IP Library Granted Patent US 11,535,552
Granted Patent B2
US 11,535,552 · App. 16/077,810 · Granted Dec 27, 2022

Chemical vapor deposition process for depositing a coating and the coating formed thereby

Inventors: Lila Raj Dahal (Perrysburg, OH); David Alan Strickler (Toledo, OH)
Assignee: Pilkington Group Limited
C03C17/2456C23C16/402C23C16/405C23C16/45512C23C16/545C03C17/3417C03C2217/23C03C2218/1525C23C16/407
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Quick Facts
Patent No.
US 11,535,552
App. No.
16/077,810
Granted
Dec 27, 2022
Kind
B2
Abstract

A chemical vapor deposition process for depositing a coating comprising silicon oxide and titanium oxide is provided. A coating formed by the chemical vapor deposition process is also provided.

Claims (20)

1. A chemical vapor deposition process for depositing a coating, comprising:

providing a glass substrate;

forming a gaseous mixture comprising a silicon-containing compound, an oxygen-containing compound, a radical scavenger, and a titanium-containing compound;

feeding the gaseous mixture through a coating apparatus prior to forming the coating; and

discharging the gaseous mixture from the coating apparatus, directing the gaseous mixture toward and along the glass substrate, and reacting the mixture over the glass substrate to form the coating thereover, the coating having a refractive index of 1.48 or more;

wherein the gaseous mixture comprises 0.1 to 5% of the titanium-containing compound by volume.

2. The chemical vapor deposition process of claim 1 , wherein the coating comprises silicon oxide and titanium oxide, with a ratio of titanium to silicon of less than 1.

3. The chemical vapor deposition process of claim 1 , wherein the coating is formed directly on the glass substrate.

4. The chemical vapor deposition process of claim 2 , wherein the silicon oxide is silicon dioxide.

5. The chemical vapor deposition process of claim 2 , wherein the titanium oxide is titanium dioxide.

6. The chemical vapor deposition process of claim 1 , wherein the coating has a refractive index of 1.50 to 1.85.

7. The chemical vapor deposition process of claim 1 , wherein the glass substrate is moving at the time of forming the coating, or wherein the glass substrate is a float glass ribbon.

8. The chemical vapor deposition process of claim 1 , wherein the coating is formed at a dynamic deposition rate of 280 nm×m/min or more.

9. The chemical vapor deposition process of claim 1 , wherein the gaseous mixture is formed prior to being fed through the coating apparatus or within the coating apparatus.

10. The chemical vapor deposition process of claim 1 , wherein the silicon-containing compound is a silane compound.

11. The chemical vapor deposition process of claim 1 , wherein the oxygen-containing compound is molecular oxygen.

12. The chemical vapor deposition process of claim 1 , wherein the oxygen-containing compound is an inorganic oxygen-containing compound.

13. The chemical vapor deposition process of claim 1 , wherein the radical scavenger is ethylene or propylene.

14. The chemical vapor deposition process of claim 1 , wherein the titanium-containing compound is an inorganic titanium-containing compound.

15. The chemical vapor deposition process of claim 1 , wherein the titanium-containing compound is an organic titanium-containing compound.

Assignments (1)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Nov 11, 2019
From: DAHAL, LILA RAJ; STRICKLER, DAVID ALAN
To: PILKINGTON GROUP LIMITED
Reel/Frame 050968/0357 →
Continuity (2)
Provisional Application 62296861 · Feb 18, 2016
Related Publication 20210094868A1 · Apr 1, 2021