Optically transparent pressure-sensitive adhesive sheet, laminate, process for producing laminate, and display device with touch panel
The present invention provides an optically clear adhesive sheet using a heat-curable polyurethane composition, wherein the optically clear adhesive sheet can, when bonded to an adherend such as a glass plate, prevent the occurrence of air bubbles even at high temperature and normal humidity and maintain a stable bonded interface. The optically clear adhesive sheet of the present invention is an optically clear adhesive sheet containing: a cured product of a heat-curable polyurethane composition, the heat-curable polyurethane composition containing a polyol component and a polyisocyanate component, the polyol component having an olefin skeleton, the polyisocyanate component containing an acyclic aliphatic polyisocyanate and/or an alicyclic polyisocyanate.
1. An optically clear adhesive sheet consisting of:
a cured product of a heat-curable polyurethane composition,
the heat-curable polyurethane composition containing a polyol component and a polyisocyanate component, wherein the heat-curable polyurethane composition does not contain an tackifier,
the polyol component consisting of a polyol having an olefin skeleton, wherein the polyol having an olefin skeleton is the only polyol component in the heat-curable polyurethane composition,
the polyisocyanate component containing at least one of an acyclic aliphatic polyisocyanate, an alicyclic polyisocyanate, a modified acyclic aliphatic polyisocyanate and a modified alicyclic polyisocyanate, wherein
the modified acyclic aliphatic polyisocyanate is obtained by reacting an acyclic aliphatic polyisocyanate having an isocyanate group with an ether compound having an ethylene oxide unit,
the modified alicyclic polyisocyanate is obtained by reacting an alicyclic polyisocyanate having an isocyanate group with an ether compound having an ethylene oxide unit, and wherein
an α ratio (A/B) of the number of moles of OH groups (A) derived from the polyol component to the number of moles of NCO groups (B) derived from the polyisocyanate component is 1.3 to 1.8.
2. The optically clear adhesive sheet according to claim 1 ,
wherein the acyclic aliphatic polyisocyanate is hexamethylene diisocyanate.
3. The optically clear adhesive sheet according to claim 1 ,
wherein the heat-curable polyurethane composition further contains a plasticizer.
4. A laminate comprising:
the optically clear adhesive sheet according to claim 1 ;
a first release liner covering one surface of the optically clear adhesive sheet; and
a second release liner covering the other surface of the optically clear adhesive sheet.
5. A method for producing the laminate according to claim 4 comprising the steps of:
mixing the polyol component and the polyisocyanate component under stirring; and
pouring a liquid obtained by the mixing under stirring between he first release liner and the second release liner to cure the liquid.
6. A display device with a touchscreen comprising:
the optically clear adhesive sheet according to claim 1 ;
a display panel; and
a touchscreen.
7. The optically clear adhesive sheet according to claim 1 ,
wherein the alicyclic polyisocyanate is isophorone diisocyanate.