Multistage emulsion polymer and process of preparing the same
A multistage emulsion polymer comprising a first polymer and a second polymer comprising structural units of a nitrogen-containing heterocyclic monomer at specific weight ratios of the first polymer to the second polymer and a Tg difference between the first and second polymers; the multistage emulsion polymer suitable for use in coating applications to provide coating films with improved dirt pick-up resistance without compromising film formation properties.
1. A multistage emulsion polymer comprising a first polymer and a second polymer,
wherein the multistage emulsion polymer comprises, by weight based on the weight of the multistage emulsion polymer, from 0.1% to 10% of structural units of a nitrogen-containing heterocyclic monomer, and 5% or more of structural units of a cycloalkyl (meth) acrylate, a C 6 -C 10 alkyl (meth) acrylate, or mixtures thereof;
wherein the second polymer comprises structural units of the nitrogen-containing heterocyclic monomer;
wherein Tg of the first polymer is at least 35° C. higher than that of the second polymer;
wherein the weight ratio of the first polymer to the second polymer is in the range of from 55:45 to 95:5.
2. The multistage emulsion polymer of claim 1 , wherein the nitrogen-containing heterocyclic monomer is an ethylenically unsaturated imidazole, imidazoline, amidine, pyridine, pyrrole, pyrrolidine, pyrrolidone, or caprolactam; or combinations thereof.
3. The multistage emulsion polymer of claim 1 , wherein the nitrogen-containing heterocyclic monomer is a vinylpyrrolidone.
4. The multistage emulsion polymer of claim 1 , wherein the multistage emulsion polymer comprises structural units of cyclohexyl (meth) acrylate, 2-ethylhexyl (meth) acrylate, or mixtures thereof.
5. The multistage emulsion polymer of claim 1 , wherein the second polymer comprises, by weight based on the weight of the second polymer, from 0.2% to 80% of structural units of the nitrogen-containing heterocyclic monomer.
6. The multistage emulsion polymer of claim 1 , wherein the weight ratio of the first polymer to the second polymer in the range of from 60:40 to 90:10.
7. The multistage emulsion polymer of claim 1 , further comprising structural units of a monoethylenically unsaturated functional monomer carrying at least one functional group selected from a carboxyl, carboxylic anhydride, sulfonic acid, amide, sulfonate, phosphoric acid, phosphonate, phosphate, or hydroxyl group, a salt thereof, or combinations thereof; and optionally structural units of an additional monoethylenically unsaturated nonionic monomer.
8. A process of preparing the multistage emulsion polymer of claim 1 by multistage free-radical polymerization, comprising:
(i) preparing a first polymer in an aqueous medium by free-radical polymerization, and
(ii) preparing a second polymer in the presence of the first polymer obtained from step (i) by free-radical polymerization, forming the multistage emulsion polymer comprising the first polymer and the second polymer;
wherein the multistage emulsion polymer comprises, by weight based on the weight of the multistage emulsion polymer, from 0.1% to 10% of structural units of a nitrogen-containing heterocyclic monomer, and 5% or more of structural units of a cycloalkyl (meth) acrylate, a C 6 -C 10 alkyl (meth) acrylate, or mixtures thereof;
wherein the second polymer comprises structural units of the nitrogen-containing heterocyclic monomer;
wherein Tg of the first polymer is at least 35° C. higher than that of the second polymer;
wherein the weight ratio of the first polymer to the second polymer is in the range of from 55:45 to 95:5.
9. An aqueous coating composition comprising the multistage emulsion polymer of claim 1 , and a pigment and/or an extender.