Polyurethane polymer having a hardness of less than or equal to 60 Shore A
The present invention relates to a novel thermoplastically processible polyurethane polymer having a hardness of ≤60 Shore A, to compositions containing this polyurethane polymer, to the uses thereof and to articles containing this polyurethane polymer.
1. A thermoplastically processible polyurethane polymer having a hardness of ≤60 Shore A, obtained by reacting the following components comprising:
(A) one or more essentially linear polyether polyols and/or one or more polyester polyols which are free of units derived from succinic acid, where a total amount of component (A) has an average molecular weight in a range from 500 g/mol to 5000 g/mol, Mn having been calculated from an OH number determined according to DIN53240,
(B) one or more diisocyanates comprising 2-methyl-1,5-diisocyanatopentane, 1,4-diisocyanatobutane, 1,5-diisocyanatopentane, 1,6-diisocyanatohexane, 2,2,4-trimethyl-1,6-diisocyanatohexane, 2,4,4-trimethyl-1,6-diisocyanatohexane, or diphenylmethane diisocyanate isomer mixtures having a diphenylmethane 4,4′-diisocyanate content of >96% by weight,
(C) one or more linear diols having a molecular weight of 62 g/mol to 500 g/mol,
(D) optionally in the presence of one or more catalysts,
(E) optionally in the presence of one or more additives, auxiliaries, or a combination thereof, and
(F) optionally in the presence of one or more monofunctional chain terminators, wherein the reaction is performed in a solvent-free fashion and comprises:
1) providing and reacting a mixture made up of the total amount of component (A), a portion of component (B) and optionally a portion or a total amount of component (D), component (E), component (F), or a combination thereof, to give an NCO-functional prepolymer, wherein there is a molar ratio of component (B) to component (A) in the range from 1.1:1.0 to 5.0:1.0,
2) Reacting the NCO-functional prepolymer with a total amount of component (C) to obtain an OH-functional prepolymer, optionally in the presence of a further portion of component (D), component (E), component (F), or a combination thereof
3) Reacting the OH-functional prepolymer with a remaining amount of component (B) and any remaining amount of component (D), component (E), component (F), or a combination thereof to obtain the thermoplastically processible polyurethane, wherein during all process steps there is a molar ratio of component (B) to a sum total of component (A) and component (C) in a range from 0.9:1.0 to 1.2:1.0.
2. The thermoplastically processible polyurethane polymer according to claim 1 , wherein component (A) comprises polyester diols having a melting temperature of 50° C., polyether polyols, or mixtures of at least 2 of these.
3. The thermoplastically processible polyurethane polymer according to claim 1 , wherein component (B) comprises 2-methyl-1,5-diisocyanatopentane, 1,6-diisocyanatohexane, 2,2,4-trimethyl-1,6-diisocyanatohexane, diphenylmethane diisocyanate isomer mixtures having a diphenylmethane 4,4′-diisocyanate content of >96% by weight, or mixtures of at least 2 of these.
4. The thermoplastically processible polyurethane polymer according to claim 1 , wherein component (C) comprises ethane-1,2-diol, butane-1,4-diol, hexane-1,6-diol, 1,4-di(hydroxyethyl)hydroquinone, cyclobutane-1,3-diol, or mixtures of at least 2 of these.
5. The thermoplastically processible polyurethane polymer according to claim 1 , wherein the thermoplastically processible polyurethane polymer has a hardness in a range from 35 Shore A to 60 Shore A as determined in accordance with DIN ISO 7619 1.
6. A plasticizer-free composition comprising at least one thermoplastically processible polyurethane polymer having a hardness of ≤60 Shore A according to claim 1 and an additive.
7. A seal, comprising a thermoplastically processible polyurethane polymer having a hardness of ≤60 Shore A according to claim 1 .
8. The seal according to claim 7 , wherein the seal is a directly injection-molded on housing seal of an electrical or electronic device and/or an extruding sealing profile.
9. A seal comprising a plasticizer-free composition according to claim 6 .
10. The seal according to claim 9 , wherein the seal is a directly the seal is a directly injection-molded-on housing seal of an electrical or electronic device and/or an extruded sealing profile.
11. A vibration damper, vibration isolator, or connection isolator, comprising a thermoplastically processible polyurethane polymer having a hardness of ≤60 Shore A according to claim 1 .
12. The vibration damper, vibration isolator, or connection isolator according to claim 11 , wherein the vibration damper, vibration isolator, or connection isolator is a foot for an electrical or electronic device, a machine foot, a corner and/or edge protector, a damper for the strings of a tennis and/or squash racket, a soft component for a protective case of a mobile telephone, or a foot for a suitcase, a sports bag or a leisure bag.
13. A vibration damper, vibration isolator, or connection isolator comprising a plasticizer-free composition according to claim 6 .
14. The vibration damper, vibration isolator, or connection isolator according to claim 13 , wherein the vibration damper, the vibration isolator, or the connection isolator is a foot for an electrical or electronic device, a machine foot, a corner and/or edge protector, a damper for the strings of a tennis and/or a squash rackets, a soft component for a protective case of a mobile telephone, or a foot for a suitcase, a sports bag, or a leisure bag.
15. A grip, comprising a thermoplastically processible polyurethane polymer having a hardness of ≤60 Shore A according to claim 1 .
16. The grip according to claim 15 , wherein the grip is part of a hand-held device, an electrical device, sports equipment, an electronic device, a suitcase, a sports bag, a leisure bag, a vehicle, a bicycle, a tool, a container, or a writing implement.
17. A grip comprising a plasticizer-free composition according to claim 6 .
18. The grip according to claim 17 , wherein the grip is a part of a hand-held device, an electrical device, sports equipment, an electronic device, a suitcase, a sports bag, a leisure bag, a vehicle, a bicycle, a tool, a container, and/or a writing implement.
19. A film, yarn, or non-woven fabric comprising a thermoplastically processible polyurethane polymer having a hardness of ≤60 Shore A according to claim 1 .
20. The film, yarn, or non-woven fabric according to claim 19 , wherein the film, the yarn, or the non-woven fabric is part of a shoe upper, clothing, or synthetic leather for furniture or automobile interior applications.
21. The film, yarn, or non-woven fabric to claim 19 , wherein the film is a film which is or has been insert-moulded with hard thermoplastics, or back-foamed with PU foam, or is part of a layer composite.
22. A film, yarn, or non-woven fabric comprising a plasticizer-free composition according to claim 6 .
23. The film, yarn, or non-woven fabric according to claim 22 , wherein the film, the yarn, or the non-woven material is part of a shoe upper, clothing, or synthetic leather for furniture or automobile interior applications.
24. The film, yarn, or non-woven fabric to claim 22 , wherein the film is or has been insert-moulded with hard thermoplastics, or back-foamed with PU foam, or is part of a layer composite.