Sample support body, ionization method, and mass spectrometry method
A sample support body is used for ionizing a component of a sample. The sample support body includes: a substrate; a porous layer provided on the substrate and having a front surface on a side opposite to the substrate; and a partition portion partitioning the front surface into a first region and a second region. The porous layer includes a main body layer having a plurality of holes opening to the front surface. The partition portion includes a partition groove formed on the front surface so as to pass between the first region and the second region.
1 . A sample support body used for ionizing a component of a sample, the sample support body comprising:
a substrate;
a porous layer provided on the substrate and having a front surface on a side opposite to the substrate; and
a partition portion partitioning the front surface into a first region and a second region, wherein
the porous layer includes a main body layer having a plurality of holes opening to the front surface, and
the partition portion includes a partition groove formed on the front surface so as to pass between the first region and the second region.
2 . The sample support body according to claim 1 , wherein a width of the partition groove is greater than a depth of the partition groove.
3 . The sample support body according to claim 2 , wherein
the depth of the partition groove is 50 μm or more and 300 μm or less, and
the width of the partition groove is at least twice the depth of the partition groove.
4 . The sample support body according to claim 1 , wherein the partition portion includes, as the partition groove, a part of an annular first partition groove surrounding the first region, a part of an annular second partition groove surrounding the second region, and a part of a third partition groove passing between the first partition groove and the second partition groove.
5 . The sample support body according to claim 1 , wherein
the partition groove extends annularly,
the first region is a region outside the partition groove, and
the second region is a region inside the partition groove.
6 . The sample support body according to claim 1 , further comprising a display portion where predetermined information is displayed,
wherein the display portion includes a display groove formed on the front surface.
7 . The sample support body according to claim 1 , wherein
the main body layer is an insulating layer, and
the porous layer further includes a conductive layer formed along at least the front surface.
8 . The sample support body according to claim 7 , wherein the substrate and the main body layer are formed by anodizing a surface layer of a metal substrate or a silicon substrate.
9 . An ionization method comprising:
a step of preparing the sample support body according to claim 7 ;
a step of disposing the sample to the front surface; and
a step of ionizing the component by irradiating the front surface with an energy ray.
10 . A mass spectrometry method comprising:
the plurality of steps of the ionization method according to claim 9 ; and
a step of detecting the ionized component.
11 . The sample support body according to claim 1 , wherein
the main body layer is an insulating layer, and
the main body layer is exposed to an outside on at least the front surface.
12 . An ionization method comprising:
a step of preparing the sample support body according to claim 11 ;
a step of disposing the sample to the front surface; and
a step of ionizing the component by irradiating the front surface with a charged droplet.
13 . The sample support body according to claim 11 , wherein the substrate and the main body layer are formed by anodizing a surface layer of a metal substrate or a silicon substrate.
14 . The sample support body according to claim 1 , wherein the partition groove is formed on the front surface by the porous layer falling into a groove formed on a front surface of the substrate on the porous layer side.