Lubricating oil composition
A lubricating oil composition is provided which comprises (a) greater than 50 wt. % of a base oil of lubricating viscosity; and (b) 0.1 to 20 wt. % of an alkyl-substituted hydroxyaromatic carboxylic acid, wherein the alkyl substituent of the alkyl-substituted hydroxyaromatic carboxylic acid has from 12 to 40 carbon atoms; wherein the lubricating oil composition is a monograde lubricating oil composition meeting specifications for SAE J300 revised January 2015 requirements for a SAE 20, 30, 40, 50, or 60 monograde engine oil, and has a TBN of 5 to 200 mg KOH/g, as determined by ASTM D2896.
1. A lubricating oil composition comprising (a) greater than 50 wt. % of a base oil of lubricating viscosity; and (b) 0.1 to 20 wt. % of an ashless alkyl-substituted hydroxyaromatic carboxylic acid, wherein the alkyl substituent of the ashless alkyl-substituted hydroxyaromatic carboxylic acid has from 12 to 40 carbon atoms; wherein the lubricating oil composition is a monograde lubricating oil composition meeting specifications for SAE BOO revised January 2015 requirements for a SAE 20, 30, 40, 50, or 60 monograde engine oil, and has a TBN of 5 to 200 mg KOH/g, as determined by ASTM D2896.
2. The lubricating oil composition of claim 1 , wherein the alkyl substituent of the ashless alkyl-substituted hydroxyaromatic carboxylic acid is a residue derived from an alpha-olefin having from 14 to 28 carbon atoms per molecule.
3. The lubricating oil composition of claim 1 , wherein the alkyl substituent of the ashless alkyl-substituted hydroxyaromatic carboxylic acid is a residue derived from an alpha-olefin having from 20 to 24 carbon atoms per molecule.
4. The lubricating oil composition of claim 1 , wherein the alkyl substituent of the ashless alkyl-substituted hydroxyaromatic carboxylic acid is a residue derived from an alpha-olefin having from 20 to 28 carbon atoms per molecule.
5. A lubricating oil composition as in any one of claims 2 , 3 , and 4 , in which the alpha-olefin is a normal alpha-olefin, an isomerized normal alpha-olefin, or a mixture thereof.
6. The lubricating oil composition of claim 1 , wherein an amount of the ashless alkyl-substituted hydroxybenzoic acid is in a range of 1.0 to 5.0 wt. % of the lubricating oil composition.
7. The lubricating oil composition of claim 1 , wherein the lubricating oil composition has a TBN in one of the following ranges: 5 to 10 mg KOH/g, 15 to 150 mg KOH/g, 20 to 80 mg KOH/g, 30 to 100 mg KOH/g, 30 to 80 mg KOH/g, 60 to 100 mg KOH/g, 60 to 150 mg KOH/g.
8. The lubricating oil composition of claim 1 , further comprising one or more of a metal detergent, a dispersant, an antiwear agent, an antioxidant, a friction modifier, a corrosion inhibitor, a rust inhibitor, a demulsifier, a foam inhibitor, a viscosity modifier, a pour point depressant, a non-ionic surfactant, and a thickener.
9. A method of lubricating an internal combustion engine comprising supplying to the internal combustion engine the lubricating oil composition of claim 1 .
10. The method of claim 9 , wherein the internal combustion engine is a compression-ignited engine.
11. The method of claim 10 , wherein the compression-ignited engine is a 4-stroke engine operated at 250 to 1100 rpm.
12. The method of claim 10 , wherein the compression ignited engine is a 2-stroke engine operated at 200 rpm or less.
13. The method of claim 10 , wherein the compression-ignited engine is fueled with a residual fuel, a marine residual fuel, a low sulfur marine residual fuel, a marine distillate fuel, a low sulfur marine distillate fuel, a high sulfur fuel, or a gaseous fuel.
14. The lubricating oil composition of claim 1 , wherein an amount of the ashless alkyl-substituted hydroxyaromatic carboxylic acid is in a range of 1.0 to 5.0 wt. % of the lubricating oil composition and wherein the alkyl substituent of the ashless alkyl-substituted hydroxyaromatic carboxylic acid is a residue derived from an alpha-olefin having from 20 to 28 carbon atoms per molecule.