IP Library Granted Patent US 12,448,489
Granted Patent B2
US 12,448,489 · App. 18/003,642 · Granted Oct 21, 2025

Resin film

Inventor: Tomoaki Hashiguchi (Settsu, JP)
Assignee: KANEKA CORPORATION
C08J5/18C08L67/04C08J2367/04C08J2467/04C08L2203/16C08L2205/025
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Quick Facts
Patent No.
US 12,448,489
App. No.
18/003,642
Granted
Oct 21, 2025
Kind
B2
Abstract

Provides is a resin film containing a poly(3-hydroxyalkanoate) resin component. A tensile modulus of the resin film is from 500 to 2000 MPa. A swelling degree of the resin film, as measured by immersion of the resin film in methyl ethyl ketone for two hours, is from 1 to 5. Preferably, the poly(3-hydroxyalkanoate) resin component is a mixture of at least two poly(3-hydroxyalkanoate) resins differing in types and/or contents of constituent monomers.

Claims (20)

1. A resin film, comprising:

a poly(3-hydroxyalkanoate) resin component comprising a copolymer (A) which is a copolymer of 3-hydroxybutyrate units and other hydroxyalkanoate units and in which a content of the other hydroxyalkanoate units is from 1 to 6 mol %, and a copolymer (B) which is a copolymer of 3-hydroxybutyrate units and other hydroxyalkanoate units and in which a content of the other hydroxyalkanoate units is at least 24 mol %,

wherein in the poly(3-hydroxyalkanoate) resin component, a proportion of the copolymer (A) is from 35 wt % to 80 wt %, and a proportion of the copolymer (B) is from 20 wt % to 65 wt %, the other hydroxyalkanoate units in the copolymer (B) are 3-hydroxyhexanoate units,

a tensile modulus of the resin film is from 500 to 1,500 MPa, and

a swelling degree of the resin film, as measured by immersion of the resin film in methyl ethyl ketone for two hours, is from 1 to 5.

2. The resin film according to claim 1 , wherein an average content of the other hydroxyalkanoate units in total monomer units constituting the poly(3-hydroxyalkanoate) resin component is from 8 to 18 mol %.

3. The resin film according claim 1 , wherein a tearing resistance of the resin film is from 7.9 to 200 N/mm.

4. The resin film according to claim 1 , wherein a thickness of the resin film is from 10 μm to 1 mm.

5. The resin film according to claim 1 , wherein the other hydroxyalkanoate units in the copolymer (A) are 3-hydroxyhexanoate units.

6. The resin film according to claim 5 , wherein in the poly(3-hydroxyalkanoate) resin component, the proportion of the copolymer (A) is from 45 to 80 wt %, and the proportion of the copolymer (B) is from 20 to 55 wt %.

7. The resin film according to claim 1 , wherein the other hydroxyalkanoate units in the copolymer (A) are selected from the group consisting of 3-hydroxyhexanoate units and 4-hydroxybutyrate units.

8. The resin film according to claim 1 , wherein the tensile modulus of the resin film is from 600 to 1,500 MPa.

9. The resin film according to claim 1 , wherein the tensile modulus of the resin film is from 700 to 1.500 MPa.

10. The resin film according to claim 1 , wherein the swelling degree of the resin film, as measured by immersion of the resin film in methyl ethyl ketone for two hours, is from 1 to 4.

11. The resin film according to claim 1 , wherein the swelling degree of the resin film, as measured by immersion of the resin film in methyl ethyl ketone for two hours, is from 1 to 2.5.

12. The resin film according to claim 1 , wherein in the poly(3-hydroxyalkanoate) resin component, the proportion of the copolymer (A) is from 45 to 80 wt %, and the proportion of the copolymer (B) is from 20 to 55 wt %.

13. The resin film according to claim 1 , wherein the content of the other hydroxyalkanoate units in the copolymer (B) is from 24 mol % to 50 mol %.

14. The resin film according to claim 1 , wherein the content of the other hydroxyalkanoate units in the copolymer (B) is from 24 mol % to 35 mol %.

15. The resin film according to claim 1 , wherein the content of the other hydroxyalkanoate units in the copolymer (B) is from 24 mol % to 30 mol %.

16. The resin film according to claim 1 , wherein in the poly(3-hydroxyalkanoate) resin component, the proportion of the copolymer (A) is from 35 wt % to 49 wt %, and the proportion of the copolymer (B) is from 51 wt % to 65 wt %.

Assignments (1)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jun 4, 2024
From: HASHIGUCHI, TOMOAKI
To: KANEKA CORPORATION
Reel/Frame 067614/0099 →
Priority Claims (1)
JP 2020-111919 · Jun 29, 2020 · national
Continuity (1)
Related Publication 20230235137A1 · Jul 27, 2023
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