IP Library Granted Patent US 12,494,697
Granted Patent B2
US 12,494,697 · App. 18/289,474 · Granted Dec 9, 2025

Heat-transfer-liquid-operated turbine and compressor

Inventors: Carmel Rotschild (Haifa, IL); Joseph Cassell (Haifa, IL)
Assignee: TECHNION RESEARCH & DEVELOPMENT FOUNDATION LIMITED
H02K7/1823B01D53/1475B01D53/92F02C6/18B01D2251/304B01D2251/306B01D2251/402B01D2251/404B01D2251/602B01D2251/606B01D2257/504B01D2258/01
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Quick Facts
Patent No.
US 12,494,697
App. No.
18/289,474
Granted
Dec 9, 2025
Kind
B2
Abstract

An energy storage and retrieval system including an air chamber, a first air compressor operating with Heat Transfer Liquid (HTL-compressor) connected to the air chamber, a second turbine, operating with Heat Transfer Liquid (HTL-turbine) connected to the air chamber, accepting compressed air from the air chamber and producing work. Related apparatus and methods are also described.

Claims (39)

1 . A method for converting waste heat of exhaust gas to work

while reducing CO 2 emission in the waste heat, comprising:

feeding into a direct contact heat exchanger an exhaust gas that comprises CO 2 and a heat transfer liquid (HTL) that comprises molten salt, thereby resulting in mixing the HTL with the exhaust gas and heating of the HTL to obtain heated HTL;

wherein the HTL comprises a CO 2 -capturing material to absorb the CO 2 from the exhaust gas, and said mixing resulting in the CO 2 -capturing material capturing the CO 2 from the exhaust gas, thereby reducing an amount of CO 2 in the exhaust gas;

operating an HTL-turbine for performing an isothermal or quasi-isothermal expansion with the heated HTL following said mixing; and

producing work using the HTL-turbine.

2 . The method of claim 1 ,

wherein the HTL exits the heat exchanger at a temperature of about the entrance temperature of the exhaust gas, while the exhaust gas exits the heat exchanger at a temperature about the entering temperature of the HTL.

3 . The method of claim 1 ,

wherein said CO 2 capturing material solidifies upon absorbing CO 2 , and the method further comprising removing the CO 2 capturing material which has absorbed CO 2 from the exhaust gas before reaching the HTL-turbine.

4 . The method according to claim 1 wherein the CO 2 -capturing material comprises a material selected from a group consisting of:

CaO;

MgO;

NaCO 3 (+H 2 O);

NaCO 3 ;

KCO 3 (+H 2 O);

KCO 3 ; and

Na 2 O.

5 . The method according to claim 1 , wherein producing work comprises producing electricity.

6 . The method according to claim 1 , wherein CO 2 capturing material which has absorbed CO 2 from the exhaust gas is removed before reaching the HTL-turbine.

7 . The method according to claim 1 , wherein the molten salt is in a molten state in a temperature range of between 140° C.-530° C.

8 . The method according to claim 1 , wherein said heating comprises heating the HTL that comprises molten salt to a temperature above 670K, using a direct heat exchanger and waste heat of exhaust gas.

9 . The method according to claim 1 , wherein interaction of the CO 2 capturing material with the CO 2 produces a new material which is removable from the HTL;

wherein the method further comprising removing the new material from the HTL.

10 . A method for converting waste heat of exhaust gas to work while

reducing CO 2 emission in the waste heat, comprising:

feeding into a direct contact heat exchanger an exhaust gas that comprises CO 2 and a heat transfer liquid (HTL) that comprises molten salt thereby resulting in mixing the HTL with the exhaust gas and heating of the HTL to obtain heated HTL;

wherein the HTL comprises a CO 2 capturing material, to absorb CO 2 from the exhaust gas, and said mixing resulting in the CO 2 -capturing material capturing the CO 2 from the exhaust gas, thereby reducing an amount of CO 2 in the exhaust gas;

operating an HTL-turbine for performing an isothermal or quasi-isothermal expansion with the heated HTL following said mixing; and

producing work using the HTL-turbine;

wherein interaction of the CO 2 capturing material with the CO 2 produces a new material which is removable from the HTL;

wherein the method further comprises removing the new material from the HTL.

11 . A method for converting waste heat of exhaust gas to work while reducing CO 2

emission in the waste heat, comprising:

feeding into a direct contact heat exchanger an exhaust gas that comprises CO 2 and a heat transfer liquid (HTL) that comprises molten salt, thereby resulting in mixing the HTL with the exhaust gas and heating of the HTL to obtain heated HTL;

wherein the HTL comprises a CO 2 capturing material to absorb CO 2 from the exhaust gas, and said mixing resulting in the CO 2 -capturing material capturing the CO 2 from the exhaust gas, thereby reducing an amount of CO 2 in the exhaust gas;

operating an HTL-turbine for performing an isothermal or quasi-isothermal expansion with the heated HTL following said mixing; and

producing work using the HTL-turbine;

wherein said CO 2 capturing material solidifies upon absorbing CO 2 , and the method further comprising removing the CO 2 capturing material which has absorbed CO 2 from the exhaust gas before reaching the HTL-turbine.

Assignments (1)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Nov 6, 2023
From: ROTSCHILD, CARMEL; CASSELL, JOSEPH
To: TECHNION RESEARCH & DEVELOPMENT FOUNDATION LIMITED
Reel/Frame 065474/0042 →
Continuity (4)
Continuation In Part PCTIL2021051061 · Aug 30, 2021
Provisional Application 63289197 · Dec 14, 2021
Provisional Application 63184928 · May 6, 2021
Related Publication 20240243639A1 · Jul 18, 2024
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