Molecules having pesticidal utility, and intermediates, compositions, and processes, related thereto
This disclosure relates to the field of molecules having pesticidal utility against pests in Phyla Arthropoda, Mollusca, and Nematoda, processes to produce such molecules, intermediates used in such processes, pesticidal compositions containing such molecules, and processes of using such pesticidal compositions against such pests. These pesticidal compositions may be used, for example, as acaricides, insecticides, miticides, molluscicides, and nematicides. This document discloses molecules having the following formula (“Formula One”).
1 . A molecule selected from one of the molecules listed in the following Table.
No.
Structure
F63
F64
F65
F75
F180
F187
F203
F211
F241
F242
F247
F252
F281
F297
F306
F309
F310
F311
F312
F316
F319
F330
F331
F342
F351
F352
F353
F354
F357
F383
F385
F386
F389
F390
F391
F392
F395
F396
F397
F398
F399
F400
F533
F541
F542
F543
F546
F547
F548
F549
F552
F553
F558
F559
F560
F561
F562
F563
F564
F565
F566
F572
F580
F584
F585
F586
F587
F588
F589
F590
F591
PF6
PF39
2 . A molecule according to claim 1 , wherein the carboxamido, and the phenyl, which are bonded to the cyclopropane, are in the R,R configuration.
3 . A composition comprising a molecule according to claim 1 , further comprises a carrier and/or an active ingredient.
4 . A composition according to claim 3 , the composition further comprises an active ingredient selected from acaricides, algicides, antifeedants, avicides, bactericides, bird repellents, chemosterilants, fungicides, herbicide safeners, herbicides, insect attractants, insect repellents, insecticides, mammal repellents, mating disrupters, molluscicides, nematicides, plant activators, plant growth regulators, rodenticides, synergists, and virucides, an active ingredient selected from AIGA, AI-1, AI-2, or AIGA-2, or further comprising Lotilaner, a structure selected from Table A, or a biopesticide.
TABLE A
Structure of M#—active ingredients
M#
Structure
M1
M2
M3
M4
M5
M6
5 . A composition according to claim 3 , the composition further comprises an active ingredient from Acetylcholinesterase (AChE) inhibitors; GABA-gated chloride channel antagonists; Sodium channel modulators; Nicotinic acetylcholine receptor (nAChR) agonists; Nicotinic acetylcholine receptor (nAChR) allosteric activators; Chloride channel activators; Juvenile hormone mimics; Miscellaneous nonspecific (multi-site) inhibitors; Modulators of Chordotonal Organs; Mite growth inhibitors; Microbial disruptors of insect midgut membranes; Inhibitors of mitochondrial ATP synthase; Uncouplers of oxidative phosphorylation via disruption of the proton gradient; Nicotinic acetylcholine receptor (nAChR) channel blockers; Inhibitors of chitin biosynthesis, type 0; Inhibitors of chitin biosynthesis, type 1; Moulting disruptor, Dipteran; Ecdysone receptor agonists; Octopamine receptor agonists; Mitochondrial complex III electron transport inhibitors; Mitochondrial complex I electron transport inhibitors; Voltage-dependent sodium channel blockers; Inhibitors of acetyl CoA carboxylase; Mitochondrial complex IV electron transport inhibitors; Mitochondrial complex II electron transport inhibitors; Ryanodine receptor modulators; or Group UN.
6 . A composition according to claim 3 , further comprises an active ingredient selected from group consisting of emamectin, eprinomectin, moxidectin and milbemycin oxime.
7 . A composition according to claim 5 , wherein the weight ratio of the molecule to the active ingredient is 100:1 to 1:100, 50:1 to 1:50, 20:1 to 1:20, 10:1 to 1:10, 5:1 to 1:5, 3:1 to 1:3, 2:1 to 1:2, or 1:1; and/or wherein the weight ratio of the molecule to the active ingredient is X:Y; wherein X is the parts by weight of the molecule and Y is the parts by weight of the active ingredient; further wherein the numerical range of the parts by weight for X is 0<X≤100 and the parts by weight for Y is 0<Y≤100; and further wherein X and Y are selected from Table C, optionally wherein a range of weight ratios of the molecule to the active ingredient is X 1 :Y 1 to X 2 :Y 2 ; further wherein X 1 >Y 1 and X 2 <Y 2 ; or wherein X 1 >Y 1 and X 2 >Y 2 ; or wherein X 1 <Y 1 and X 2 <Y 2 .
TABLE C
active
100
X, Y
X, Y
ingredient (Y)
50
X, Y
X, Y
X, Y
Parts by weight
20
X, Y
X, Y
X, Y
15
X, Y
X, Y
10
X, Y
X, Y
5
X, Y
X, Y
X, Y
3
X, Y
X, Y
X, Y
X, Y
2
X, Y
X, Y
X, Y
1
X, Y
X, Y
X, Y
X, Y
X, Y
1
2
3
5
10
molecule (X) Parts by weight
active
100
X, Y
ingredient (Y)
50
X, Y
X, Y
Parts by weight
20
X, Y
X, Y
15
X, Y
X, Y
X, Y
10
5
X, Y
3
X, Y
X, Y
X, Y
2
X, Y
X, Y
1
X, Y
X, Y
X, Y
X, Y
15
20
50
100
molecule (X) Parts by weight.
8 . A process to control a pest, wherein the process comprises applying to a locus, a pesticidally effective amount of a molecule or a composition according to claim 3 .
9 . A process according to claim 7 , wherein the pest is selected from the group consisting of ants, aphids, bed bugs, beetles, bristletails, caterpillars, cockroaches, crickets, earwigs, fleas, flies, grasshoppers, grubs, leafhoppers, lice, locusts, maggots, mites, nematodes, planthoppers, psyllids, sawflies, scales, silverfish, slugs, snails, spiders, springtails, stink bugs, symphylans, termites, thrips, ticks, wasps, whiteflies, and wireworms.
10 . A process according claim 7 , wherein the pest is a sap-feeding pest or a chewing pest; or wherein the pest is selected from the group consisting of aphids, leafhoppers, moths, scales, thrips, psyllids, mealybugs, stinkbugs, and whiteflies; or from the group consisting of caterpillars, beetles, grasshoppers, and locusts; or wherein the pest is selected from the group consisting of Orders Anoplura and Hemiptera; or from the group consisting of Coleoptera and Lepidoptera; or wherein the pest is selected from the group consisting of Aulacaspis spp., Aphrophora spp., Aphis spp., Bemisia spp., Coccus spp., Euschistus spp., Lygus spp., Macrosiphum spp., Nezara spp., and Rhopalosiphum spp; or from the group consisting of Anthonomus spp., Cerotoma spp., Chaetocnema spp., Colaspis spp., Cyclocephala spp., Diabrotica spp., Hypera spp., Phyllophaga spp., Phyllotreta spp., Sphenophorus spp., and Sitophilus spp.