IP Library Granted Patent US 11,498,849
Granted Patent B2
US 11,498,849 · App. 16/911,707 · Granted Nov 15, 2022

Solid electrolyte material and battery

Inventors: Tetsuya Asano (Nara, JP); Akihiro Sakai (Nara, JP); Yusuke Nishio (Osaka, JP); Masashi Sakaida (Hyogo, JP); Akinobu Miyazaki (Osaka, JP); Shinya Hasegawa (Kyoto, JP)
Assignee: PANASONIC INTELLECTUAL PROPERTY MANAGEMENT CO., LTD.
C01F17/36H01M10/0562H01M2300/008
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Quick Facts
Patent No.
US 11,498,849
App. No.
16/911,707
Granted
Nov 15, 2022
Kind
B2
Abstract

A solid electrolyte material contains Li, Y, at least one selected from the group consisting of Mg, Ca, Sr, Ba, Zn, Sc, La, Sm, Bi, Zr, Hf, Nb, and Ta, and at least one selected from the group consisting of Cl, Br, and I. An X-ray diffraction pattern of the solid electrolyte material obtained by using Cu-Kα radiation as the X-ray source includes peaks within the range in which the diffraction angle 2θ is 25° or more and 35° or less, and also includes at least one peak within the range in which the diffraction angle 2θ is 43° or more and 51° or less.

Claims (45)

1. A solid electrolyte material comprising:

Li;

Y;

at least one selected from the group consisting of Mg, Ca, Sr, Ba, Zn, Sc, La, Sm, Bi, Zr, Hf, Nb, and Ta; and

at least one selected from the group consisting of Cl, Br, and I, wherein:

an X-ray diffraction pattern of the solid electrolyte material obtained by using Cu-Kα radiation as an X-ray source

includes a plurality of peaks within a range in which a diffraction angle 2θ is 25° or more and 35° or less, and

includes at least one peak within a range in which the diffraction angle 2θ is 43° or more and 51° or less.

2. The solid electrolyte material according to claim 1 , wherein

the X-ray diffraction pattern further includes two peaks within a range in which the diffraction angle 2θ is 50° or more and 63° or less.

3. The solid electrolyte material according to claim 1 , wherein

the X-ray diffraction pattern further includes a peak within a range in which the diffraction angle 2θ is 13° or more and 18° or less.

4. The solid electrolyte material according to claim 1 , wherein:

the solid electrolyte material contains a sublattice of the at least one selected from the group consisting of Cl, Br, and I; and

the sublattice has a cubic close-packed or distorted cubic close-packed structure.

5. A battery comprising:

a solid electrolyte material according to claim 1 ;

a positive electrode;

a negative electrode; and

an electrolyte layer between the positive electrode and the negative electrode, wherein

at least one selected from the group consisting of the positive electrode, the negative electrode, and the electrolyte layer contains the solid electrolyte material.

6. A solid electrolyte material comprising:

Li;

Y;

at least one selected from the group consisting of Mg, Ca, Sr, Ba, Zn, Sc, La, Sm, Bi, Zr, Hf, Nb, and Ta; and

at least one selected from the group consisting of Cl, Br, and I, wherein:

a first converted pattern, which is obtained by measuring an X-ray diffraction pattern of the solid electrolyte material by using Cu-Kα radiation as an X-ray source and converting the X-ray diffraction pattern to change a horizontal axis of the X-ray diffraction pattern from a diffraction angle 2θ to q,

where q=4π sin θ/λ, where λ is a wavelength of the Cu-Kα radiation,

includes a base peak within a range in which q is 1.76 Å −1 or more and 2.18 Å −1 or less;

a second converted pattern, which is obtained by converting the X-ray diffraction pattern to change the horizontal axis of the X-ray diffraction pattern from the diffraction angle 2θ to q/q 0 ,

where q 0 is a q corresponding to the base peak in the first converted pattern,

includes a peak within each of a range in which q/q 0 is 1.14 or more and 1.17 or less and a range in which q/q 0 is 1.62 or more and 1.65 or less.

7. The solid electrolyte material according to claim 6 , wherein

the second converted pattern includes a peak within each of a range in which q/q 0 is 1.88 or more and 1.94 or less and a range in which q/q 0 is 1.9 or more and 2.1 or less.

8. The solid electrolyte material according to claim 6 , wherein

the second converted pattern includes a peak within a range in which q/q 0 is 0.49 or more and 0.56 or less.

9. The solid electrolyte material according to claim 6 , wherein:

the solid electrolyte material contains a sublattice of the at least one selected from the group consisting of Cl, Br, and I; and

the sublattice has a cubic close-packed or distorted cubic close-packed structure.

10. A battery comprising:

a solid electrolyte material according to claim 6 ;

a positive electrode;

a negative electrode; and

an electrolyte layer between the positive electrode and the negative electrode, wherein

at least one selected from the group consisting of the positive electrode, the negative electrode, and the electrolyte layer contains the solid electrolyte material.

Assignments (1)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Sep 18, 2020
From: ASANO, TETSUYA; SAKAI, AKIHIRO; NISHIO, YUSUKE; SAKAIDA, MASASHI; MIYAZAKI, AKINOBU; HASEGAWA, SHINYA
To: PANASONIC INTELLECTUAL PROPERTY MANAGEMENT CO., LTD.
Reel/Frame 053810/0180 →
Priority Claims (1)
JP JP2018-000425 · Jan 5, 2018 · national
Continuity (2)
Continuation PCTJP2018046258 · Dec 17, 2018
Related Publication 20200328460A1 · Oct 15, 2020
Cited By (1)
US 12,463,247