IP Library › Granted Patent US 12,707,731
Granted Patent B2
US 12,707,731 · App. 17/930,760 · Granted Aug 11, 2026

Light-driven ultrafast electric gating

Inventors: Samuel Ciocys (Berkeley, CA); Alessandra Lanzara (Piedmont, CA)
Assignee: THE REGENTS OF THE UNIVERSITY OF CALIFORNIA
H10F30/28H03K17/56H10F30/2823H10F77/143H10F10/16H10F77/12H10F77/122
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Quick Facts
Patent No.
US 12,707,731
App. No.
17/930,760
Filed
Sep 9, 2022
Granted
Aug 11, 2026
Kind
B2
Art Unit
2893
USPC
257/24
Abstract

A source and drain electrode are spaced apart by an optically exposed gate region above a surface photovoltage effect (SPV) bulk. A two-dimensional material is deposited upon the gate region. The gate region is activated by exposure to an ultrafast light pulse, which may be infrared or near-infrared, and may be a focused collimated laser pulse with a sub-picosecond width. The pulse causes electron-hole pair generation resulting in band bending in the SPV material, which generates an electric field within the 2D material, thereby modifying the electronic properties between source and drain via a field-effect. After passage of the pulse, conduction continues in the device until the conductive electron-hole pairs recombine during the SPV decay time. The two-dimensional material may comprise a crystalline atomic monolayer. The activation is repeatable with subsequent pulses, resulting in the device cycling on and off within timescales less than 200 picoseconds.

Claims (28)

1 . A device comprising:

a semiconductor, the semiconductor capable of exhibiting a surface photovoltage effect;

an insulating buffer layer disposed on the surface of the semiconductor;

a two-dimensional material disposed on the surface of the insulating buffer layer;

a drain electrode disposed on the two-dimensional material and a source electrode disposed on the two-dimensional material; and

an area between the drain electrode and the source electrode configured to be illuminated by sub-picosecond infrared pulses from an infrared light source,

wherein a current flowing from the source electrode to the drain electrode is modified by a gate dependent property of the two-dimensional material when the area is illuminated by the sub-picosecond infrared pulse and subsequent surface photovoltage decay time afterward.

2 . The device of claim 1 , wherein the two-dimensional material comprises a crystalline solid selected from a group consisting of: a single layer of atoms, a single molecular layer, one or more layers of atoms ranging from approximately 1 Å to approximately 10 nm thickness, one or more single molecular layers totaling approximately 1 Å to approximately 10 nm thickness, one or more molecular layers totaling approximately 1 Å to approximately 10 nm thickness, and a thin multilayered material of approximately 1 to approximately 5 monolayers thickness.

3 . The device of claim 1 , wherein the gate dependent property is selected from a group of properties consisting of magnitude and spin polarization.

4 . The device of claim 1 , wherein the modification by the gate dependent property of the two-dimensional material is reversibly restored after the area is illuminated by the sub-picosecond infrared pulse and the surface photovoltage has substantially decayed.

5 . The device of claim 1 , wherein switching of the modification of the gate dependent property and back occurs at timescales of less than about 200 picoseconds.

6 . The device of claim 1 , wherein the semiconductor is a semiconductor selected from a group consisting of: bismuth selenide (Bi 2 Se 3 ), gallium arsenide (GaAs), and silicon.

7 . The device of claim 1 , wherein the two-dimensional material is a two-dimensional material selected from a group consisting of: graphene, and a transition metal dichalcogenide (TMD).

8 . The device of claim 1 , wherein the insulating buffer layer is a material selected from group consisting of: hexagonal boron nitride (hBN), a thin-film high-k dielectric, and a thin film strontium titanate (SrTiO 3 ) dielectric.

9 . The device of claim 1 , further comprising an infrared light source capable of producing sub-picosecond coherent infrared pulses.

10 . The device of claim 9 , wherein the infrared light source is an infrared laser.

11 . The device of claim 10 , wherein the infrared laser is a focused sub-picosecond near-infrared pulsed laser having a full width at half maximum (FWHM) pulse of less than one picosecond.

12 . An apparatus comprising:

a focused sub-picosecond near-infrared pulsed laser having a full width at half maximum (FWHM) pulse of less than one picosecond capable of producing sub-picosecond infrared pulses;

a bulk semiconductor, the semiconductor exhibiting a surface photovoltage effect, a two-dimensional electronic system being formed at a surface of the bulk material;

a drain electrode disposed on the surface of the semiconductor and a source electrode disposed on the surface of the semiconductor; and

an area between the drain electrode and the source electrode configured to be illuminated by sub-picosecond infrared pulses from the infrared laser, producing picosecond time-varying electric fields at the bulk material's surface, thereby reversibly modulating a quantum well spectrum and a Rashba effect.

13 . The apparatus of claim 12 , where the two-dimensional electronic system formed at the surface of the bulk material is that of a two-dimensional electron gas.

14 . The apparatus of claim 12 , wherein when the device is in operation, current flowing from the source electrode to the drain electrode is modified by a gate dependent property of the two-dimensional electronic system when the area is illuminated by a sub-picosecond infrared pulse and subsequent surface photovoltage decay time afterward.

15 . The apparatus of claim 14 , wherein the gate dependent property of the two-dimensional electronic system is selected from a group consisting of magnitude and spin-polarization.

