Doped passivated contacts
PolySi:Ga/SiO 2 passivated contacts were prepared using ion implantation and dopant inks to introduce Ga into a-Si. Following crystallization anneals these p-type contacts exhibited improved passivation (iVoc of about 730 mV) over B-doped passivated contacts for solar cells.
1. A method for fabricating gallium doped passivated contacts in a photovoltaic solar cell, the method comprising the steps of: providing a silicon substrate wherein the substrate is doped using ion implantation of gallium or spin-on dopant inks containing gallium; and wherein the doped substrate is annealed and passivated; wherein the annealing of the doped substrate comprises annealing at a temperature of about 950° C.; and wherein the passivated contacts have iVoc values of from about 710 to about 732 mV; and wherein the passivated contacts exhibit J oe values of from about 8.2 to about 3.0 fA/cm 2 , and wherein the passivated contacts are passivated with Al 2 O 3 and wherein the passivated contacts do not have pileup of gallium at a SiO 2 interface of the silicon substrate.
2. A photovoltaic solar cell comprising a silicon substrate comprising gallium doped passivated contacts wherein the passivated contacts have iVoc values of from about 710 to about 732 mV; and wherein the passivated contacts exhibit J oe values of from about 8.2 to about 3.0 fA/cm 2 ; and wherein the passivated contacts do not have pileup of gallium at a SiO 2 interface of the silicon substrate; and wherein the passivated contacts have fewer dopant-related defects in the SiO 2 interface when compared to contacts made with a boron dopant; and wherein the passivated contacts are passivated with Al 2 O 3 , and wherein the solar cell exhibits efficiency greater than at least 20%.
3. The photovoltaic solar cell of claim 2 wherein the silicon substrate is a crystalline silicon.
4. The photovoltaic solar cell of claim 2 wherein the silicon substrate is an n-type doped silicon.
5. The photovoltaic solar cell of claim 2 wherein the silicon substrate is a p-type doped silicon.
6. The photovoltaic solar cell of claim 2 wherein the silicon substrate is a monocrystalline silicon.
7. The photovoltaic solar cell of claim 2 wherein the silicon substrate is a multicrystalline silicon.