Surfactant composition for the reinjection of produced water
The invention relates to the use of a non-ionic surfactant and an anionic surfactant for enhancing the injectivity of an injection well, wherein the non-ionic surfactant and the anionic surfactant are added to produced water, to form a reinjection stream which is injected into a subterranean formation by the injection well.
1. A method for enhancing the injectivity of an injection well, comprising:
adding a non-ionic surfactant and an anionic surfactant to water produced from the well, to form a reinjection stream;
injecting the reinjection stream into a subterranean formation via the injection well such that the injectivity of the injection well is enhanced;
wherein the anionic surfactant is of the formula R 2 —Y, wherein R 2 is a saturated or unsaturated aliphatic or aromatic group having from 10 to 18 carbon atoms, a mean degree of unsaturation from 0 to 3, and a mean degree of branching of from 0 to 5; and
wherein —Y is —O—(CH 2 CH(R 3 )O) m —(CH 2 CH 2 O) n —SO 3 − M + , wherein:
R 3 is an aliphatic or aromatic group having from 1 to 10 carbon atoms,
m is from 1 to 20,
n is from 0 to 5, and
M + is a monovalent cation.
2. The method of claim 1 , wherein the injectivity of the injection well is increased by a factor of at least 1.5 relative to the injectivity of the injection well when the non-ionic surfactant and the anionic surfactant are not present in the reinjection stream containing produced water which is injected into the subterranean formation by the injection well.
3. The method of claim 1 , wherein the injectivity of the injection well is maintained or restored at a level of at least 30%, relative to the maximal injectivity of the injection well.
4. The method of claim 1 , wherein the total concentration of the non-ionic surfactant and anionic surfactant in the reinjection stream is less than 500 ppm by weight.
5. The method of claim 1 , wherein the non-ionic surfactant is of formula R 1 —X, wherein R 1 is a saturated or unsaturated aliphatic or aromatic group having from 10 to 18 carbon atoms, a mean degree of unsaturation from 0 to 3, and a mean degree of branching of from 0 to 5, and X is a hydrophilic group selected from the group consisting of polyoxyalkylene groups, sorbitan groups, polyethoxylated sorbitan groups, polyglyceryl groups and glycosidic groups.
6. The method of claim 5 , wherein —X is —O—(CH 2 CH 2 O) p —H, and wherein p is from 1 to 20.
7. The method of claim 1 , wherein the weight proportion of anionic surfactant relative to the total of the anionic surfactant and non-ionic surfactant in the reinjection stream is from 50 to 95%.
8. The method of claim 1 , wherein the anionic surfactant and non-ionic surfactant are continuously added to the produced water for a period of time of at least 1 month.
9. The use of claim 1 , wherein a nature and/or a proportion of the non-ionic surfactant and the anionic surfactant are selected by preparing a plurality of mixtures of non-ionic surfactant, anionic surfactant, produced water or simulated produced water, and oil, agitating the plurality of mixtures and identifying a mixture which provides a water/oil micro-emulsion.
10. A method of extracting hydrocarbons from a subterranean formation, comprising:
collecting a production stream comprising hydrocarbons and produced water from at least one hydrocarbon production well;
separating the production stream into at least one or more hydrocarbon streams as well as a stream of produced water;
continuously adding a non-ionic surfactant and an anionic surfactant to at least part of the stream of produced water to provide a reinjection stream;
continuously injecting said reinjection stream into the subterranean formation by at least one injection well
wherein the anionic surfactant is of formula R 2 —Y, wherein R 2 is a saturated or unsaturated aliphatic or aromatic group having from 10 to 18 carbon atoms, a mean degree of unsaturation from 0 to 3, and a mean degree of branching of from 0 to 5; and
wherein —Y is —O—(CH 2 CH(R 3 )O) m —(CH 2 CH 2 O) n —SO 3 − M + , wherein:
R3 is an aliphatic or aromatic group having from 1 to 10 carbon atoms,
m is from 1 to 20,
n is from 0 to 5, and
M+ is a monovalent cation.
11. The method of claim 10 , wherein the injection well has an injectivity which is maintained or restored at a level of at least 30%, relative to its maximal injectivity.
12. The method of claim 10 , wherein the total concentration of the non-ionic surfactant and anionic surfactant in the reinjection stream is less than 500 ppm, by weight.
13. The method of claim 10 , wherein the non-ionic surfactant is of formula R 1 —X, wherein R 1 is a saturated or unsaturated aliphatic or aromatic group having from 10 to 18 carbon atoms, a mean degree of unsaturation from 0 to 3, and a mean degree of branching of from 0 to 5, and X is a hydrophilic group selected from polyoxyalkylene groups, sorbitan groups, polyethoxylated sorbitan groups, polyglyceryl groups and glycosidic groups.
14. The method of claim 13 , wherein —X is —O—(CH 2 CH 2 O) p —H, wherein p is from 1 to 20.
15. The method of claim 10 , wherein the weight proportion of anionic surfactant relative to the total of the anionic surfactant and non-ionic surfactant in the reinjection stream is from 50 to 95%.
16. The method of claim 10 , wherein the method is continuously implemented for a period of time of at least 1 month.