Electrode mixture manufacturing method and electrode mixture
View Patent ↗The present invention provides: an electrode mixture manufacturing method comprising the processes of introducing a first binder, an electrode active material, and a conductive material into an extruder, performing a first mixing of the first binder, the electrode active material, and the conductive material in the extruder, additionally introducing a second binder into the extruder and performing a second mixing, and yielding an electrode mixture resulting from the first mixing and the second mixing; an electrode mixture manufactured thereby; and an electrode manufacturing method using the electrode mixture.
1. A method for manufacturing an electrode mixture for a secondary battery, comprising:
injecting a first binder, an electrode active material and a conductive material into an extruder;
a first mixing process of mixing the first binder, the electrode active material and the conductive material in the extruder;
a second mixing process of further adding a second binder to the extruder; and
obtaining an electrode mixture derived from the first mixing process and the second mixing process;
wherein a content of the first binder is from 2.1% to 2.4% based on a total weight of the electrode mixture, and
wherein a content of the second binder is from 0.8% to 1% based on the total weight of the electrode mixture.
2. The method of claim 1 , wherein:
the first mixing process comprises: generating a granular first powder as a first particle and/or a second particle is attached to the first binder,
wherein the first particle is formed of the electrode active material and the second particle is formed of the conductive material; and
the second mixing process comprises: a network physically connecting the first powder as the second binder becomes fibrous.
3. The method of claim 2 , wherein the granular first powder is dispersed in the first mixing process and is bonded to the network during the second mixing process to form a lump of electrode mixture having a solid content of 100%.
4. The method of claim 3 , wherein a plurality of short fibers form the network as shear stress is formed in the second binder by the extruder, and
wherein the plurality of short fibers are connected to the first binder and/or are connected directly to the granular first powder.
5. The method of claim 1 , wherein the second binder is polytetrafluoroethylene (PTFE).
6. The method of claim 1 , wherein the first binder is one or more selected from the group consisting of polyethylene oxide (PEO), polyvinylidene fluoride (PVdF), and polyvinylidene fluoride-co-hexafluoropropylene (PVDF-HFP).
7. The method of claim 1 , wherein the electrode active material is a positive electrode active material, and
wherein, in the first and second mixing processes, the extruder is operated at a speed of from 30 rpm to 70 rpm under a temperature of from 20 to 60 degrees Celsius.
8. The method of claim 1 , wherein the electrode active material is a negative electrode active material, and
wherein, in the first and second mixing processes, the extruder is operated at a speed of from 30 rpm to 70 rpm under a temperature of from 80 to 120 degrees Celsius.
9. The method of claim 1 , further comprising rolling the obtained electrode mixture to produce an electrode mixture in the form of a film having an average thickness of from 1 micrometer to 100 micrometers.