Filter device, purification device, chemical solution production method
A filtering device is for obtaining a chemical liquid by purifying a liquid to be purified and has an inlet portion, an outlet portion, a filter A, a filter B different from the filter A, and a flow path extending from the inlet portion to the outlet portion, in which the filter A and the filter B are arranged in series between the inlet portion and the outlet portion and have, and the filter A is selected from the group consisting of predetermined filters A1, A2, and A3.
1. A filtering device for obtaining a chemical liquid by purifying a liquid to be purified, comprising:
an inlet portion;
an outlet portion;
a filter A;
at least three filters B different from the filter A; and
a flow path extending from the inlet portion to the outlet portion,
wherein the filter A and the filters B are arranged in series between the inlet portion and the outlet portion,
the filter A is selected from the group consisting of a filter A1, a filter A2, and a filter A3,
the filter A1 has a porous base material made of polytetrafluoroethylene and a coating layer which is disposed to cover the porous base material and contains a fluorinated ionomer,
the fluorinated ionomer contains
a fluorinated monomer unit containing an ethylene group and a functional group which is convertible into a hydrophilic group selected from the group consisting of —SO 2 F, —COOR, —COF, and a combination of these, R is a C 1 -C 20 alkyl radical or a C 6 -C 20 aryl radical;
a monomer unit derived from at least one bis-olefin selected from the group consisting of Formulas (OF-1), (OF-2), and (OF-3); and
at least one kind of atom selected from the group consisting of an iodine atom and a bromine atom,
in Formula (OF-1), j is an integer of 2 to 10, and R1, R2, R3, and R4 may be the same as or different from each other and each represent H, F, or a C 1 -C 5 alkyl group, a perfluoroalkyl group, or a fluoroalkyl group,
in Formula (OF-2), a plurality of A's may be the same as or different from each other and are each independently selected from the group consisting of F, Cl, and H, a plurality of B's may be the same as or different from each other and are each independently selected from the group consisting of F, Cl, H, and ORB, RB is a branched or linear alkyl radical capable of being at least partially fluorinated or chlorinated, E is a divalent group which is capable of being inserted into an ether bond, is fluorinated as necessary, and has 2 to 10 carbon atoms,
in Formula (OF-3), E, A, and B have the same definition as E, A, and B in Formula (OF-2), R5, R6, and R7 may be the same as or different from each other and each represent H, F, a C 1 -C 5 alkyl group, a perfluoroalkyl group, or a fluoroalkyl group,
the filter A2 contains a copolymer having a repeating unit based on tetrafluoroethylene and another repeating unit,
the filter A3 is a laminated structure having a first layer which consists of a porous base material made of polytetrafluoroethylene having a first hydrophilic group on a surface thereof and a second layer which is disposed on the first layer and consists of a porous base material made of polytetrafluoroethylene having a second hydrophilic group different from the first hydrophilic group on a surface thereof,
the filters B includes at least two filters BU disposed on an upstream side of the filter A on the flow path,
the at least two filters BU have a pore size larger than a pore size of the filter A,
one of the at least two filters BU contains a polypropylene not having an ion exchange group or polyethylene not having an ion exchange group,
the other of the at least two filters BU contains a resin having an ion exchange group which is an imide group,
the filters B includes at least a filter BD disposed on a downstream side of the filter A on the flow path, and
at least the one filter BD has a pore size smaller than a pore size of the filter A.
2. The filtering device according to claim 1 ,
wherein each of the first hydrophilic group and the second hydrophilic group is at least one kind of hydrophilic group selected from the group consisting of a polyether group, a hydroxyl group, a thioether group, a thiol group, a quaternary ammonium group, a carboxylic acid group, a sulfonic acid group, and a group obtained by combining these.
3. The filtering device according to claim 1 ,
wherein the at least two filters BU have a pore size equal to or greater than 20 nm.
4. The filtering device according to claim 1 , further comprising:
a return flow path capable of returning the liquid to be purified to an upstream side of a first reference filter from a downstream side of the first reference filter,
wherein the first reference filter consists of at least one kind of filter selected from the group consisting of the filter A and the filter BU.
5. The filtering device according to claim 1 ,
wherein at least the one filter BD has a pore size equal to or smaller than 20 nm.
6. The filtering device according to claim 1 ,
wherein the filter BD contains at least one kind of compound selected from the group consisting of polyolefin, polyamide, polyfluorocarbon, polystyrene, polysulfone, and polyethersulfone.
7. The filtering device according to claim 1 , further comprising:
a return flow path capable of returning the liquid to be purified to an upstream side of a second reference filter from a downstream side of the second reference filter,
wherein the second reference filter consists of at least one kind of filter selected from the group consisting of the filter A and the filter BD.
8. The filtering device according to claim 1 , further comprising:
a tank which is disposed in series with the filter A on the flow path.
9. The filtering device according to claim 8 , further comprising:
a filter C having a pore size equal to or greater than 20 nm that is disposed in series with the tank on an upstream side of the tank in the flow path.