16 . The apparatus of claim 15 , wherein the semiconductor is a semiconductor from the group of bismuth selenide (Bi 2 Se 3 ), gallium arsenide (GaAs), and silicon.

17 . The apparatus of claim 14 , wherein when the device is in operation, the modification by the gate dependent property of the two-dimensional electronic system is reversibly restored after the area is illuminated by the sub-picosecond infrared pulse and the surface photovoltage has decayed.

18 . The apparatus of claim 14 , wherein switching of the modification of the gate-dependent property and back occurs at timescales of less than about 200 picoseconds.

Assignments (2)
CONFIRMATORY LICENSE Recorded Feb 4, 2025
From: REGENTS OF THE UNIVERSITY OF CALIFORNIA
To: U.S. DEPARTMENT OF ENERGY
Reel/Frame 070107/0424 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Sep 29, 2022
From: CIOCYS, SAMUEL; LANZARA, ALESSANDRA
To: THE REGENTS OF THE UNIVERSITY OF CALIFORNIA
Reel/Frame 061261/0075 →
Continuity (2)
Provisional Application 63242392 · Sep 9, 2021
Related Publication 20230110264A1 · Apr 13, 2023
References Cited (22)
US 20050056867A1 · Nauka · 2005 [cited by examiner]
US 20090290150A1 · Takimoto · 2009 [cited by examiner]
US 20150243826A1 · An · 2015 [cited by examiner]
US 20200194602A1 · Choi · 2020 [cited by examiner]
US 20220102570A1 · Bessonov · 2022 [cited by examiner]
Ciocys, Samuel T. et al., “Driving ultrafast spin and energy modulation in quantum well states via photo-induced electric fields,” NPJ Quantum Materials, 79, 2022, pp. 1-10. [cited by applicant]
King, Philip D. C. et al., “Large tunable Rashba spin splitting of a two-dimensional electron gas in Bi2Se3”, Phys. Rev. Lett. 107, Aug. 26, 2011, pp. 1-5. [cited by applicant]
Benia, Hadji et al., “Reactive chemical doping of the Bi2Se3 topological insulator” Phys. Rev. Lett. 107, May 13, 2011, pp. 1-4. [cited by applicant]
Bianchi, Marco et al., “Simultaneous quantization of bulk conduction and valence states through adsorption of nonmagnetic impurities on Bi2Se3”, Phys. Rev. Lett. 107, May 19, 2011, pp. 1-5. [cited by applicant]
Datta, Supriyo et al., “Electronic analog of the electro-optic modulator”, Appl. Phys. Lett. 56, Issue 7, Feb. 1990, pp. 665-667. [cited by applicant]
Wang, Te-Hsien et al., “Wide-range ideal 2D Rashba electron gas with large spin splitting in Bi2Se3/MoTe2 heterostructure”, npj Comput. Mater 3, 2017, pp. 1-6. [cited by applicant]
Chen, Chaoyu et al. “Robustness of topological order and formation of quantum well states in topological insulators exposed to ambient environment” Proc. Natl. Acad. Sci. 109, Chen, C. et al. Robustness of topological o… [cited by applicant]
Papalazarou, E. et al. “Unraveling the Dirac fermion dynamics of the bulk-insulating topological system Bi2Te2Se”, Phys. Rev. Mater. 2, 2018, pp. 1-13. [cited by applicant]
Yoshikawa, T. et al. “Bidirectional surface photovoltage on a topological insulator”, Phys. Rev. B 100, 165311, 2019, pp. 1-6. [cited by applicant]
Ishida, Y. et al., “Emergent photovoltage on SmB6 surface upon bulk-gap evolution revealed by pump-and-probe photoemission spectroscopy” Sci. Rep. 5, 8160, Jul. 23, 2015, pp. 1-6. [cited by applicant]
Ciocys, Samuel et al., “Manipulating long-lived topological surface photovoltage in bulkinsulating topological insulators Bi2Se3 and Bi2Te3”. npj Quantum Mater. 5, 2020, pp. 1-7. [cited by applicant]
Neupane, Madhab et al., “Gigantic surface lifetime of an intrinsic topological insulator”, Phys. Rev. Lett. 115, 116801, 2015, pp. 1-5. [cited by applicant]
Zhu, Z.-H. et al., “Rashba spin-splitting control at the surface of the topological insulator Bi2Se3”, Phys. Rev. Lett. 107, Jun. 3, 2011, pp. 1-5. [cited by applicant]
Bianchi, Marco et al. “Robust surface doping of Bi2Se3 by Rubidium intercalation” ACS Nano 6, Jul. 27, 2012, pp. 7009-7015. [cited by applicant]
Wray, L. A. et al. “A topological insulator surface under strong Coulomb, magnetic and disorder perturbations”, Nat. Phys. 7, Jan. 2011, pp. 32-27. [cited by applicant]
Valla, T. et al., “Photoemission spectroscopy of magnetic and nonmagnetic impurities on the surface of the Bi2Se3 topological insulator”, Phys. Rev. Lett. 108, 2012 pp. 1-6. [cited by applicant]
Zhang, Z. et al., “Band bending in semiconductors: chemical and physical consequences at surfaces and interfaces”, Chem. Rev. 112, 5520-5551 (2012). [cited by applicant]