting parts on the one surfaces of the first and second separators, and the carbon fibers are buried at corners of the projecting parts on the another surfaces of the first and second separators, and
a surface occupying area ratio of the conductive particles per unit area at the corners of the projecting parts on the one surfaces of the first and second separators is 20 to 60%.
2. The fuel cell according to claim 1 , wherein the conductive particles are tin oxide particles.
3. The fuel cell according to claim 2 , wherein a particle size of the tin oxide particles is 5 nm to 10 nm.
4. A method for manufacturing a fuel cell separator with a projection-depression shape formed on its surface, comprising sandwiching a metal plate between a first die and a second die, and performing press-forming, wherein
the first die comprises a projecting part and a depressed part,
the second die comprises a projecting part in a place opposed to the depressed part of the first die and a depressed part in a place opposed to the projecting part of the first die,
a groove filled with conductive particles is formed in a predetermined place in the depressed part of the first die, and the conductive particles contained in the groove are supplied to a surface of the metal plate during the press-forming, and
in the press-forming of the separator, the press-forming is performed in a state where the metal plate is disposed between the first and second dies, and a carbon fiber sheet is disposed between the metal plate and the second die, so that conductive particles are buried in a projecting part on one surface of the separator and carbon fibers are buried in a projecting part on another surface of the separator,
wherein the predetermined place is a corner of the projecting part of the first die, and the conductive particles are buried at a corner of the projecting part on the one surface of the separator during the press-forming process, and
a surface occupying area ratio of the conductive particles per unit area at the corner of the projecting part on the one surface of the separator is 20 to 60%.
5. The method for manufacturing a fuel cell separator according to claim 4 , wherein the conductive particles are tin oxide particles.
6. The method for manufacturing a fuel cell separator according to claim 5 , wherein a particle size of the tin oxide particles is be 5 nm to 10 nm.