10. The filtering device according to claim 1 ,
wherein the chemical liquid is at least one kind of chemical liquid selected from the group consisting of a developer, a rinsing solution, a wafer washing solution, a line washing solution, a prewet solution, a wafer rinsing solution, a resist solution, a solution for forming an underlayer film, a solution for forming an overlayer film, and a solution for forming a hardcoat, or at least one kind of chemical liquid selected from the group consisting of an aqueous developer, an aqueous rinsing solution, a peeling solution, a remover, an etching solution, an acidic washing solution, and a phosphoric acid, and a phosphoric acid-aqueous hydrogen peroxide mixture.
11. A purification device comprising:
the filtering device according to claim 1 ; and
at least one distiller connected to the inlet portion of the filtering device.
12. The purification device according to claim 11 ,
wherein the at least the one distiller includes a plurality of distillers connected in series.
13. A method for manufacturing a chemical liquid by purifying a liquid to be purified, comprising:
a filtration step of purifying the liquid to be purified by using the filtering device according to claim 1 so as to obtain a chemical liquid.
14. The method for manufacturing a chemical liquid according to claim 13 , further comprising:
a filter washing step of washing the filter A and the filter B before the filtration step.
15. The method for manufacturing a chemical liquid according to claim 13 , further comprising:
a device washing step of washing a liquid contact portion of the filtering device before the filtration step.
16. A method for manufacturing a chemical liquid by purifying a liquid to be purified, comprising:
a step of filtering the liquid to be purified by using;
a filter A including a porous base material which is made of polyfluorocarbon and a coating layer which is disposed to cover the porous base material and contains a resin having a hydrophilic group; and
at least three filters B different from the filter A so as to obtain a chemical liquid,
wherein the filters B include at least two filters BU disposed on an upstream side of the filter A on a flow path,
the at least two filters BU have a pore size larger than a pore size of the filter A,
one of the at least two filters BU contains a polypropylene not having an ion exchange group or polyethylene not having an ion exchange group
the other of the at least two filters BU contains a resin having an ion exchange group which is an imide group,
the filters B includes at least a filter BD disposed on a downstream side of the filter A on the flow path, and
at least the one filter BD has a pore size smaller than a pore size of the filter A.
17. A filtering device for obtaining a chemical liquid by purifying a liquid to be purified, comprising:
an inlet portion;
an outlet portion;
a filter A;
at least one filter B different from the filter A;
a flow path extending from the inlet portion to the outlet portion; and
a return flow path,
wherein the filter A and the filter B are arranged in series between the inlet portion and the outlet portion,
the filter A is selected from the group consisting of a filter A1, a filter A2, and a filter A3,
the filter A1 has a porous base material made of polytetrafluoroethylene and a coating layer which is disposed to cover the porous base material and contains a fluorinated ionomer,
the fluorinated ionomer contains
a fluorinated monomer unit containing an ethylene group and a functional group which is convertible into a hydrophilic group selected from the group consisting of —SO 2 F, —COOR, —COF, and a combination of these, R is a C 1 -C 20 alkyl radical or a C 6 -C 20 aryl radical;
a monomer unit derived from at least one bis-olefin selected from the group consisting of Formulas (OF-1), (OF-2), and (OF-3); and
at least one kind of atom selected from the group consisting of an iodine atom and a bromine atom,
in Formula (OF-1), j is an integer of 2 to 10, and R1, R2, R3, and R4 may be the same as or different from each other and each represent H, F, or a C 1 -C 5 alkyl group, a perfluoroalkyl group, or a fluoroalkyl group,
in Formula (OF-2), a plurality of A's may be the same as or different from each other and are each independently selected from the group consisting of F, Cl, and H, a plurality of B's may be the same as or different from each other and are each independently selected from the group consisting of F, Cl, H, and ORB, RB is a branched or linear alkyl radical capable of being at least partially fluorinated or chlorinated, E is a divalent group which is capable of being inserted into an ether bond, is fluorinated as necessary, and has 2 to 10 carbon atoms,
in Formula (OF-3), E, A, and B have the same definition as E, A, and B in Formula (OF-2), R5, R6, and R7 may be the same as or different from each other and each represent H, F, a C 1 -C 5 alkyl group, a perfluoroalkyl group, or a fluoroalkyl group,
the filter A2 contains a copolymer having a repeating unit based on tetrafluoroethylene and another repeating unit, and
the filter A3 is a laminated structure having a first layer which consists of a porous base material made of polytetrafluoroethylene having a first hydrophilic group on a surface thereof and a second layer which is disposed on the first layer and consists of a porous base material made of polytetrafluoroethylene having a second hydrophilic group different from the first hydrophilic group on a surface thereof,
the filter B includes at least one filter BU disposed on an upstream side of the filter A on the flow path, and
the return path is capable of returning the liquid to be purified to a downstream side of the filter BU from a downstream side of the filter A.
