Granted Patent B2

US 12,337,376 · App. 18/005,411 · Granted Jun 24, 2025

Inventors: Azghar Munshi (Castelgomberto, IT); René Vargovic (Wunstorf, DE); Lukas Mirko Reinold (Hannover, DE); Maria Schweinefuss (Hannover, DE)

Assignee: HÜTTENES-ALBERTUS CHEMISCHE WERKE GESELLSCHAFT MIT BESCHRÄNKTER HAFTUNG

B22C1/181B22C11/00

Abstract

Claims (133)

1. A process for producing an article for use in the foundry industry, selected from the group consisting of molds, cores, feeder elements and molding material mixtures, said process comprising the following steps:

(S1) producing or providing a binder system comprising the following components in three spatially separate vessels:

a component (A) comprising particulate amorphous silicon dioxide,

a first liquid component (B) comprising waterglass,

and

a second liquid component (C) comprising aluminate ions dissolved in an aqueous phase,

(S2) contacting a mold base material (D) and constituents of all the said components (A), (B) and (C) of the binder system in predetermined ratios in one or more steps, so as to result in a molding material mixture in which the aluminate ions and the particulate amorphous silicon dioxide are mixed into the waterglass, wherein steps (S1) and (S2) are conducted in a facility for producing molding material mixtures.

2. The process as claimed in claim 1 , wherein

the contacting of the mold base material (D) and constituents of all the said components (A), (B) and (C) of the binder system in predetermined ratios in one or more steps in step (S2) is conducted by using

an amount of the first liquid component (B) present as a constituent of the binder system in step (S1)

and/or

an amount of the second liquid component (C) present as a constituent of the binder system in step (S1)

and/or

selected constituents of the first liquid component (B) after separation of the first liquid component (B) present in step (S1) as a constituent of the binder system

and/or

selected constituents of the first liquid component (C) after separation of the second liquid component (C) present in step (S1) as a constituent of the binder system

in the contacting in step (S2),

and/or

wherein constituents and/or amounts of the first liquid component (B) and second liquid component (C) each present as a constituent of the binder system in step (S1), in step (S2),

are first mixed in a predetermined ratio, so as to result in a mixture comprising waterglass and aluminate ions in predetermined proportions, and then the mold base material (D) is contacted with this mixture,

or

not mixing before the mold base material (D) is contacted (i) fully simultaneously, (ii) partly simultaneously or (iii) in any sequence successively with constituents or amounts of the first liquid component (B) and the second liquid component (C).

3. The process as claimed in claim 1 , wherein, in step (S2), constituents or amounts of the first liquid component (B) are added at an individually predetermined dosing rate and/or constituents or amounts of the second liquid component (C) at an individually predetermined dosing rate

(i) to the mold base material (D)

and/or

(ii) to constituents or amounts of another component of the binder system, wherein the facility for production of molding material mixtures comprises:

one or more dosing devices for metered addition of constituents or amounts of the first liquid component (B) and/or of constituents or amounts of the second liquid component (C) and/or of constituents or amounts of component (A) comprising particulate amorphous silicon dioxide and/or the mold base material (D)

and

an open-loop or closed-loop control device for the one dosing device or the multiple dosing devices.

4. The process as claimed in claim 1 ,

wherein the total mass of the constituents or amounts of the first liquid component (B) and of the constituents or amounts of the second liquid component (C) used in the contacting in step (S2) comprises:

15% to 35% by weight of silicon dioxide,

8% to 17% by weight of alkali metal oxide,

aluminate ions, calculated as Al 2 O 3 , in an amount up to 4.0% by weight,

where the percentages by weight are based on the total mass of the constituents or amounts of the first liquid component (B) and of the constituents or amounts of the second liquid component (C) used in the contacting in step (S2)

and/or

where, in the total mass of the constituents or amounts of the first liquid component (B) and constituents or amounts of the second liquid component (C) used in step (S2), the mass ratio of alkali metal oxide to Al 2 O 3 is in the range from 35:1 to 3:1.

5. The process as claimed in claim 1 ,

wherein, in step (S2), the temperature of the constituents or amounts of the first liquid component (B) used and of the constituents or amounts of the second liquid component (C) used at the start of the contacting or mixing are each within a range from 5 to 35° C.

and/or

wherein, in the total mass of the constituents or amounts of the first liquid component (B) and constituents or amounts of the second liquid component (C) used in step (S2), the mass ratio of Al 2 O 3 to SiO 2 is greater than 1:70.

6. The process as claimed in claim 1 , wherein

constituents or amounts of component (A) comprising particulate amorphous silicon dioxide are contacted in step (S2) with the mold base material and with constituents or amounts of the first liquid component (B) and constituents or amounts of the second liquid component (C), wherein

component (A) used as a constituent of the binder system in step (S1)

(i) is particulate, or

(ii) is a suspension of particulate amorphous silicon dioxide

and/or

the constituents or amounts of component (A) used in step (S2), comprising particulate amorphous silicon dioxide, are used (i) in the form of a powder or granular material, or (ii) as a suspension

and/or

the particulate amorphous silicon dioxide of component (A) is used as a constituent in step (S2) and is selected from the group consisting of:

particulate synthetic amorphous silicon dioxide containing silicon dioxide in a proportion of at least 80% by weight, based on the total mass of the particulate synthetic amorphous silicon dioxide, and at least carbon as secondary constituent;

particulate synthetic amorphous silicon dioxide comprising oxidic zirconium as secondary constituent and preferably producible by thermal breakdown of ZrSiO 4 ;

particulate synthetic amorphous silicon dioxide producible by oxidizing metallic silicon by means of an oxygenous gas;

particulate synthetic amorphous silicon dioxide producible by quenching a silicon dioxide melt;

fumed silica;

and

mixtures thereof

and/or

component (A) comprising particulate amorphous silicon dioxide additionally comprises one, two, three or more further constituents that are used as well in step (S2) and are independently selected from the group consisting of:

particulate materials,

water-soluble materials,

alkali metal hydroxides,

surfactants,

film formers,

hydrophobizing agents,

and

carbohydrates.

