IP Library Granted Patent US 11,208,367
Granted Patent B2
US 11,208,367 · App. 17/042,536 · Granted Dec 28, 2021

Production method for p-xylene

Inventors: Ai Minoda (Tokyo, JP); Masanari Akiyama (Tokyo, JP); Yasuhiro Araki (Tokyo, JP)
Assignee: ENEOS CORPORATION
C07C5/41C07C2/52C07C15/08
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Quick Facts
Patent No.
US 11,208,367
App. No.
17/042,536
Granted
Dec 28, 2021
Kind
B2
Abstract

A method for producing p-xylene, comprising: a dimerization step of bringing a first raw material comprising isobutene into contact with a dimerization catalyst to generate C8 components comprising diisobutylene; a cyclization step of bringing a second raw material comprising the C8 components into contact with a dehydrogenation catalyst comprising Pt in the presence of water to obtain a reaction product comprising p-xylene; and a collection step of collecting p-xylene from the reaction product.

Claims (10)

1. A method for producing p-xylene, comprising:

bringing a first raw material comprising isobutene into contact with a dimerization catalyst to generate C8 components comprising diisobutylene;

bringing a second raw material comprising the C8 components into contact with a dehydrogenation catalyst comprising Pt in the presence of water to obtain a reaction product comprising p-xylene, wherein the amount of water is from 0.1 equivalents to 10 equivalents based on the C8 components in the second raw material; and

collecting p-xylene from the reaction product.

2. The method according to claim 1 , wherein a C8 collected fraction comprising at least one selected from the group consisting of diisobutylene, 2,2,4-trimethylpentane, 2,5-dimethylhexane, 2,5-dimethylhexene and 2,5-dimethylhexadiene is further collected from the reaction product.

3. The method according to claim 2 , wherein the C8 collected fraction is recycled to the second raw material.

4. The method according to claim 1 , wherein a C4 collected fraction comprising at least one selected from the group consisting of isobutene and isobutane is further collected from the reaction product.

5. The method according to claim 4 , wherein the C4 collected fraction is recycled to the first raw material.

6. The method according to claim 1 , wherein the dimerization catalyst comprises at least one acidic catalyst selected from the group consisting of sulfuric acid, zeolite, solid phosphoric acid, hydrofluoric acid, ionic liquids, and ion-exchange resins.

7. The method according to claim 1 , wherein the dehydrogenation catalyst further comprises Sn.

Assignments (1)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Oct 21, 2020
From: MINODA, AI; AKIYAMA, MASANARI; ARAKI, YASUHIRO
To: ENEOS CORPORATION
Reel/Frame 054173/0360 →
Priority Claims (1)
JP JP2018-067599 · Mar 30, 2018 · national
Continuity (1)
Related Publication 20210009487A1 · Jan 14, 2021