Negative electrode for lithium secondary battery, lithium secondary battery comprising negative electrode, and method for preparing negative electrode for lithium secondary battery
Disclosed is a negative electrode composition, a negative electrode for a lithium secondary battery, including the same, and a lithium secondary battery including the negative electrode, and a method for preparing a negative electrode composition.
1. A negative electrode for a lithium secondary battery, comprising:
a negative electrode current collector layer; and
a negative electrode active material layer provided on at least one surface of the negative electrode current collector layer,
wherein the at least one negative electrode active material layer comprises a negative electrode composition comprising: a negative electrode active material; a negative electrode conductive material; and a negative electrode binder,
wherein the negative electrode active material comprises Si and SiO,
a weight ratio of the Si: SiO is in a range of 65:35 to 85:15,
wherein the Si has an average particle diameter D50 of 1 μm or more and 10 μm or less,
wherein the SiO has an average particle diameter D50 of 1 μm or more and 10 μm or less,
an amount of SiO on a surface opposite to a surface of the negative electrode active material layer facing the negative electrode current collector layer is higher than an amount of SiO on the surface facing the negative electrode current collector layer, and
further comprising on the negative electrode active material layer: (i) a junction region comprising the surface facing the negative electrode current collector layer; and (ii) a surface region comprising the surface opposite to the surface facing the negative electrode current collector layer, wherein a weight ratio of the Si: SiO in the junction region is 95:5 to 100:0, and wherein a weight ratio of the Si: SiO in the surface region is 5:95 to 0:100.
2. The negative electrode of claim 1 , wherein the at least one negative electrode active material layer has a first concentration gradient where the amount of SiO is increased in a direction from the surface facing the negative electrode current collector layer to the surface opposite to the surface facing the negative electrode current collector layer.
3. The negative electrode of claim 1 , wherein the negative electrode active material is present in an amount of 60 parts by weight or more based on 100 parts by weight of the negative electrode composition.
4. The negative electrode of claim 1 , wherein the negative electrode conductive material comprises: a planar conductive material, and a linear conductive material.
5. The negative electrode of claim 4 , wherein the negative electrode active material layer has a concentration gradient where an amount of the planar conductive material is increased in a direction from the surface facing the negative electrode current collector layer to the surface opposite to the surface facing the negative electrode current collector layer.
6. The negative electrode of claim 4 , wherein the planar conductive material and the linear conductive material are comprised in an amount of 90 parts by weight or more and 99.9 parts by weight or less and 0.1 part by weight or more and 10 parts by weight or less, respectively, based on 100 parts by weight of the negative electrode conductive material.
7. The negative electrode of claim 1 , wherein the negative electrode current collector layer has a thickness of 1 μm or more and 100 μm or less, and
wherein the negative electrode active material layer has a thickness of 20 μm or more and 500 μm or less.
8. The negative electrode of claim 1 , wherein the negative electrode active material layer is present on both surfaces of the negative electrode current collector.
9. The negative electrode of claim 1 , wherein the at least one negative electrode active material layer comprises three regions in the thickness direction, and is sequentially divided as:
a first active material layer region;
a second active material layer region; and
a third active material layer region,
wherein
the first active material layer region faces the negative electrode current collector layer,
the first active material layer region comprises SiO in an amount of 10 parts by weight or less based on 100 parts by weight of the negative electrode active material, and
the third active material layer region comprises SiO in an amount of 80 parts by weight or more based on 100 parts by weight of the negative electrode active material.
10. A lithium secondary battery comprising:
a positive electrode;
the negative electrode for a lithium secondary battery of claim 1 ;
a separator provided between the positive electrode and the negative electrode; and
an electrolyte.