7. The process as claimed in claim 1 , wherein the proportion of silicon dioxide in component (A) comprising particulate amorphous silicon dioxide based on the total mass of component (A) comprising particulate amorphous silicon dioxide.

8. The process as claimed in claim 1 , wherein the first liquid component (B) and/or the second liquid component (C) present as a constituent of the binder system in step (S1) is/are used in step (S2) out of the respective vessel without further processing and/or

wherein the first liquid component (B) comprises one or more alkali metals M from the group consisting of lithium, sodium and potassium, where the proportion of potassium ions, calculated as K 2 O, is greater than 0.1% by weight,

and/or

wherein the second liquid component (C) comprises one or more alkali metals M from the group consisting of lithium, sodium and potassium, where the proportion of potassium ions, calculated as K 2 O, is preferably greater than 0.1% by weight,

and/or

wherein the total mass of the first liquid component (B) and of the second liquid component (C) comprises one or more alkali metals M from the group consisting of lithium, sodium and potassium, where the proportion of potassium ions, calculated as K 2 O, is greater than 0.1% by weight,

and/or

wherein the first liquid component (B), comprises a content of alkali metal silicate in the range from 20% by weight to 60% by weight, based on the total mass of the first liquid component (B);

and/or

wherein the first liquid component (B) comprises waterglass with a molar SiO 2 /alkali metal oxide modulus in the range from 1.6 to 4.0.

9. The process as claimed in claim 1 ,

wherein the first liquid component (B) and/or the second liquid component (C) additionally comprise(s) one, two or more further constituents that are used as well in step (S2) and are independently selected from the group consisting of:

surface-active substances,

alkali metal phosphates,

oxidic boron compounds,

and/or

wherein the second liquid component (C) comprises dissolved alkali metal aluminates that are used in step (S2),

and/or

wherein the first liquid component (B) comprises

a content of aluminate ions, calculated as Al 2 O 3 , of not greater than 0.4% by weight,

and/or

a content of lithium ions, calculated as LiO 2 , of not greater than 0.1% by weight,

and/or

a content of boron ions, calculated as B 2 O 3 , of not greater than 0.1% by weight,

based in each case on the total mass of the first liquid component (B),

and/or

wherein the second liquid component (C) comprises

in the aqueous phase, a content of aluminate ions, calculated as Al 2 O 3 , in the range from 0.4% by weight to 35% by weight,

and/or

a content of lithium ions, calculated as LiO 2 , of not greater than 0.1% by weight,

and/or

a content of boron ions, calculated as B 2 O 3 , of not greater than 0.1% by weight,

based in each case on the total mass of the second liquid component (C),

and/or

wherein the total mass of the constituents or amounts of the first liquid component (B) and constituents or amounts of the second liquid component (C) used in the contacting in step (S2) comprises

a content of aluminate ions, calculated as Al 2 O 3 , in the range from 0.4% to 4.0% by weight,

and/or

a content of lithium ions, calculated as LiO 2 , of not greater than 0.1% by weight,

and/or

a content of boron ions, calculated as B 2 O 3 , of not greater than 0.1% by weight,

where the percentages by weight are based on the total mass of the constituents or amounts of the first liquid component (B) and of the constituents or amounts of the second liquid component (C) used in the contacting in step (S2).

10. The process as claimed in claim 1 , wherein the article is produced in step (S2) using respective total masses of the mold base material (D) and of the respective constituents or amounts of component (A) comprising particulate amorphous silicon dioxide, of the first liquid component (B) and of the second liquid component (C), where:

0.1 to 3.0 parts by weight of component (A) comprising particulate amorphous silicon dioxide is used, based on 100 parts by weight of the total mass of the refractory mold base material (D) used,

and/or

constituents or amounts of the first liquid component (B) and constituents or amounts of the second liquid component (C) are used in the range from 0.5 to 20 parts by weight in total, based on 100 parts by weight of the amount of the refractory mold base material (D) used,

and/or

the ratio of

the total mass of the constituents or amounts of the first liquid component (B) used

to

the total mass of the constituents or components of the second liquid component (C) used

is in the range from 86:1 to 1:1.

11. The process as claimed in claim 1 , comprising the steps of (S3) three-dimensionally shaping the molding material mixture, (S4) curing the binder, so as to result in a mold, a core or a feeder element, wherein, in step (S4),

the curing, at least in portions, is effected at a temperature in the range from 100° C. to 300° C.,

and/or

the shaped molding material mixture is heated in a heatable shaping mold

and/or

the shaped molding material mixture is heated by contact with hot air

and/or

the shaped molding material mixture is heated by action of microwaves

and/or

the shaped molding material mixture is heated by passage of current

and/or

the shaped molding material mixture is cured using carbon dioxide

and/or

the shaped molding material mixture is cured using esters.

Assignments (1)

Priority Claims (1)

Continuity (1)

References Cited (29)