IP Library Granted Patent US 11,548,955
Granted Patent B2
US 11,548,955 · App. 16/759,079 · Granted Jan 10, 2023

Component addition polymerization

Inventors: Andrew M. Savo (Cherry Hill, NJ); Alfred K. Schultz (Maple Glen, PA); Kenneth Laughlin (Maple Glen, PA); John Reffner (North Wales, PA)
Assignees: DDP Specialty Electronic Materials US, INC.; DDP Specialty Electronic Materials US 8, LLC
C08F2/18C08F12/36C08F212/08C08F212/36
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Quick Facts
Patent No.
US 11,548,955
App. No.
16/759,079
Granted
Jan 10, 2023
Kind
B2
Abstract

Provided is a collection of polymeric beads, wherein the beads comprise (i) 75 to 99% by weight, based on the weight of the bead, polymerized units of monofunctional vinyl monomer, and (ii) 1 to 25% by weight, based on the weight of the bead, polymerized units of multifunctional vinyl monomer; wherein, within each bead, the average concentration of moles of polymerized units of multifunctional vinyl monomer per cubic micrometer is MVAV; wherein, within each bead, T1000 is a sequence of 1,000 unique connected polymerized monomer units; wherein, within each T1000, MVSEQ is the weight percent polymerized units of multifunctional vinyl monomer, based on the weight of T1000; wherein MVRATIO=MVSEQ/MVAV; and wherein 90% or more of the beads by volume are uniform beads, wherein a uniform bead is a bead in which 90% or more of all T1000 sequences has MVRATIO of 1.5 or less.

Claims (13)

1. A collection of polymeric beads, wherein the beads comprise

(i) 75 to 99% by weight, based on the weight of the bead, polymerized units of monofunctional vinyl monomer, and

(ii) 1 to 25% by weight, based on the weight of the bead, polymerized units of multifunctional vinyl monomer;

wherein, within each bead, the average concentration of moles of polymerized units of multifunctional vinyl monomer per cubic micrometer is MVAV;

wherein, within each bead, T1000 is a sequence of 1,000 unique connected polymerized monomer units;

wherein, within each T1000, MVSEQ is the weight percent polymerized units of multifunctional vinyl monomer, based on the weight of T1000;

wherein MVRATIO=MVSEQ/MVAV;

and

wherein 90% or more of the beads by volume are uniform beads, wherein a uniform bead is a bead in which 90% or more of all T1000 sequences has MVRATIO of 1.5 or less.

2. The collection of polymeric beads of claim 1 , wherein, in 90% or more of the beads by volume, 90% or more of all T1000 sequences has MVRATIO of 1.25 or less.

3. The collection of polymeric beads of claim 1 , wherein the monofunctional monomer comprises styrene.

4. The collection of polymeric beads of claim 1 , wherein the multifunctional monomer comprises divinylbenzene.

5. The collection of polymeric beads of claim 1 , wherein 35% or less of the T1000 sequences have MVRATIO of 0.5 or less.

Assignments (2)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Oct 4, 2022
From: LAUGHLIN, KENNETH BRUCE
To: DDP SPECIALTY ELECTRONIC MATERIALS US 5, LLC.
Reel/Frame 061303/0900 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Oct 4, 2022
From: SCHULTZ, ALFRED; REFFNER, JOHN; SAMMLER, ROBERT; SAVO, ANDREW M.
To: DUPONT SPECIALTY PRODUCTS USA, LLC.
Reel/Frame 061304/0021 →
Continuity (2)
Provisional Application 62584216 · Nov 10, 2017
Related Publication 20200325251A1 · Oct 15, 2020