IP Library Granted Patent US 11,441,021
Granted Patent B2
US 11,441,021 · App. 16/925,521 · Granted Sep 13, 2022

Pneumatic tire

Inventors: Pascal Patrick Steiner (Vichten, LU); Georges Marcel Victor Thielen (Schouweiler, LU); Marc Weydert (Bertrange, LU); Benoit Duez (Mamer, LU)
Assignee: The Goodyear Tire & Rubber Company
C08L9/06B60C1/0016C08F132/08C08F212/08C08F293/005C08G77/26C08G77/28C08K3/36
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Quick Facts
Patent No.
US 11,441,021
App. No.
16/925,521
Granted
Sep 13, 2022
Kind
B2
Abstract

The present invention is directed to a pneumatic tire having a tread comprising a vulcanizable rubber composition comprising, based on 100 parts by weight of elastomer (phr), (A) 100 phr of a solution polymerized styrene-butadiene rubber having a glass transition temperature (Tg) ranging from −85° C. to −50° C.; (B) from 1 to 30 phr of a process oil; (C) from 20 to 80 phr of a hydrocarbon resin having a Tg of at least 30° C.; and (D) from 90 to 150 phr of silica.

Claims (31)

1. A pneumatic tire having a tread comprising a vulcanizable rubber composition comprising, based on 100 parts by weight of elastomer (phr),

(A) 100 phr of a solution polymerized styrene-butadiene rubber having a glass transition temperature (Tg) ranging from −85° C. to −50° C.;

(B) from 1 to 30 phr of a process oil;

(C) from 20 to 80 phr of a hydrocarbon resin having a Tg of at least 30° C.; and

(D) from 90 to 150 phr of silica.

2. The pneumatic tire of claim 1 , wherein the amount of process oil ranges from 1 to 10 phr.

3. The pneumatic tire of claim 1 , wherein the hydrocarbon resin is selected from the group consisting of styrene/alphamethylstyrene copolymer resins, C5/C9 copolymer resins, dicyclopentadiene resins, and aromatic dicyclopentadiene resins and combinations thereof.

4. The pneumatic tire of claim 1 , wherein the resin is an aromatic modified dicyclopentadiene resin.

5. The pneumatic tire of claim 1 , wherein the resin is a styrene/alphamethylstyrene copolymer resins.

6. The pneumatic tire of claim 1 , wherein the resin is a DCPD-based resin comprising from about 5 to about 90 mol % units derived from DCPD.

7. The pneumatic tire of claim 1 , wherein the resin is a DCPD-based resin comprising from 1 to 20 mol % aromatic hydrogen.

8. The pneumatic tire of claim 1 , wherein the resin is a C5/C9 resin comprising 50-90% (by weight) piperylenes, 0-5% isoprene, 10-30% amylenes, 2-5% cyclics, 4-10% styrenics, and 4-10% indenics.

9. The pneumatic tire of claim 1 , wherein the resin is a C5/C9 resin comprising an aromatic hydrogen content between 3 and 15 mole percent.

10. The pneumatic tire of claim 1 , wherein the solution polymerized styrene-butadiene rubber is functionalized with an alkoxysilane group and at least one functional group selected from the group consisting of primary amines and thiols.

11. The pneumatic tire of claim 1 , wherein the oil is selected from the group consisting of aromatic, paraffinic, naphthenic, MES, TDAE, heavy naphthenic oils, and vegetable oils.

12. The pneumatic tire of claim 1 , wherein the solution polymerized styrene-butadiene rubber functionalized with an alkoxysilane group and a primary amine group, and is represented by the formula (1) or (2)

wherein P is a (co)polymer chain of a conjugated diolefin or a conjugated diolefin and an aromatic vinyl compound, R 1 is an alkylene group having 1 to 12 carbon atoms, R 2 and R 3 are each independently an alkyl group having 1 to 20 carbon atoms, an allyl group or an aryl group, n is an integer of 1 or 2, m is an integer of 1 or 2, and k is an integer of 1 or 2, with the proviso that n+m+k is an integer of 3 or 4,

wherein P, R 1 , R 2 and R 3 have the same definitions as give for the above-mentioned formula (1), j is an integer of 1 to 3, and h is an integer of 1 to 3, with the provision that j+h is an integer of 2 to 4.

13. The pneumatic tire of claim 1 , wherein the solution polymerized styrene-butadiene rubber is functionalized with an alkoxysilane group and a primary amine group comprises the reaction product of a living polymer chain and a terminating agent of the formula

RN—(CH 2 ) X —Si—(OR′) 3 ,

wherein R in combination with the nitrogen (N) atom is a protected amine group which upon appropriate post-treatment yields a primary amine, R′ represents a group having 1 to 18 carbon atoms selected from an alkyl, a cycloalkyl, an allyl, or an aryl; and X is an integer from 1 to 20.

14. The pneumatic tire of claim 1 wherein the solution polymerized styrene-butadiene rubber is functionalized with an alkoxysilane group and a thiol, and comprises the reaction product of a living anionic polymer and a silane-sulfide modifier represented by the formula

(R 4 O) x R 4 y Si—R 5 —S—SiR 4 3

wherein Si is silicon; S is sulfur; O is oxygen; x is an integer selected from 1, 2 and 3; y is an integer selected from 0, 1, and 2; x+y=3; R 4 is the same or different and is (C 1 -C 16 ) alkyl; and R 5 is aryl, and alkyl aryl, or (C 1 -C 16 ) alkyl.

15. A vulcanizable rubber composition comprising

(A) 100 phr of a solution polymerized styrene-butadiene rubber having a glass transition temperature (Tg) ranging from −85° C. to −50° C.;

(D) from 1 to 30 phr of a process oil;

(E) from 55 to 80 phr of a hydrocarbon resin having a Tg of at least 30° C.; and

(F) from 90 to 150 phr of silica.

16. The vulcanizable rubber composition of claim 15 , wherein the amount of process oil ranges from 1 to 10 phr.

17. The vulcanizable rubber composition of claim 15 , in the form of a component of product selected from the group consisting of shoes, shoe soles, transmission belts, hoses, vibration dampers, airsprings, conveyor belts, and track belts.

Assignments (1)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Aug 13, 2020
From: STEINER, PASCAL PATRICK; THIELEN, GEORGES MARCEL VICTOR; WEYDERT, MARC; DUEZ, BENOIT
To: THE GOODYEAR TIRE & RUBBER COMPANY
Reel/Frame 053486/0703 →
Continuity (2)
Continuation In Part 16524284 · Jul 29, 2019
Related Publication 20210032443A1 · Feb 4, 2021
Cited By (3)
US 12,522,021 US 12,558,920 US 12,583,952