IP Library Granted Patent US 12,168,739
Granted Patent B2
US 12,168,739 · App. 17/813,924 · Granted Dec 17, 2024

Method of manufacturing adhesive member, method of manufacturing display device including the same, and display device manufactured by the method of manufacturing display device

Inventor: Tetsuya Fujiwara (Yokohma, JP)
Assignee: SAMSUNG DISPLAY CO., LTD.
C09J133/10C09J7/22C09J175/04G02B1/14C09J2203/326C09J2301/408C09J2301/416G06F1/1652
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Quick Facts
Patent No.
US 12,168,739
App. No.
17/813,924
Granted
Dec 17, 2024
Kind
B2
Abstract

A method of manufacturing an adhesive member includes providing, for a substrate, a resin composition having a viscosity of about 5 cP to about 50 cP, as measured according to JISK2283 method, at about 25° C. The resin composition is exposed to a first light to form a preliminary adhesive member having a curing rate of about 80% to about 98%. The preliminary adhesive member is exposed to a second light having a light integral/dose that is more than that of the first light to form an adhesive member. The preliminary adhesive member may have a loss tangent (tan δ) of about 0.2 to about 0.6 and may have a glass transition temperature of about −70° C. to −30° C. Accordingly, the preliminary adhesive member and adhesive member formed by the method of manufacturing an adhesive member may exhibit increased reliability.

Claims (26)

1. A method of manufacturing an adhesive member, comprising:

providing, on a substrate, a resin composition having a viscosity of about 5 cP to about 50 cP (exclusive of 50), as measured according to a JISK2283 method, at about 25° C.;

exposing the resin composition to a first light to form a preliminary adhesive member having a curing rate of about 80% to about 98% (exclusive of 80 and 98); and

exposing the preliminary adhesive member to a second light having a light integral that is greater than a light integral of the first light to form an adhesive member,

wherein the preliminary adhesive member has a loss tangent (tan δ) of about 0.2 to about 0.6 (exclusive of 0.6), and the adhesive member has a glass transition temperature of about −70° C. to about −30° C. (exclusive of −30).

2. The method of claim 1 , wherein the resin composition is provided by an inkjet printing method or a dispensing method.

3. The method of claim 1 , wherein the resin composition includes at least one (meth)acrylate monomer containing a (meth)acryloyl group, at least one urethane (meth)acrylate oligomer, and at least one photoinitiator.

4. The method of claim 3 , wherein the curing rate of the preliminary adhesive member satisfies Equation 1 below:

Z 1 =[( X 1 −Y 1 )/ X 1 ]×100%  [Equation 1]

wherein, in Equation 1 above,

X 1 is an absorption amount of the (meth)acryloyl group measured by Fourier-transform infrared spectroscopy (FT-IR) in the resin composition, Y 1 is an absorption amount of the (meth)acryloyl group as measured by FT-IR in the preliminary adhesive member, and Z 1 is the curing rate of the preliminary adhesive member.

5. The method of claim 3 , wherein a weight average molecular weight of the (meth)acrylate monomer is about 100 to about 500.

6. The method of claim 3 , wherein a weight average molecular weight of the urethane (meth)acrylate oligomer is about 10,000 to about 40,000 (exclusive of 40,000).

7. The method of claim 3 , wherein the urethane (meth)acrylate oligomer includes a plurality of acrylic groups.

8. The method of claim 3 , wherein the photoinitiator includes a radical polymerization initiator.

9. The method of claim 1 , wherein a light integral of the first light is about 200 mJ/cm 2 to about 1,000 mJ/cm 2 , and a light integral of the second light is about 3,500 mJ/cm 2 to about 4,500 mJ/cm 2 .

10. The method of claim 1 , wherein the adhesive member has a 180 degree peel strength of about 800 gf/25 mm or more with respect to a polymer substrate.

11. The method of claim 1 , wherein the adhesive member has a curing rate of greater than 90%.

12. A method of manufacturing a display device comprising:

providing, on a substrate, a resin composition having a viscosity of about 5 cP to about 50 cP (exclusive of 50), as measured according to a JISK2283 method, at about 25° C.;

exposing the resin composition to a first light to form a preliminary adhesive member having a curing rate of about 80% to about 98% (exclusive of 80 and 98);

providing a protective member on the preliminary adhesive member; and

exposing the preliminary adhesive member to a second light having a light integral that is greater than that of the first light to form an adhesive member,

wherein the preliminary adhesive member has a loss tangent (tan δ) of about 0.2 to about 0.6 (exclusive of 0.6), and the adhesive member has a glass transition temperature of about −70° C. to about −30° C. (exclusive of −30).

13. The method of claim 12 , wherein the second light passes through the protective member and exposes the preliminary adhesive member.

14. The method of claim 12 , wherein the resin composition includes at least one (meth)acrylate monomer, at least one urethane (meth)acrylate oligomer, and at least one photoinitiator.

Assignments (1)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jul 20, 2022
From: FUJIWARA, TETSUYA
To: SAMSUNG DISPLAY CO., LTD.
Reel/Frame 060571/0642 →
Priority Claims (1)
KR 10-2021-0164273 · Nov 25, 2021 · national
Continuity (1)
Related Publication 20230159801A1 · May 25, 2023
Cited By (2)
US 12,325,813 US 12,537,889