IP Library Granted Patent US 11,233,254
Granted Patent B2
US 11,233,254 · App. 15/438,536 · Granted Jan 25, 2022

Process for delivering liquid H

Inventors: Jamie D. Holladay (Richland, WA); John Barclay (Richland, WA)
Assignees: Battelle Memorial Institute; Emerald Energy NW, LLC
H01M8/04208F25B21/00F25J1/001F25J1/0022H01M2250/20
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Quick Facts
Patent No.
US 11,233,254
App. No.
15/438,536
Granted
Jan 25, 2022
Kind
B2
Abstract

A process that includes pre-cooling a H 2 gas feedstock with a compressed liquid natural gas via a heat exchanger, introducing the pre-cooled H 2 gas feedstock into an active magnetic regenerative refrigerator H 2 liquefier module, and delivering liquid H 2 from the active magnetic regenerative refrigerator H 2 liquefier module to a liquid H 2 vehicle dispenser.

Claims (21)

1. A process comprising:

pre-cooling a H 2 gas feedstock via a heat exchanger wherein a compressed liquid natural gas is used in the heat exchanger for pre-cooling the H 2 gas feedstock;

introducing the pre-cooled H 2 gas feedstock into an active magnetic regenerative refrigerator H 2 liquefier that comprises at least one layer of a magnetic refrigerant material; and

delivering a first portion of liquid H 2 from the active magnetic regenerative refrigerator H 2 liquefier to a liquid H 2 dispenser for dispensing the liquid H 2 to a liquid H 2 vehicle, and compressing a second portion of liquid H 2 from the active magnetic regenerative refrigerator H 2 liquefier resulting in compressed hydrogen.

2. The process of claim 1 , further comprising compressing liquid natural gas resulting in the compressed liquid natural gas.

3. The process of claim 1 , further comprising:

introducing a portion of the liquid natural gas to a liquid natural gas dispenser for dispensing to a liquid natural gas vehicle;

introducing a portion of the compressed liquid natural gas to a compressed liquid natural gas dispenser for dispensing to a compressed liquid natural gas vehicle; and

introducing the compressed hydrogen into a compressed hydrogen dispenser for dispensing to a compressed hydrogen vehicle.

4. The process of claim 3 , further comprising:

dispensing compressed hydrogen at 700 bar from the compress hydrogen dispenser;

dispensing liquid H 2 at 2.7 bar from the liquid H 2 dispenser;

dispensing liquid natural gas at 2.7 bar from the liquid natural gas dispenser; and

dispensing compressed liquid natural gas at 240 bar from the compressed liquid natural gas dispenser.

5. The process of claim 3 , further comprising generating the H 2 gas feedstock via a solid oxide fuel cell, and introducing methane from the compressed liquid natural gas into the solid oxide fuel cell.

6. The process of claim 1 , wherein the pre-cooling of the H 2 gas feedstock comprises cooling 300 psia H 2 gas from 290 K to 140 K.

7. The process of claim 6 , further comprising introducing the 140 K pre-cooled H 2 gas feedstock into the active magnetic regenerative refrigerator H 2 liquefier, and cooling the H 2 from 140 K to 20 K in the active magnetic regenerative refrigerator H 2 liquefier resulting in the liquid H 2 .

8. The process of claim 7 , further comprising generating the H 2 gas feedstock via a solid oxide fuel cell, and introducing methane from the compressed liquid natural gas into the solid oxide fuel cell.

9. The process of claim 1 , further comprising generating the H 2 gas feedstock via a solid oxide fuel cell.

10. The process of claim 9 , further comprising introducing methane from the compressed liquid natural gas into the solid oxide fuel cell.

11. The process of claim 1 , wherein the active magnetic regenerative refrigerator H 2 liquefier comprises a rotary wheel that includes an annular bed, the annular bed comprising the at least one layer of the magnetic refrigerant material.

Assignments (3)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Mar 29, 2021
From: BARCLAY, JOHN
To: EMERALD ENERGY NW, LLC
Reel/Frame 055757/0729 →
CONFIRMATORY LICENSE Recorded Mar 15, 2017
From: BATTELLE MEMORIAL INSTITUTE, PACIFIC NORTHWEST DIVISION
To: U.S. DEPARTMENT OF ENERGY
Reel/Frame 041582/0096 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Mar 2, 2017
From: HOLLADAY, JAMIE D.
To: BATTELLE MEMORIAL INSTITUTE
Reel/Frame 041444/0178 →
Continuity (2)
Provisional Application 62298356 · Feb 22, 2016
Related Publication 20170244120A1 · Aug 24, 2017
Cited By (1)
US 12,288,904