Etching liquid for titanium and/or titanium alloy, method for etching titanium and/or titanium alloy with use of said etching liquid, and method for producing substrate with use of said etching liquid
An etching method for quickly removing a seed layer that is formed of titanium and/or a titanium alloy, while suppressing dissolution of other metals from copper wiring lines and the like, for continuous and stable processing; and a composition which is used for this etching method. The composition comprises, based on a total amount of the composition, 0.01 to 0.23% by mass hydrogen peroxide, 0.2 to 3% by mass fluoride, 0.0005 to 0.025% by mass of a halide ion other than a fluoride ion, and water. A method for using the composition to produce a substrate is also described.
1. A composition for etching titanium and/or a titanium alloy, wherein the composition consists essentially of a hydrogen peroxide (A), a fluoride (B), a halide ion (C) other than the fluoride ion which is contained in the fluoride (B), and water (D),
wherein a content of the hydrogen peroxide (A) is from 0.01 to 0.23 mass % based on a total amount of the composition,
a content of the fluoride (B) is from 0.2 to 3 mass % based on the total amount of the composition, and
a content of the halide ion (C) is from 0.0005 to 0.025 mass % based on the total amount of the composition,
wherein the source of the halide ion (C) is at least one selected from the group consisting of lithium chloride, sodium chloride, potassium chloride, ammonium chloride, lithium bromide, sodium bromide, potassium bromide, ammonium bromide, lithium iodide, sodium iodide, potassium iodide, and ammonium iodide.
2. The composition according to claim 1 , wherein the fluoride (B) comprises at least one selected from the group consisting of hydrogen fluoride, acidic ammonium fluoride, acidic sodium fluoride, and acidic potassium fluoride.
3. The composition according to claim 1 , wherein the halide ion (C) comprises at least one selected from the group consisting of a chloride ion and a bromide ion.
4. The composition according to claim 1 , being a composition for etching titanium and/or a titanium alloy while suppressing etching of copper or a copper alloy.
5. The composition according to claim 1 , having an etching rate of copper of 100 nm/min or less at 30° C.
6. The composition according to claim 1 , wherein a ratio of an etching rate of titanium to an etching rate of copper is at least 2 at 30° C.
7. An etching method, comprising etching titanium and/or a titanium alloy with the composition according to claim 1 .
8. A method for forming an electric circuit, comprising etching titanium and/or a titanium alloy with the composition according to claim 1 to form an electric circuit in which titanium and/or a titanium alloy and copper or a copper alloy are laminated.
9. A method for producing a substrate, comprising etching titanium and/or a titanium alloy with the composition according to claim 1 .