18. A filtering device for obtaining a chemical liquid by purifying a liquid to be purified, comprising:
an inlet portion;
an outlet portion;
a filter A;
at least one filter B different from the filter A;
a flow path extending from the inlet portion to the outlet portion; and
a return flow path,
wherein the filter A and the filter B are arranged in series between the inlet portion and the outlet portion,
the filter A is selected from the group consisting of a filter A1, a filter A2, and a filter A3,
the filter A1 has a porous base material made of polytetrafluoroethylene and a coating layer which is disposed to cover the porous base material and contains a fluorinated ionomer,
the fluorinated ionomer contains
a fluorinated monomer unit containing an ethylene group and a functional group which is convertible into a hydrophilic group selected from the group consisting of —SO 2 F, —COOR, —COF, and a combination of these, R is a C 1 -C 20 alkyl radical or a C 6 -C 20 aryl radical;
a monomer unit derived from at least one bis-olefin selected from the group consisting of Formulas (OF-1), (OF-2), and (OF-3); and
at least one kind of atom selected from the group consisting of an iodine atom and a bromine atom,
in Formula (OF-1), j is an integer of 2 to 10, and R1, R2, R3, and R4 may be the same as or different from each other and each represent H, F, or a C 1 -C 5 alkyl group, a perfluoroalkyl group, or a fluoroalkyl group,
in Formula (OF-2), a plurality of A's may be the same as or different from each other and are each independently selected from the group consisting of F, Cl, and H, a plurality of B's may be the same as or different from each other and are each independently selected from the group consisting of F, Cl, H, and ORB, RB is a branched or linear alkyl radical capable of being at least partially fluorinated or chlorinated, E is a divalent group which is capable of being inserted into an ether bond, is fluorinated as necessary, and has 2 to 10 carbon atoms,
in Formula (OF-3), E, A, and B have the same definition as E, A, and B in Formula (OF-2), R5, R6, and R7 may be the same as or different from each other and each represent H, F, a C 1 -C 5 alkyl group, a perfluoroalkyl group, or a fluoroalkyl group,
the filter A2 contains a copolymer having a repeating unit based on tetrafluoroethylene and another repeating unit,
the filter A3 is a laminated structure having a first layer which consists of a porous base material made of polytetrafluoroethylene having a first hydrophilic group on a surface thereof and a second layer which is disposed on the first layer and consists of a porous base material made of polytetrafluoroethylene having a second hydrophilic group different from the first hydrophilic group on a surface thereof,
the filter B includes at least a filter BD disposed on a downstream side of the filter A on the flow path, and
the return path is capable of returning the liquid to be purified to a downstream side of the filter A from a downstream side of the filter BD.
19. A filtering device for obtaining a chemical liquid by purifying a liquid to be purified, comprising:
an inlet portion;
an outlet portion;
a filter A3;
at least one filter B different from the filter A3; and
a flow path extending from the inlet portion to the outlet portion,
wherein the filter A3 and the filter B are arranged in series between the inlet portion and the outlet portion,
the filter A3 is a laminated structure having a first layer which consists of a porous base material made of polytetrafluoroethylene having a first hydrophilic group on a surface thereof and a second layer which is disposed on the first layer and consists of a porous base material made of polytetrafluoroethylene having a second hydrophilic group different from the first hydrophilic group on a surface thereof, and
each of the first hydrophilic group and the second hydrophilic group is at least one kind of hydrophilic group selected from the group consisting of a polyether group, a thioether group, a thiol group, and a group obtained by combining these.
20. A method for manufacturing a chemical liquid by purifying a liquid to be purified, comprising:
a step of filtering the liquid to be purified by using;
a filter A including a porous base material which is made of polyfluorocarbon and a coating layer which is disposed to cover the porous base material and contains a resin having a hydrophilic group;
a filter B different from the filter A so as to obtain a chemical liquid; and
a return flow path,
wherein the filter B includes at least one filter BU disposed on an upstream side of the filter A on a flow path, and
the return path is capable of returning the liquid to be purified to a downstream side of the filter BU from a downstream side of the filter A.
21. A method for manufacturing a chemical liquid by purifying a liquid to be purified, comprising:
a step of filtering the liquid to be purified by using;
a filter A including a porous base material which is made of polyfluorocarbon and a coating layer which is disposed to cover the porous base material and contains a resin having a hydrophilic group;
a filter B different from the filter A so as to obtain a chemical liquid; and
a return flow path,
wherein the filter B includes at least a filter BD disposed on a downstream side of the filter A on the flow path, and
the return path is capable of returning the liquid to be purified to a downstream side of the filter A from a downstream side of the filter BD.
22. A method for manufacturing a chemical liquid by purifying a liquid to be purified, comprising:
a step of filtering the liquid to be purified by using;
a filter A3 including a porous base material which is made of polyfluorocarbon and a coating layer which is disposed to cover the porous base material and contains a resin having a hydrophilic group; and
a filter B different from the filter A3 so as to obtain a chemical liquid,
wherein the filter A3 is a laminated structure having a first layer which consists of a porous base material made of polytetrafluoroethylene having a first hydrophilic group on a surface thereof and a second layer which is disposed on the first layer and consists of a porous base material made of polytetrafluoroethylene having a second hydrophilic group different from the first hydrophilic group on a surface thereof, and
each of the first hydrophilic group and the second hydrophilic group is at least one kind of hydrophilic group selected from the group consisting of a polyether group, a thioether group, a thiol group, and a group obtained by combining these.