Aromatic polythiol compound for optical material
An embodiment relates to an aromatic polythiol compound for optical materials, and the aromatic polythiol compound according to the embodiment contains a phenyl group and a large number of sulfur atoms in its polythiol structure so that a polymerizable composition and an optical material obtained therefrom have excellent optical properties such as high refractive index and low specific gravity, as well as excellent mechanical properties such as low cure shrinkage; thus, they can be advantageously used for producing various plastic optical lenses such as eyeglass lenses and camera lenses.
1. An aromatic polythiol compound prepared by reacting a divinylbenzene compound represented by Formula 1 below and a bi- or higher-functional aliphatic polythiol,
wherein the bi- or higher-functional aliphatic polythiol is at least one selected from the group consisting of ethoxylated trimethylolpropane tri(3-mercaptopropionate), tris[2-(3-mercaptopropionyloxy)ethyl]isocyanurate, dipentaerythritol hexa(3-mercaptopropionate), and 5,9-dimercaptomethyl-1,13-dimercapto-3,7,11-trithiatridecane, and
wherein the molar ratio of the divinylbenzene compound to the bi- or higher-functional aliphatic polythiol is 1:2 to 1:10:
2. An aromatic polythiol compound prepared by reacting a divinylbenzene compound represented by Formula 1 below and a bi- or higher-functional aliphatic polythiol,
wherein the aromatic polythiol compound has a number average molecular weight of 500 to 3,000, and
wherein the bi- or higher-functional aliphatic polythiol is at least one selected from the group consisting of ethoxylated trimethylolpropane tri(3-mercaptopropionate), tris[2-(3-mercaptopropionyloxy)ethyl]isocyanurate, dipentaerythritol hexa(3-mercaptopropionate), and 5,9-dimercaptomethyl-1,13-dimercapto-3,7,11-trithiatridecane: