Extrudable polymer composition and method of making molded articles utilizing the same
The present invention provides an extrudable polymer composition comprising a base polymer and a bicomponent fiber comprising a low melt temperature component selected from the group consisting of high density polyethylene (HDPE) and polylactic acid (PLA) and a high melt temperature component selected from the group consisting of PET, 100% PDLA, 100% PLLA or a 50/50 blend of 100% PDLA and 100% PLLA, and nylon wherein the base polymer has a melt temperature of about 20° C. to 40° C. lower than this high melt temperature component of the bicomponent fiber.
1. An extrudable polymer composition comprising:
a) a base polymer; and
b) a bicomponent fiber comprising a low melt temperature component selected from the group consisting of high density polyethylene (HDPE) and polylactic acid (PLA) and a high melt temperature component selected from the group consisting of PET, 100% PDLA, 100% PLLA or a 50/50 blend of 100% PDLA and 100% PLLA, and nylon wherein the base polymer has a melt temperature of about 20° C. to 40° C. lower than this high melt temperature component of the bicomponent fiber.
2. The extrudable polymer composition according to claim 1 , wherein the low melt temperature component is bioHDPE.
3. The extrudable polymer composition according to claim 2 , wherein the high melt temperature component is stereocomplex PLA.
4. The extrudable polymer composition according to claim 3 , further comprising one or more components comprising cyclodextrin, nanofibers, a natural oil, fatty acid, fatty acid ester, wax or waxy ester, a crystallinity agent, a starch-based rheology agent and/or a gloss agent.
5. The extrudable polymer composition of claim 4 , wherein the natural oil is selected from the group consisting of lard, beef tallow, fish oil, coffee oil, coconut oil, soy bean oil, safflower oil, tung oil, tall oil, calendula, rapeseed oil, peanut oil, linseed oil, sesame oil, grape seed oil, olive oil, jojoba oil, dehydrated castor oil, tallow oil, sunflower oil, cottonseed oil, corn oil, canola oil, orange oil, and mixtures thereof.
6. The extrudable polymer composition of claim 4 , wherein the nanofibers are derived from fibers of silica or cellulose.
7. The extrudable polymer composition of claim 4 , wherein the crystallinity agent is selected from the group consisting of mica, kaolin, clay, talc, calcium carbonate, aluminum oxide and mixtures thereof.
8. The extrudable polymer composition of claim 4 , wherein the moisture level is less than about 0.02% of water.
9. The extrudable polymer composition of claim 1 , further comprising an additive selected from the group consisting of additional plasticizers, impact modifiers, additional fiber reinforcement, antioxidants, antimicrobials, fillers, UV stabilizers, colorants, glass transition temperature modifiers, melt temperature modifiers and heat deflection temperature modifiers.
10. The extrudable polymer composition of claim 1 , wherein the composition has a heat deflection temperature of greater than about 52° C. and a melt temperature between about 153° C. and about 230° C.
11. An article of manufacture formed from the extrudable polymer composition of claim 4 .
12. The article of manufacture of claim 11 , wherein the article of manufacture is selected from the group consisting of a bottle, lid, cap, closure, container, package and canister.
13. The article of manufacture of claim 11 , wherein article of manufacture is a container.
14. The extrudable polymer composition of claim 1 , wherein the bicomponent fiber comprises about 0.1% to about 10% by weight of the extrudable polymer composition.