IP Library Granted Patent US 12,466,989
Granted Patent B2
US 12,466,989 · App. 17/275,797 · Granted Nov 11, 2025

Microemulsions and uses thereof

Inventors: Sanjay Misra (Kuala Lumpur, MY); Jamal Mohamed Ibrahim (Kuala Lumpur, MY); Intan Khalida Saleh (Kuala Lumpur, MY)
Assignee: PETROLIAM NASIONAL BERHAD (PETRONAS)
C09K8/536C09K8/524C09K8/528C09K8/602C09K8/92C11D3/33E21B37/06
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Quick Facts
Patent No.
US 12,466,989
App. No.
17/275,797
Granted
Nov 11, 2025
Kind
B2
Abstract

The present invention generally relates to microemulsions comprising a compound of Formula (I), a solvent, a surfactant and optionally a co-surfactant disclosed herein, wherein the ratio of the surfactant to the co-surfactant is about 100:0 to about 20:90. The disclosed microemulsions may be useful in preventing or removing organic deposits, inorganic deposits, metal naphthenates, napthenic acids, and/or mixtures thereof from subterranean formations. The disclosed microemulsions may also be useful in stimulating tight carbonate reservoirs.

Claims (10)

1 . A microemulsion comprising:

a solution comprising glutamic acid N,N-di acetic acid (GLDA) or salts thereof, kerosene, linear alkyl benzene sulfonic acid (LABSA), and n-butanol, wherein the ratio of LABSA to n-butanol is 50:50; and wherein the ratio of the solution comprising GLDA, or salts thereof, to kerosene is 60:40.

2 . The microemulsion of claim 1 , wherein the solution has a pH value of about 1.7 to about 4.

3 . The microemulsion of claim 1 , wherein glutamic acid N,N-di acetic acid (GLDA) or salts thereof and kerosene are present in an amount in which the solubilization point of the microemulsion is achieved.

4 . The microemulsion of claim 1 , wherein the microemulsion has a droplet size of less than 140 nm.

5 . A method for preventing or removing formation of organic deposits, inorganic deposits, metal naphthenates, naphthenic acids and/or mixtures thereof from subterranean formations comprising the steps of:

(i) providing the microemulsion of claim 1 , and

(ii) introducing the microemulsion into a subterranean formation.

6 . The method of claim 5 , further comprising the step of contacting the microemulsion with the organic deposits, inorganic deposits, metal naphthenates, naphthenic acids, and/or mixtures formed on a surface of a downhole pipeline.

7 . A method for stimulating a carbonate reservoir in a subterranean formation, comprising injecting the microemulsion of claim 1 into the subterranean formation.

Assignments (1)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Mar 12, 2021
From: MISRA, SANJAY; MOHAMED IBRAHIM, JAMAL; SALEH, INTAN KHALIDA
To: PETROLIAM NASIONAL BERHAD (PETRONAS)
Reel/Frame 055577/0728 →
Priority Claims (1)
MY PI2018001571 · Sep 14, 2018 · national
Continuity (1)
Related Publication 20210348048A1 · Nov 11, 2021
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