Granted Patent B1

US 12,508,569 · App. 19/211,915 · Granted Dec 30, 2025

Inventors: Ehab Abdelhamed Abdelrahman Ahmed (Riyadh, SA); Babiker Yagoub Elhadi Abdulkhair (Riyadh, SA)

Assignee: IMAM MOHAMMAD IBN SAUD ISLAMIC UNIVERSITY

B01J20/024B01J20/0274B01J20/041B01J20/20B01J20/28011B01J20/28016B01J20/3078

Abstract

Claims (26)

1 . A ZnFe(BO 3 )O/Fe 2 CaO 4 /C nanocomposite material, comprising:

an orthorhombic ZnFe(BO 3 )O phase; and

an orthorhombic Fe 2 CaO 4 phase,

wherein the ZnFe(BO 3 )O/Fe 2 CaO 4 /C nanocomposite material comprises irregularly shaped granular and flake-like particles.

2 . The ZnFe(BO 3 )O/Fe 2 CaO 4 /C nanocomposite material of claim 1 , wherein the ZnFe(BO 3 )O/Fe 2 CaO 4 /C nanocomposite material has an oxygen content in a range from 40 to 80 atomic % (at. %), a calcium content in a range from 1 to 20 at. %, an iron content in a range from 5 to 25 at. %, a boron content in a range from 1 to 20 at. %, a zinc content in a range from 0.5 to 15 at. %, and a carbon content in a range from 0.5 to 25 at. % based on the total number of atoms in the ZnFe(BO 3 )O/Fe 2 CaO 4 /C nanocomposite material.

3 . The ZnFe(BO 3 )O/Fe 2 CaO 4 /C nanocomposite material of claim 2 , wherein the ZnFe(BO 3 )O/Fe 2 CaO 4 /C nanocomposite material has an oxygen content in a range from 50 to 70 atomic % (at. %), a calcium content in a range from 1 to 15 at. %, an iron content in a range from 8 to 20 at. %, a boron content in a range from 1 to 15 at. %, a zinc content in a range from 0.5 to 10 at. %, and a carbon content in a range from 0.5 to 20 at. % based on the total number of atoms in the ZnFe(BO 3 )O/Fe 2 CaO 4 /C nanocomposite material.

4 . The ZnFe(BO 3 )O/Fe 2 CaO 4 /C nanocomposite material of claim 3 , wherein the ZnFe(BO 3 )O/Fe 2 CaO 4 /C nanocomposite material has an oxygen content in a range from 55 to 65 atomic % (at. %), a calcium content in a range from 5 to 10 at. %, an iron content in a range from 10 to 18 at. %, a boron content in a range from 3 to 12 at. %, a zinc content in a range from 1 to 8 at. %, and a carbon content in a range from 1 to 15 at. % based on the total number of atoms in the ZnFe(BO 3 )O/Fe 2 CaO 4 /C nanocomposite material.

5 . The ZnFe(BO 3 )O/Fe 2 CaO 4 /C nanocomposite material of claim 4 , wherein the ZnFe(BO 3 )O/Fe 2 CaO 4 /C nanocomposite material has an oxygen content in a range from 57 to 63 atomic % (at. %), a calcium content in a range from 6 to 9 at. %, an iron content in a range from 12 to 16 at. %, a boron content in a range from 5 to 9 at. %, a zinc content in a range from 3 to 7 at. %, and a carbon content in a range from 2 to 10 at. %.

6 . The ZnFe(BO 3 )O/Fe 2 CaO 4 /C nanocomposite material of claim 1 , wherein the ZnFe(BO 3 )O/Fe 2 CaO 4 /C nanocomposite material has an average crystallite size in a range from 40 to 95 nm.

7 . The ZnFe(BO 3 )O/Fe 2 CaO 4 /C nanocomposite material of claim 6 , wherein the ZnFe(BO 3 )O/Fe 2 CaO 4 /C nanocomposite material has an average crystallite size in a range from 50 to 85 nm.

8 . The ZnFe(BO 3 )O/Fe 2 CaO 4 /C nanocomposite material of claim 1 , wherein the ZnFe(BO 3 )O/Fe 2 CaO 4 /C nanocomposite material has an average crystallite size in a range from 55 to 75 nm.

9 . The ZnFe(BO 3 )O/Fe 2 CaO 4 /C nanocomposite material of claim 1 , wherein the ZnFe(BO 3 )O/Fe 2 CaO 4 /C nanocomposite material has an average crystallite size in a range from 65 to 70 nm.

10 . A method for making the ZnFe(BO 3 )O/Fe 2 CaO 4 /C nanocomposite material of claim 1 , comprising:

adding an ammonium tartrate solution to a solution comprising Fe(NO 3 ) 3 · 9 H 2 O, Zn(NO 3 ) 2 · 6 H 2 O, Ca(NO 3 ) 2 · 4 H 2 O and boric acid under stirring to form a reaction mixture;

adding triethylene glycol to the reaction mixture to form a stabilized mixture and stirring at 250° C. until a solid is formed; and

calcining the solid at a temperature in a range from 600 to 800° C. for 1 to 5 hours to form the ZnFe(BO 3 )O/Fe 2 CaO 4 /C nanocomposite material.

11 . The method of claim 10 , wherein the concentration of ammonium tartrate in the reaction mixture is in a range from 40 to 70 g/L.

12 . The method of claim 10 , wherein the concentration of Fe(NO 3 ) 3 · 9 H 2 O in the reaction mixture is in a range from 20 to 40 g/L.

13 . The method of claim 10 , wherein the concentration of Zn(NO 3 ) 2 · 6 H 2 O in the reaction mixture is in a range from 5 to 15 g/L.

14 . The method of claim 10 , wherein the concentration of Ca(NO 3 ) 2 · 4 H 2 O in the reaction mixture is in a range from 5 to 15 g/L.

15 . The method of claim 10 , wherein the concentration of boric acid in the reaction mixture is in a range from 15 to 25 g/L.

16 . The method of claim 10 , wherein the concentration of triethylene glycol in the stabilized mixture is in a range from 30 to 40 ml per liter of stabilized mixture.

17 . The method of claim 10 , wherein the solid is calcined at a temperature in a range from 650 to 750° C.

18 . The method of claim 17 , wherein the solid is calcined at a temperature of 700° C.

19 . The method of claim 10 , wherein the solid is calcined for 2 to 4 hours.

20 . The method of claim 19 , wherein the solid is calcined for 3 hours.

Assignments (1)

References Cited (11)