Aluminum-oxide-forming composition and method for producing same, and polyolefin-based polymer nanocomposite containing zinc oxide particles or aluminum oxide particles and method of producing same
A method for producing aluminum oxide is provided. The method uses an aluminum-oxide-forming agent containing a partially hydrolyzed aluminum alkyl compound containing an aluminum trialkyl or a mixture thereof, and a solvent. It is thus possible to produce an aluminum oxide thin film or aluminum oxide particles on or in a substrate that is not resistant to polar solvents. A method of producing a polyolefin-based polymer nanocomposite containing zinc oxide particles or aluminum oxide particles using a solution containing a partially hydrolyzed zinc alkyl or a solution containing a partially hydrolyzed aluminum alkyl is also provided. The polyolefin-based polymer nanocomposite contains a polyolefin substrate and zinc oxide particles or aluminum oxide particles, and does not contain a dispersant. The zinc oxide particles or aluminum oxide particles have an average particle size of less than 100 nm.
1. A polyolefin-based polymer nanocomposite, which comprises a polyolefin base material and aluminum oxide particles and does not contain a dispersing agent, wherein the polyolefin base material is at least one selected from ethylene homopolymers; ethylene copolymers obtained by polymerizing ethylene and at least one type selected from propylene and α-olefins having 4 to 8 carbon atoms; propylene homopolymers; and propylene copolymers obtained by polymerizing propylene and at least one type selected from ethylene and α-olefins having 4 to 8 carbon atoms, wherein the polyolefin base material does not contain a carboxylic acid, and wherein the average particle diameter of the aluminum oxide particles is less than 100 nm, the content of the aluminum oxide particles is 3 wt % or more, and the aluminum oxide particles are prepared from alkyl aluminum partial hydrolyzate by heating in the polyolefin base material.
2. The nanocomposite according to claim 1 , wherein the aluminum oxide particles are dispersed in the polyolefin base material.
3. The nanocomposite according to claim 1 , wherein the alkyl aluminum partial hydrolyzate is an alkyl aluminum partial hydrolyzate prepared by adding water to a solution containing an organic solvent an alkyl aluminum compound comprising a trialkyl aluminum or a mixture thereof at a molar ratio of 0.5 to 1.4 relative to aluminum in the alkyl aluminum compound.
4. A method for producing a polyolefin-based polymer nanocomposite which contains aluminum oxide particles, the method comprising (E) a step of impregnating a polyolefin powder with a solution containing a partial hydrolyzate of an alkyl aluminum compound comprised of a trialkyl aluminum or a mixture thereof wherein the alkyl groups may be the same or different and have 1 to 12 carbon atoms, and wherein the solution containing a partial hydrolyzate is prepared by adding water to a solution containing a non-alcoholic organic solvent and an alkyl aluminum compound of a trialkyl aluminum or a mixture thereof at a molar ratio of 0.5 to 1.4 relative to aluminum in the alkyl aluminum compound,
(F) a step of removing an organic solvent contained therein by drying the polyolefin powder,
(G) a step of supplying moisture to the alkyl aluminum partial hydrolyzate contained in the polyolefin powder to facilitate hydrolysis of the partial hydrolyzate; and
(H) a step of melting the polyolefin powder by heating to obtain a polyolefin-based polymer nanocomposite containing aluminum oxide particles.
5. The production method according to claim 4 , wherein the trialkyl aluminum is an alkyl aluminum compound represented by general formula (2-2) below:
AlR 2 3 (2-2)
wherein R 2 represents a methyl group, an ethyl group, an isobutyl group, an n-hexyl group or an n-octyl group, and the three R 2 groups may be the same or different.
6. The production method according to claim 4 , wherein the polyolefin powder has been prepared using a Ziegler-Natta catalyst.
7. The production method according to claim 4 , wherein the polyolefin-based polymer nanocomposite obtained in step (H) is a composite in which the aluminum oxide particles are dispersed in the polyolefin base material.