Method for forming assembled nanomaterial coating by solute-assisted assembly, and resulting products
A method for forming a nanomaterial coating through solute-assisted assembly includes steps of: providing a mixture comprising a solvent, a solute, and a nanomaterial or particle; applying sonication to the mixture; and contacting a substrate with the mixture so as to form a coating of the nanomaterial or the particle onto the substrate. The solute is selected from a salt, a sugar, an acid, a base, or a combination thereof. The resulting products comprising the nanomaterial coating include articles for flexible electronics and functional textiles.
1. A method, comprising steps of:
providing a mixture comprising a solvent, a solute, and a nanomaterial or particle, wherein the solute is selected from the group consisting of a salt, a sugar, and any combination thereof, wherein the solute is soluble in the solvent;
applying sonication to the mixture; and
contacting a substrate with the mixture so as to form a coating of the nanomaterial or the particle onto the substrate.
2. The method of claim 1 , wherein the nanomaterial or particle is hydrophilic while the substrate is hydrophobic, or the nanomaterial or particle is hydrophobic while the substrate is hydrophilic.
3. The method of claim 1 , wherein the nanomaterial or particle is selected from the group consisting of a metal, an oxide, a metal hydroxide not soluble in water, a metal salt not soluble in water, a transition metal chalcogenide, a carbide, a nitride, a carbonitride, a single element material, a polymer, or any combination thereof.
4. The method of claim 1 , wherein the nanomaterial is exfoliated and/or dispersed after sonication is applied.
5. The method of claim 1 , wherein the substrate comprises a polymer, a glass sheet, a metal foil, a paper, or a combination thereof.
6. The method of claim 1 , wherein the substrate is contacted with the mixture through a dip coating process, a roll-to-roll process, a mechanical stirring process, or a combination thereof.
7. The method of claim 1 , wherein the coating comprises layered nanomaterials, and the layered nanomaterials have a size of spacing, which is controlled by a species of the solute, wherein the solute is a salt, and ions of the salt enlarges an interlayer spacing between two adjacent layers of the layered nanomaterials so as to control the size of spacing.
8. The method of claim 1 , wherein the nanomaterial or particle has a size in a range of from about 1 nm to about 10 microns.
9. The method of claim 1 , wherein the nanomaterial or particle comprises nanomaterials having at least one dimension in a range of from about 1 nm to about 1,000 nm.
10. The method of claim 1 , wherein the nanomaterial or particle comprises microparticles having a diameter in a range of from about 1 micron to about 10 microns.
11. The method of claim 1 , wherein the solute comprises one or more salts.
12. The method of claim 11 , wherein the nanomaterial or particle is hydrophilic, and the substrate comprises a polymer.
13. The method of claim 1 , wherein the solvent is water or comprises water and another solvent.
14. The method of claim 1 , wherein the mixture contains no surfactant.