Carbon mineralization using hyaloclastite, volcanic ash and pumice mineral and an alkaline solution, cement and concrete using same and method of making and using same
View Patent ↗The invention comprises a method of mineralization of carbon dioxide. The method comprises delivering hyaloclastite, a volcanic glass or pumice to a mill capable of reducing the particle size of the hyaloclastite, a volcanic glass or pumice; processing the hyaloclastite, a volcanic glass or pumice in the mill so that the processed hyaloclastite, a volcanic glass or pumice has a volume-based mean particle size of less than or equal to 40 μm; and exposing the hyaloclastite, a volcanic glass or pumice to carbon dioxide in gaseous, liquid or solid form during or after the particle reduction process. Optionally a carbon dioxide sorbent or carbonation enhancing agent is added to the hyaloclastite pozzolan or mineral during the grinding or post-grinding process and combined with carbon dioxide during grinding or post grinding.
1. A method of mineralizing carbon dioxide comprising:
combining a carbonation aid for facilitating the conversion of one or more of CaO, MgO, Na 2 O, K 2 O or FeO to a carbonate or a CO 3 containing mineral in the presence of CO 2 with basaltic hyaloclastite or intermediate basaltic hyaloclastite; and
exposing the carbonation aid and the basaltic hyaloclastite or intermediate basaltic hyaloclastite to carbon dioxide in gaseous, liquid or solid form, wherein the carbon dioxide gas is at a concentration greater than its atmospheric concentration.
2. The method of claim 1 , wherein the carbonation aid is an amine, an ammonium salt, a metal-oxide framework, an enzyme, an amino acid, a quinone, an ionic liquid, a porous organic polymer, a covalent-organic framework or combinations or mixtures thereof.
3. The method of claim 2 , wherein the basaltic hyaloclastite or intermediate basaltic hyaloclastite has a mean particle size less than or equal to approximately 40 μm.
4. The method of claim 2 , wherein the basaltic hyaloclastite or intermediate basaltic hyaloclastite has a volume-based mean particle size of less than or equal to 20 μm.
5. The method of claim 2 , wherein the basaltic hyaloclastite or intermediate basaltic hyaloclastite has a volume-based mean particle size of less than or equal to 10 μm.
6. A method of mineralizing carbon dioxide comprising:
combining a carbon dioxide sorbent microporous material for facilitating the conversion of one or more of CaO, MgO, Na 2 O, K 2 O or FeO to a carbonate or a CO 3 containing mineral in the presence of CO 2 with basaltic hyaloclastite or intermediate hyaloclastite; and
exposing the carbon dioxide sorbent microporous material and the basaltic hyaloclastite or intermediate basaltic hyaloclastite to carbon dioxide in gaseous, liquid or solid form, wherein the carbon dioxide gas is at a concentration greater than its atmospheric concentration.
7. The method of claim 6 , wherein the carbon dioxide sorbent microporous material is a metal-oxide framework, an activated microporous carbon material, a carbon nanotube, graphite, graphene, a zeolite, a porous organic polymer, a covalent-organic framework or combinations or mixtures thereof.
8. The method of claim 7 , wherein the basaltic hyaloclastite or intermediate basaltic hyaloclastite has a mean particle size less than or equal to approximately 40 μm.
9. The method of claim 7 , wherein the basaltic hyaloclastite or intermediate basaltic hyaloclastite has a volume-based mean particle size of less than or equal to 20 μm.
10. The method of claim 7 , wherein the basaltic hyaloclastite or intermediate basaltic hyaloclastite has a volume-based mean particle size of less than or equal to 10 μm.
11. A method of mineralizing carbon dioxide comprising:
exposing a carbonation aid to carbon dioxide in gaseous, liquid or solid form, wherein the carbon dioxide gas is at a concentration greater than its atmospheric concentration and wherein the carbonation aid facilitates the conversion of one or more of CaO, MgO, Na 2 O, K 2 O or FeO to a carbonate or a CO 3 containing mineral in the presence of CO 2 ; and
combining the carbonation aid with basaltic hyaloclastite or intermediate basaltic hyaloclastite.
12. The method of claim 11 , wherein the carbonation aid is an amine, an ammonium salt, a metal-oxide framework, an enzyme, an amino acid, a quinone, an ionic liquid, a porous organic polymer, a covalent-organic framework or combinations or mixtures thereof.
13. The method of claim 12 , wherein the basaltic hyaloclastite or intermediate basaltic hyaloclastite has a mean particle size less than or equal to approximately 40 μm.
14. The method of claim 12 , wherein the basaltic hyaloclastite or intermediate basaltic hyaloclastite has a volume-based mean particle size of less than or equal to 20 μm.
15. The method of claim 12 , wherein the basaltic hyaloclastite or intermediate basaltic hyaloclastite has a volume-based mean particle size of less than or equal to 10 μm.
16. A method of mineralizing carbon dioxide comprising:
exposing a carbon dioxide sorbent microporous material to carbon dioxide in gaseous, liquid or solid form, wherein the carbon dioxide gas is at a concentration greater than its atmospheric concentration, wherein the carbon dioxide sorbent microporous material facilitates the conversion of one or more of CaO, MgO, Na 2 O, K 2 O or FeO to a carbonate or a CO 3 containing mineral in the presence of CO 2 ; and
combining the carbon dioxide sorbent microporous material with basaltic hyaloclastite or intermediate basaltic hyaloclastite.
17. The method of claim 16 , wherein the carbon dioxide sorbent microporous material is a metal-oxide framework, an activated microporous carbon material, a carbon nanotube, graphite, graphene, a zeolite, a porous organic polymer, a covalent-organic framework or combinations or mixtures thereof.
18. The method of claim 17 , wherein the basaltic hyaloclastite or intermediate basaltic hyaloclastite has a mean particle size less than or equal to approximately 40 μm.
19. The method of claim 17 , wherein the basaltic hyaloclastite or intermediate basaltic hyaloclastite has a volume-based mean particle size of less than or equal to 20 μm.
20. The method of claim 17 , wherein the basaltic hyaloclastite or intermediate basaltic hyaloclastite has a volume-based mean particle size of less than or equal to 10 μm.