Liquid crystal composition and dimming device thereof
A liquid crystal composition includes a component A composed of one or more liquid crystals with negative dielectric anisotropy and a component B composed of one or more compounds selected from a general formula I, where the optical anisotropy of the liquid crystal composition is larger than 0.14. The elastic coefficient of a liquid crystal system is adjusted by introducing a bi-mesogenic compound into a negative liquid crystal or a negative liquid crystal mixture. When the liquid crystal composition is used for the dimming device, the minimum light transmittance of the dimming device in the dark state can be significantly reduced, the adjustment range of the light transmittance in the light state and the dark state can be expanded, and the haze in the dark state can be increased, thereby broadening the use range. R 1 -MG 1 -X-MG 2 -R 2 I
1. A liquid crystal composition, comprising:
Component A consists of one or more negative liquid crystal components;
Component B consists of one or more compounds selected from the group of compounds of formula I; and
Component C consists of one or more ionic compounds;
R 1 -MG 1 -X-MG 2 -R 2 I;
wherein,
R 1 and R 2 each independently denote —H, —F, —Cl, —CN, —NCS or a chain alkyl group with 1 to 25 C atoms where one or more H atoms may be independently substituted by halogen or CN and one or more nonadjacent —CH 2 — may be independently replaced by —O—, —S—, —NH—, —N(CH 3 )—, —CO—, —COO—, —OCO—, —OCOO—, —SCO—, —COS—, —CH═CH—, —CH═CF—, —CF═CF— or —C≡C— in such a manner that two —O— are not directly adjacent to one another,
MG 1 and MG 2 each independently denote a mesogenic group,
X is a straight-chain alkyl group with 1, 3 or 5-40 C atoms or a branched alkyl group with 3 or 5-40 C atoms where one or more nonadjacent —CH 2 — may be independently replaced by —O—, —S—, —NH—, —N(CH 3 )—, —CO—, —COO—, —OCO—, —OCOO—, —SCO—, —COS—, —CH═CH—, —CH═CF—, —CF═CF—, —C≡C— or —CH(CN)— in such a manner that no two —O— are adjacent to one another or no two groups selected from —OCO—, —SCO—, —OCOO—, —COS—, —COO— and —CH═CH— are adjacent to each other,
the optical anisotropy of the liquid crystal composition is greater than 0.14.
2. The liquid crystal composition of claim 1 , wherein mesogenic group is selected from the group of formula II
—H 1 B 1 —H 2 p B 2 —H 3 q B 3 —H 4 f II
wherein,
H 1 , H 2 , H 3 and H 4 each independently denote a ring structure selected from the group of
wherein 1-4 H atoms of the ring structures may be independently substituted by halogen, CN or a chain alkyl group with 1-7 C atoms where at least one —CH 2 — may be replaced by —CHO—, —CO—, —COO— or —OCO— and at least one H atom may be substituted by F or Cl, B 1 , B 2 and B 3 each independently denote-COO—, —OCO—, —OCOO—, —OCH 2 —, —CH 2 O—, —CF 2 O—, —(CH 2 ) 2 —, —(CH 2 ) 4 —, —C≡C—, —CH═CH—, —CF 2 CF 2 —, —CF═CF—, —CH═CH—COO—, —OCO—CH═CH— or a single bond,
p, q and r is 0 or 1.
3. The liquid crystal composition of claim 2 , wherein the mesogenic group each independently comprises at least two six-membered rings.
4. The liquid crystal composition of claim 3 , wherein the mesogenic group is each independently selected from the group of
and their mirror structures, wherein 1-4 H atoms of the six-membered ring may be independently substituted by halogen, CN or a chain alkyl group with 1-7 C atoms where one or more nonadjacent —CH 2 — may be replaced by —CHO—, —CO—, —COO— or —OCO— and one or more H atoms may be substituted by F or Cl.
5. The liquid crystal composition of claim 1 , wherein R 1 and R 2 each independently denote —F, —Cl, —CN, —OCF 3 , —CF 3 or an unsubstituted chain alkyl group with 1-10 C atoms.
6. The liquid crystal composition of claim 1 , wherein X is selected of formula III
—Y 1 CH 2 s Y 2 — III
wherein, Y 1 and Y 2 each independently denote —COO—, —OCO—, —O—, —CH═CH—, —CF 2 O—, —OCF 2 —, —CF 2 CF 2 — or a single bond, and
s is an odd number between 3 and 13.
7. The liquid crystal composition of claim 1 , wherein the liquid crystal composition further comprises one or more dyes.
8. The liquid crystal composition of claim 7 , wherein the dye is a dichroic dye.
9. The liquid crystal composition of claim 1 , wherein the liquid crystal composition further comprises a light stabilizer and an UV inhibitor.
10. The liquid crystal composition of claim 1 , wherein the component B is 1%-20% by weight of the liquid crystal composition.
11. A light modulating device comprising the liquid crystal composition of claim 1 , and further comprising:
an upper transparent substrate and a lower transparent substrate, wherein the inner surfaces of the upper transparent substrate and the lower transparent substrate are respectively provided with an upper transparent electrode and a lower transparent electrode; and
a liquid crystal layer disposed between the upper transparent substrate and the lower transparent substrate, which contains the liquid crystal composition;
wherein, the light modulating device is in a transparent state when no voltage is applied, and is in a dark state when a voltage is applied.