IP Library Granted Patent US 11,384,604
Granted Patent B2
US 11,384,604 · App. 17/018,524 · Granted Jul 12, 2022

Laser induced graphene coated optical fibers

Inventors: Satyan Gopal Bhongale (Cypress, TX); Daniel Joshua Stark (Houston, TX); Etienne Samson (Cypress, TX); Li Gao (Katy, TX)
Assignee: Halliburton Energy Services, Inc.
E21B17/003E21B47/00G01D5/268G01N21/00G02B6/02395G02B6/443G02B6/4415G02B6/4479H01G11/08H01G11/10H01G11/36H01G11/86G02B6/02
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Quick Facts
Patent No.
US 11,384,604
App. No.
17/018,524
Granted
Jul 12, 2022
Kind
B2
Abstract

Optical fiber having a graphene coating, a method to apply a graphene coating onto an optical fiber, and a fiber optic cable having a graphene coating are disclosed. A first carbon based coating is applied to an optical fiber along a longitudinal axis of the optical fiber. A laser beam is focused at the first carbon based coating. A first surface of the first carbon based coating is photothermally converted into a first layer of graphene.

Claims (42)

1. A method to apply a graphene coating onto an optical fiber, the method comprising:

applying a first carbon based coating to an optical fiber along a longitudinal axis of the optical fiber;

focusing a laser beam at the first carbon based coating;

photothermally converting a first surface of the first carbon based coating into a first layer of graphene; and

forming a plurality of electrical components on the first layer of graphene.

2. The method of claim 1 , wherein photothermally converting the first surface of the first carbon based coating into the first layer of graphene comprises converting carbon atoms of the first carbon based coating from having an sp3 hybridization to an sp2 hybridization.

3. The method of claim 1 , further comprising:

applying a second carbon based coating to the optical fiber along the longitudinal axis of the optical fiber; and

photothermally converting a first surface of a second carbon based coating into a second layer of graphene,

wherein the second layer of graphene is positioned in between an optical core component of the optical fiber and the first layer of graphene.

4. The method of claim 1 , further comprising:

photothermally converting the first surface of the first carbon based coating into a graphene electrode pattern; and

forming at least one of positive electrode and at least one of negative electrode from the graphene electrode pattern,

wherein the plurality of electrical components are formed from the at least one positive and the at least one negative graphene electrode.

5. The method of claim 4 , further comprising:

forming a power source from the plurality of electrical components,

wherein the power source supplies power to a downhole tool.

6. The method of claim 4 , further comprising:

forming a sensor component from the plurality of electrical components,

wherein the sensor component provides measurements of a downhole environment.

7. The method of claim 6 , wherein the sensor component is operable to measure at least one of a pressure, temperature, resistivity, electromagnetic field strength and direction, acoustic field strength, radioactive flux, water content, and pH of the downhole environment.

8. The method of claim 1 , further comprising treating the first layer of graphene with a charged chemical to form a microsupercapacitor on the first layer of graphene.

9. The method of claim 8 , further comprising selecting the charged chemical from at least one of manganese dioxide, ferric oxyhydroxide, polyaniline, and poly(vinyl alcohol).

10. The method of claim 1 , further comprising combining the first layer of graphene with at least one of MoS2, hexagonal boron nitride, and transition metal dichalcogenides to form at least one of the plurality of electrical components.

11. The method of claim 1 , further comprising disposing a preformed electrical component onto the first layer of graphene.

12. The method of claim 1 , further comprising applying an intermediary layer around the optical fiber.

13. The method of claim 12 , further comprising:

applying second carbon based coating to the intermediary layer along the longitudinal axis of the optical fiber;

focusing the laser beam at the second carbon based coating; and

photothermally converting a first surface of the second carbon based coating into a second layer of graphene.

14. The method of claim 12 , wherein the intermediary layer is applied to the optical fiber before first carbon based coating to the optical fiber.

15. A method to apply a graphene coating onto an optical fiber, the method comprising:

applying a first carbon based coating to an optical fiber along a longitudinal axis of the optical fiber;

focusing a laser beam at a first carbon based coating of the optical fiber;

photochemically converting a first surface of the first carbon based coating into a first layer of graphene; and

forming a plurality of electrical components on the first layer of graphene.

16. The method of claim 15 , further comprising:

applying a second carbon based coating to the optical fiber along the longitudinal axis of the optical fiber; and

photochemically converting a first surface of a second carbon based coating into a second layer of graphene,

wherein the second layer of graphene is positioned in between an optical core component of the optical fiber and the first layer of graphene.

17. The method of claim 15 , further comprising disposing a preformed electrical component onto the first layer of graphene.

18. The method of claim 15 , further comprising applying an intermediary layer around the optical fiber.

Assignments (3)
INTELLECTUAL PROPERTY AGREEMENT Recorded Nov 4, 2021
From: BHONGALE, SATYAN
To: HALLIBURTON ENERGY SERVICES, INC.
Reel/Frame 058029/0062 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Oct 21, 2020
From: STARK, DANIEL JOSHUA; SAMSON, ETIENNE; GAO, LI
To: HALLIBURTON ENERGY SERVICES, INC.
Reel/Frame 054124/0507 →
IP AGREEMENT Recorded Oct 21, 2020
From: BHONGALE, SATYAN
To: HALLIBURTON ENERGY SERVICES, INC.
Reel/Frame 054159/0706 →
Continuity (2)
Division 16315990
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