Methods of preparing low tack soft gel compositions and such gel compositions prepared therefrom
Disclosed herein are methods of preparing thermoplastic gels and dry silicone gels with an alkyl ester polydimethylsiloxane having a formula (I): (I) Also disclosed are thermoplastic gels and dry silicone gels prepared by the disclosed methods. In the formula (I), n is about 60% to about 90% of the formula (I); m is about 10% to about 40% of the formula (I); R is —(C═O)—OR 1 ; and R is a C 2 -C 20 alkyl group. The alkyl ester polydimethylsiloxane has a weight average molecular weight of about 10,000 g/mol to about 50,000 g/mol. The hardness of the thermoplastic gels is less than 120 g peak load. The hardness of the dry silicone gels is less than 100 g peak load.
1. A method of preparing a low tack soft polymer gel, comprising:
preparing a polymer gel composition;
and
treating the polymer gel composition with an alkyl ester polydimethylsiloxane having a formula (I):
where
n is about 60% to about 90% of the formula (I);
m is about 10% to about 40% of the formula (I);
R is —(C═O)—OR 1 ; and
R 1 is a C 2 -C 20 alkyl group,
wherein the alkyl ester polydimethylsiloxane has a weight average molecular weight of about 10,000 g/mol to about 50,000 g/mol,
to provide the low tack soft polymer gel.
2. The method of claim 1 , wherein the low tack soft polymer gel has a tack time of about 2 seconds or less.
3. The method of claim 2 , wherein the low tack soft polymer gel has a tack time of about 1 second or less.
4. The method of claim 1 , wherein the low tack soft polymer gel has an adhesiveness less than 20 mJ.
5. The method of claim 1 , wherein n is about 70% to about 80% of the formula (I).
6. The method of claim 1 , wherein m is about 20% to about 30% of the formula (I).
7. The method of claim 1 , wherein the alkyl ester polydimethylsiloxane has a weight average molecular weight of about 15,000 g/mol to about 45,000 g/mol.
8. The method of claim 1 , wherein the alkyl ester polydimethylsiloxane has a weight average molecular weight of about 20,000 g/mol to about 40,000 g/mol.
9. The method of claim 8 , wherein the alkyl ester polydimethylsiloxane has a weight average molecular weight of about 25,000 g/mol to about 35,000 g/mol.
10. The method of claim 9 , wherein the alkyl ester polydimethylsiloxane has a weight average molecular weight between about 31,000 and about 33,000.
11. The method of claim 1 , wherein R 1 is a C 9 to C 18 alkyl group.
12. The method of claim 1 , wherein the alkyl ester polydimethylsiloxane has a number average molecular weight between about 13,000 and about 14,000.
13. The method of claim 1 , wherein the alkyl ester polydimethylsiloxane has a polydispersity index between about 2 and about 3.
14. The method of claim 13 , wherein the alkyl ester polydimethylsiloxane has a polydispersity index between about 2.3 and about 2.4.
15. The method of claim 1 , wherein the low tack soft polymer gel exhibits a hardness of less than 120 g peak load.
16. The method of claim 1 , wherein the polymer gel composition is selected from the group consisting of a thermoplastic gel composition and a silicone gel composition.
17. The method of claim 16 , wherein the preparing of the silicone gel composition comprises
preparing an uncured silicone gel composition; and
curing the uncured silicone gel composition to provide a cured silicone gel comprising crosslinked silicone polymers having a Si—O backbone.
18. The method of claim 17 , wherein preparing the uncured silicone gel composition comprises mixing a base polymer having a Si-vinyl group, a crosslinker, and a chain extender.
19. The method of claim 18 , wherein the base polymer is a vinyl-terminated polydimethylsiloxane.
20. The method of claim 17 , wherein the treating comprises
treating the cured silicone gel or uncured silicone gel composition with the alkyl ester polydimethylsiloxane of formula (I) to provide the low tack soft polymer gel.
21. The method of claim 20 , wherein the treating comprises
treating a surface of the cured silicone gel or uncured silicone gel composition with the alkyl ester polydimethylsiloxane of formula (I).
22. The method of claim 20 , wherein the treating comprises mixing into the uncured silicone gel composition the alkyl ester polydimethylsiloxane having a formula (I).
23. The method of claim 16 , wherein the silicone gel composition is a dry silicone gel composition.
24. The method of claim 16 , wherein the preparing of the thermoplastic gel composition comprises
mixing a styrene triblock copolymer, a styrene diblock copolymer, or a combination thereof, with an oil extender to provide a pre-swell.
25. The method of claim 24 , wherein the styrene triblock copolymer is selected from poly(styrene-butadiene-styrene), poly(styrene-ethylene/butylene-styrene), poly(styrene-ethylene/propylene-styrene), poly(styrene-ethylene/ethylene-propylene-styrene), poly(styrene-isoprene-styrene), and combinations thereof.
26. The method of claim 24 , wherein the styrene diblock copolymer is selected from poly(styrene-ethylene/propylene), poly(styrene-ethylene/butylene), and combinations thereof.
27. The method of claim 24 , wherein the treating comprises
treating the pre-swell with the alkyl ester polydimethylsiloxane of formula (I).
28. The method of claim 27 , wherein the treating of the pre-swell comprises
mixing into the pre-swell the alkyl ester polydimethylsiloxane of formula (I) to provide the low tack soft polymer gel.
29. The method of claim 24 , further comprising shaping the pre-swell to provide a shaped thermoplastic gel.
30. The method of claim 29 , wherein the treating comprises
treating a surface of the shaped thermoplastic gel with the alkyl ester polydimethylsiloxane having a formula (I) to provide the low tack soft polymer gel.