Hybrid multifunctional composite material and method of making the same
Hybrid composite materials including carbon nanotube sheets and flexible ceramic materials, and methods of making the same are provided herein. In one embodiment, a method of forming a hybrid composite material is provided, the method including: placing a layer of a first flexible ceramic composite on a lay-up tooling surface; applying a sheet of a pre-preg carbon fiber reinforced polymer on the flexible ceramic composite; curing the flexible ceramic composite and the pre-preg carbon fiber reinforced polymer sheet together to form a hybrid composite material; and removing the hybrid composite material from the lay-up tooling surface, wherein the first flexible ceramic composite comprises an exterior surface of the hybrid composite material.
1. A method of forming a hybrid composite material comprising:
placing a layer of a first flexible ceramic composite on a lay-up tooling surface, wherein the first flexible ceramic composite (i) comprises a ceramic and a sheet of a carbon nanotube network that has undergone strain-induced alignment, (ii) comprises a volume fraction of carbon nanotubes from 20% to 90%, and (iii) has a Young's Modulus of at least 100 GPa;
applying a sheet of a pre-preg carbon fiber reinforced polymer on the flexible ceramic composite;
curing the flexible ceramic composite and the pre-preg carbon fiber reinforced polymer sheet together to form a hybrid composite material; and
removing the hybrid composite material from the lay-up tooling surface,
wherein the first flexible ceramic composite comprises an exterior surface of the hybrid composite material.
2. The method of claim 1 , further comprising:
applying one or more sheets of non-woven carbon fiber tissue on the first flexible ceramic composite; and
curing the first flexible ceramic composite and the carbon fiber tissue together to form a second flexible ceramic composite before applying the sheet of pre-preg carbon fiber reinforced polymer on the second flexible ceramic composite.
3. The method of claim 2 , wherein the step of applying one or more sheets of non-woven carbon fiber tissue further comprises applying one or more ceramic precursors to the first flexible ceramic composite or to the one or more sheets of non-woven carbon nanotube tissue before curing the first flexible ceramic composite and the carbon nanotube tissue.
4. The method of claim 1 , further comprising applying a release agent to the lay-up tooling surface before placing thereon the layer of a flexible ceramic composite.
5. The method of claim 1 , wherein the curing occurs over a period from about 1 hour to 48 hours.
6. The method of claim 1 , wherein the curing is conducted at a temperature from about 100° C. to about 1500° C.
7. The method of claim 1 , wherein the first flexible ceramic composite has a coefficient of thermal expansion that is from about 80% to about 120% of the coefficient of thermal expansion of the pre-preg carbon fiber reinforced polymer.
8. The method of claim 1 , wherein the volume fraction of carbon nanotubes in the hybrid composite material is from about 40% to about 70%.
9. The method of claim 1 , wherein the ceramic material comprises silicon carbonitride, silicon aluminum carbonitride, or a combination thereof.
10. The method of claim 1 , wherein the carbon nanotubes of the carbon nanotube network comprise multi-walled carbon nanotubes.
11. The method of claim 1 , wherein the hybrid composite material has a tensile strength of at least about 500 MPa.
12. The method of claim 1 , wherein the hybrid composite material has an electrical conductivity of at least about 3×10 6 S·m −1 .
13. The method of claim 1 , wherein the first flexible ceramic composite is produced by a process that comprises pyrolysis of a ceramic precursor, which comprises liquid polysilazane, that has been impregnated into the carbon nanotube network that has undergone strain-induced alignment.