Method and system for battery electrode lamination using overlapped irregular shaped active material and adhesive
Systems and methods for electrode lamination using overlapped irregular shaped active material may include a battery having a cathode, an electrolyte, and an anode, with the anode including an active material on a metal current collector. The active material may include a plurality of irregularly shaped pieces bonded to the metal current collector, and may include silicon, carbon, and a pyrolyzed polymer. The active material may include more than 50% silicon by weight. The plurality of irregularly shaped pieces may be roll press laminated to the metal current collector. Gaps may remain between some of the irregularly shaped pieces of active material. The gaps may absorb strain in the active material during lithiation of the anode. The metal current collector may include a copper or nickel foil. Portions of the metal current collector not covered by active material may be protected by an adhesive or inorganic layer.
1. A battery comprising:
a cathode, an electrolyte, and an anode,
the anode comprising an active material layer on a metal current collector,
the active material layer consisting of a plurality of irregularly shaped pieces comprising silicon and pyrolyzed polymer,
wherein the plurality of irregularly shaped pieces are coupled to the metal current collector by a polymer adhesive,
wherein the plurality of irregularly shaped pieces cover a surface of the current collector with less than 100% coverage of the surface of the current collector by the plurality of irregularly shaped pieces.
2. The battery according to claim 1 , wherein the active material layer comprises more than 50% silicon by weight.
3. The battery according to claim 1 , wherein the plurality of irregularly shaped pieces are roll press laminated to the metal current collector.
4. The battery according to claim 1 , wherein gaps remain between some of the plurality of irregularly shaped pieces.
5. The battery according to claim 4 , wherein the gaps absorb strain in the active material layer during lithiation of the anode.
6. The battery according to claim 1 , wherein the metal current collector comprises a copper or nickel foil in electrical contact with the active material layer.
7. The battery according to claim 1 , wherein portions of the metal current collector not covered by the active material layer are protected by the polymer adhesive or an inorganic layer.
8. The battery according to claim 1 , wherein the electrolyte comprises a liquid, solid, or gel.
9. The battery according to claim 1 , wherein the battery comprises a lithium ion battery.
10. The battery according to claim 1 , wherein a portion of the active material layer is in direct contact with the metal current collector.
11. A method of forming a battery, the method comprising:
fabricating a battery comprising a cathode, an electrolyte, and an anode, the anode comprising an active material layer on a metal current collector,
wherein the active material layer consists of a plurality of irregularly shaped pieces comprising silicon and pyrolyzed polymer,
wherein the plurality of irregularly shaped pieces are coupled to the metal current collector using a polymer adhesive, and
wherein the plurality of irregularly shaped pieces cover a surface of the current collector with less than 100% coverage of the surface of the current collector by the plurality of irregularly shaped pieces.
12. The method according to claim 11 , wherein the active material layer comprises more than 50% silicon by weight.
13. The method according to claim 11 , comprising roll press laminating the plurality of irregularly shaped pieces to the metal current collector.
14. The method according to claim 11 , wherein gaps remain between some of the plurality of irregularly shaped pieces of active material layer.
15. The method according to claim 14 , wherein the gaps absorb strain in the active material layer during lithiation of the anode.
16. The method according to claim 11 , wherein the metal current collector comprises a copper or nickel foil in electrical contact with the active material layer.
17. The method according to claim 11 , wherein portions of the metal current collector not covered by the active material layer are protected by the polymer adhesive or an inorganic layer.
18. The method according to claim 11 , wherein the battery comprises a lithium ion battery and the electrolyte comprises a liquid, solid, or gel.
19. The method according to claim 11 , wherein a portion of the active material layer is in direct contact with the metal current collector.