Stable herbicidal compositions
The present invention provide stable agrochemical compositions comprising 2-amino-4-[hydroxy(methyl)phosphinoyl]butyric acid (glufosinate), an organosilicone adjuvant, a nonionic surfactant and optionally one or more other active ingredients. A process for the preparation of such compositions and their use in controlling weeds are also provided.
1. A composition comprising a water soluble salt of glufosinate, an organosilicone adjuvant and a non-ionic surfactant,
wherein said non-ionic surfactant is selected from the group consisting of a polyethylene glycol ester of a fatty acid, a polyalkylene glycol monobutyl ether, a tristyryl phenol alkoxylate, and a C 1 -C 25 alcohol alkoxylate,
wherein said composition does not include a suspending agent, and
wherein said composition is an oil-in water emulsion,
wherein the composition does not exhibit creaming or phase separation after storage at 54±2° C. for 14 days and at 0° C. or −5° C. for 7 days.
2. The composition of claim 1 , wherein said water soluble salt is glufosinate ammonium or glufosinate-P.
3. The composition of claim 1 , wherein said organosilicone adjuvant is an organomodified siloxane selected from the group consisting of alkyl-modified trisiloxanes, alkoxylated trisiloxanes, and polyalkyleneoxide-modified trisiloxanes.
4. The composition of claim 1 , wherein said composition further comprises an anionic surfactant.
5. The composition of claim 4 , wherein said anionic surfactant is selected from the group consisting of ether carboxylate of a fatty alcohol having 10-24 carbon atoms, a sulphonate of a fatty alcohol having 10-24 carbon atoms, a sulfate of a fatty alcohol having 10-24 carbon atoms, a phosphate of a fatty alcohol having 10-24 carbon atoms, a salt of a tristrylphenol ether phosphate, a salt of a tristrylphenol ether sulfate, a linear alkyl benzene sulphonate, and an alkyl sulfosuccinate.
6. The composition as claimed in claim 1 , wherein said composition comprises from 1% to 60% by weight of glufosinate, 0.1% to 5% by weight of the organosilicone adjuvant, and 0.1% to 25% by weight of the nonionic surfactant, wherein all weights are based on the total weight of the composition.
7. A method of weed control, said method comprising applying to plants or to their locus an effective amount of the composition of claim 1 .
8. A composition comprising a water soluble salt of glufosinate, an organosilicone adjuvant, a non-ionic surfactant, and one or more additional active ingredients
wherein said non-ionic surfactant is selected from the group consisting of a polyethylene glycol ester of a fatty acid, a polyalkylene glycol monobutyl ether, a tristyryl phenol alkoxylate, and a C 1 -C 25 alcohol alkoxylate;
wherein said composition does not include a suspending agent; and
wherein said composition is an oil-in water emulsion,
wherein the composition does not exhibit creaming or phase separation after storage at 54±2° C. for 14 days and at 0° C. or −5° C. for 7 days.
9. The composition of claim 8 , wherein said additional active ingredient is an herbicide.
10. The composition of claim 9 , wherein said herbicide is selected from the group consisting of diphenyl ethers, carbamates, thiocarbamates, haloacetanilides, phenoxycarboxylic acid herbicides, triazolinone herbicides, N-phenylphthalimi de herbicides, aryloxyphenoxy herbicides, quinolyloxy herbicides, quinoxalyloxy herbicides, pyridyloxy herbicides, benzoxalyloxy herbicides, benzothiazoleyloxyphenoxyalkanecarboxylic ester herbicides, cyclohexanedione herbicides, imidazolinones, pyrimidyloxypyridinecarboxylic acid herbicides, pyrimidyloxybenzoic acid herbicides, sulfonylureas, triazoleopyrimidinesulfonamide herbicides, and S—(N-aryl-N-alkylcarbamoylmethyl)dithiophosphoric esters.
11. A method of weed control said method comprising applying to plants or to their locus an effective amount of the composition of claim 8 .
12. A composition comprising a water soluble salt of glufosinate, an organosilicone adjuvant, a non-ionic surfactant and an additional herbicide selected from oxyfluorfen, S-metolachlor, haloxyfop and clodinafop,
wherein said non-ionic surfactant is selected from the group consisting of a polyethylene glycol ester of a fatty acid, a polyalkylene glycol monobutyl ether, a tristyryl phenol alkoxylate, and a C 1 -C 25 alcohol alkoxylate;
wherein said composition does not include a suspending agent; and
wherein said composition is an oil-in water emulsion,
wherein the composition does not exhibit creaming or phase separation after storage at 54±2° C. for 14 days and at 0° C. or −5° C. for 7 days.