IP Library Granted Patent US 11,458,754
Granted Patent B2
US 11,458,754 · App. 16/858,766 · Granted Oct 4, 2022

Ink set

Inventor: Tsutomu Umebayashi (Kanagawa, JP)
Assignee: FUJIFILM CORPORATION
B41M5/0023B41M5/50C09D11/101C09D11/107C09D11/40
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Quick Facts
Patent No.
US 11,458,754
App. No.
16/858,766
Granted
Oct 4, 2022
Kind
B2
Abstract

An ink set includes an ink-jet color ink that contains a colorant, an organic solvent, a polymerizable compound, and a photopolymerization initiator and a clear ink which contains an organic solvent and a vinyl chloride-vinyl acetate copolymer and in which Mt2/Mt1 is 0.40 or more where Mt1 represents a total mass content of a nonvolatile component, and Mt2 represents a mass content of the vinyl chloride-vinyl acetate copolymer.

Claims (24)

1. An ink set comprising:

an ink-jet color ink that contains a colorant, an organic solvent, a polymerizable compound, and a photopolymerization initiator; and

a clear ink that contains an organic solvent and a vinyl chloride-vinyl acetate copolymer, and in which Mt2/Mt1 is 0.40 or more, wherein Mt1 represents a total mass content of a nonvolatile component in the clear ink, and Mt2 represents a mass content of the vinyl chloride-vinyl acetate copolymer in the clear ink.

2. The ink set according to claim 1 , wherein a content of the vinyl chloride-vinyl acetate copolymer contained in the clear ink is from 1.0% by mass to 6.0% by mass relative to a total amount of the clear ink.

3. The ink set according to claim 1 , wherein a content of the organic solvent contained in the clear ink is 90% by mass or more relative to a total amount of the clear ink.

4. The ink set according to claim 2 , wherein a content of the organic solvent contained in the clear ink is 90% by mass or more relative to a total amount of the clear ink.

5. The ink set according to claim 1 , wherein the polymerizable compound contained in the ink-jet color ink includes a bifunctional urethane (meth)acrylate having a weight-average molecular weight of from 2,000 to 15,000.

6. The ink set according to claim 4 , wherein the polymerizable compound contained in the ink-jet color ink includes a bifunctional urethane (meth)acrylate having a weight-average molecular weight of from 2,000 to 15,000.

7. The ink set according to claim 1 , wherein the ink-jet color ink further contains a vinyl chloride-vinyl acetate copolymer.

8. The ink set according to claim 6 , wherein the ink-jet color ink further contains a vinyl chloride-vinyl acetate copolymer.

9. The ink set according to claim 7 , wherein a total content of the polymerizable compound and the vinyl chloride-vinyl acetate copolymer that are contained in the ink-jet color ink is from 10% by mass to 20% by mass relative to a total amount of the ink-jet color ink.

10. The ink set according to claim 9 , wherein a content of the vinyl chloride-vinyl acetate copolymer contained in the ink-jet color ink is from 0.5% by mass to 2.0% by mass relative to a total amount of the ink-jet color ink.

11. The ink set according to claim 7 , wherein Mt1, Mt2, Mc1, and Mc2 satisfy the following formula (1):

Mc 2/ Mc 1≤ Mt 2/ Mt 1  Formula (1)

wherein Mt1 represents the total mass content of the nonvolatile component contained in the clear ink,

Mt2 represents the mass content of the vinyl chloride-vinyl acetate copolymer contained in the clear ink,

Mc1 represents a total mass content of a nonvolatile component contained in the ink-jet color ink, and

Mc2 represents a mass content of the vinyl chloride-vinyl acetate copolymer contained in the ink-jet color ink.

12. The ink set according to claim 11 , wherein a total content of the polymerizable compound and the vinyl chloride-vinyl acetate copolymer that are contained in the ink-jet color ink is from 10% by mass to 20% by mass relative to a total amount of the ink-jet color ink.

13. The ink set according to claim 11 , wherein a content of the vinyl chloride-vinyl acetate copolymer contained in the ink-jet color ink is from 0.5% by mass to 2.0% by mass relative to a total amount of the ink-jet color ink.

14. The ink set according to claim 1 , wherein a content of a polymerizable compound in the clear ink is 3% by mass or less relative to a total amount of the clear ink.

15. The ink set according to claim 6 , wherein a content of a polymerizable compound in the clear ink is 3% by mass or less relative to a total amount of the clear ink.

16. The ink set according to claim 12 , wherein a content of a polymerizable compound in the clear ink is 3% by mass or less relative to a total amount of the clear ink.

17. The ink set according to claim 13 , wherein a content of a polymerizable compound in the clear ink is 3% by mass or less relative to a total amount of the clear ink.

Assignments (1)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Apr 30, 2020
From: UMEBAYASHI, TSUTOMU
To: FUJIFILM CORPORATION
Reel/Frame 052532/0233 →
Priority Claims (1)
JP JP2017-213192 · Nov 2, 2017 · national
Continuity (2)
Continuation PCTJP2018038894 · Oct 18, 2018
Related Publication 20200254799A1 · Aug 13, 2020