Aerogel composite
An aerogel composite may include a substrate and an aerogel, where a ratio of a carbon content in a surface of the aerogel composite to a total carbon content of the aerogel composite is from 2 to 3. The aerogel composite, when used in a high-temperature environment, may generate a low amount of a volatile organic compound (VOC), so that the generation of a bad odor is suppressed, and the hydrophobicity is high.
1 . An aerogel composite comprising:
a substrate; and
an aerogel including a plurality of open pores;
wherein the aerogel composite includes carbon (C), silicon (Si), and oxygen (O), and wherein a ratio of a carbon content in a surface of the aerogel composite to a total carbon content of the aerogel composite is from 2 to 3 based on a total sum of carbon, silicon, and oxygen in the aerogel composite being 100 wt %.
2 . The aerogel composite of claim 1 , wherein the ratio of the carbon content in the surface of the aerogel composite to the total carbon content of the aerogel composite is from 2 to 2.85.
3 . The aerogel composite of claim 1 , wherein the surface of the aerogel composite comprises silicon in an amount from 20 wt % to 50 wt %, the surface of the aerogel composite comprises oxygen in an amount from 30 wt % to 60 wt %, and the surface of the aerogel composite comprises carbon in an amount from 5 wt % to 30 wt %, based on a total sum of carbon, silicon, and oxygen in the surface of the aerogel composite being 100 wt %.
4 . The aerogel composite of claim 1 , wherein the aerogel composite comprises silicon in an amount from 20 wt % to 50 wt %, the aerogel composite comprises oxygen in an amount from 40 wt % to 75 wt %, and the aerogel composite comprises carbon in an amount from 1 wt % to 20 wt %, based on the total sum of the carbon, silicon, and oxygen in the aerogel composite being 100 wt %.
5 . The aerogel composite of claim 4 , wherein a ratio of the total carbon content of the aerogel composite to a total silicon content of the aerogel composite is from 0.05 to 0.30.
6 . The aerogel composite of claim 1 , wherein a ratio of a silicon content in the surface of the aerogel composite to a total silicon content of the aerogel composite is from 0.9 to 2.0.
7 . The aerogel composite of claim 1 , wherein a ratio of an oxygen content in the surface of the aerogel composite to a total oxygen content of the aerogel composite is from 0.5 to 1.0.
8 . The aerogel composite of claim 1 , wherein when the aerogel composite is heated at a temperature of 150° C. for 15 minutes, an amount of trimethylethoxysilane (TMES), trimethylsilanol (TMS), or hexamethyldisiloxane (HMDSO) generated per unit weight of the aerogel composite is 10 μg/g or less.
9 . The aerogel composite of claim 1 , wherein the aerogel composite has a moisture impregnation rate (wt %) of 15 wt % or less, wherein the moisture impregnation rate is represented by Equation 1:
Moisture impregnation rate (wt %)={(Weight of sample after impregnation−Weight of sample before impregnation)/(Weight of sample before impregnation)}×100 [Equation 1]
wherein in Equation 1, the weight of the sample after impregnation is a weight measured after impregnating the sample in distilled water at 21±2° C. for 15 minutes.
10 . The aerogel composite of claim 1 , wherein the aerogel composite has a thickness from 0.5 mm to 20 mm.
11 . The aerogel composite of claim 1 , wherein the aerogel composite has a density from 0.05 g/cm 3 to 0.50 g/cm 3 .
12 . The aerogel composite of claim 1 , wherein the aerogel comprises silica, methylsilylated silica, dimethylsilylated silica, trimethylsilylated silica, or a mixture thereof.
13 . The aerogel composite of claim 1 , wherein the aerogel comprises a plurality of primary aerogel particles having a particle diameter of greater than 0 nm to 5 nm, wherein the plurality of primary aerogel particles are aggregated or bonded in a plurality of secondary aerogel particles.
14 . The aerogel composite of claim 1 , wherein the aerogel composite has a compressive strength from 20 kPa to 80 kPa at 10% strain, and wherein the aerogel composite has a tensile strength from 30 N/cm 2 to 60 N/cm 2 .
15 . A heat insulation member comprising the aerogel composite of claim 1 .
16 . The heat insulation member of claim 15 , wherein the heat insulation member further comprises a support member on an upper surface of the aerogel composite or a lower surface of the aerogel composite or both.