IP Library › Granted Patent US 12,709,782
Granted Patent B2
US 12,709,782 · App. 18/037,344 · Granted Aug 18, 2026

Ferritic stainless steel sheet and production method

Inventors: Ryo Kobayashi (Tokyo, JP); Masaharu Hatano (Tokyo, JP)
Assignee: NIPPON STEEL STAINLESS STEEL CORPORATION
C21D9/46C21D8/1233C21D8/1272C22C38/001C22C38/002C22C38/02C22C38/04C22C38/06C22C38/22C21D2201/05C21D2211/005C22C2202/02
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Quick Facts
Patent No.
US 12,709,782
App. No.
18/037,344
Filed
May 17, 2023
Granted
Aug 18, 2026
Kind
B2
Art Unit
1733
USPC
148/610
Abstract

There is provided a ferritic stainless steel sheet including a magnetized area fraction of 50% or more wherein the ferritic stainless steel sheet chemical composition includes, in mass %: C: 0.015% or less, Si: 3.0% or less, Mn: 1.0% or less, S: 0.0040% or less, P: 0.08% or less, Al: 0.80% or less, N: 0.030% or less, Cr: 15.0 to 25.0%, Mo: 0.5 to 3.0%, Ti: 0 to 0.50%, Nb: 0 to 0.50%, Ni: 0 to 0.50%, Cu: 0% or more to less than 0.1%, Zr: 0 to 1.0%, V: 0 to 1.0%, REM: 0 to 0.05%, and B: 0 to 0.01%, with the balance: Fe and impurities, and satisfies Formula (i): 0.10≤Ti+Nb≤0.50.

Claims (64)

1 . A ferritic stainless steel sheet, wherein

a chemical composition consists of, in mass %:

C: 0.015% or less,

Si: 3.0% or less,

Mn: 1.0% or less,

S: 0.0040% or less,

P: 0.08% or less,

Al: 0.80% or less,

N: 0.030% or less,

Cr: 15.0 to 25.0%,

Mo: 0.5 to 3.0%,

Ti: 0 to 0.50%,

Nb: 0 to 0.50%,

Ni: 0 to 0.50%,

Cu: 0% or more to less than 0.1%,

Zr: 0 to 1.0%,

V: 0 to 1.0%,

REM: 0 to 0.05%, and

B: 0 to 0.01%,

with the balance: Fe and impurities, and

satisfies Formula (i) shown below:

0.10≤Ti+Nb≤0.50  (i)

where symbols of elements in the formula indicate contents (mass %) of the elements contained in the steel, and when an element is not contained, zero will be set to the corresponding symbol;

a maximum grain size of grains is 343 μm or more; and

the ferritic stainless steel sheet comprises a magnetized area fraction of 70% or more, wherein the magnetized area fraction is an area fraction of a magnetized region, the magnetized region being determined by the following steps using a magnetic domain observation microscope:

(a) an amount of change in reflection light intensity is measured in a state where no magnetic field is applied to a sample, and a threshold is specified for an amount of change in reflection light intensity with which 99% of an observation region is determined to be unmagnetized;

(b) with a magnetic field of 1000 Oe applied to the sample, a region having an amount of change in reflection light intensity exceeding the specified threshold of step (a) is extracted as a magnetized region; and

(c) the observation is performed in three visual fields with a magnification within a range of x1000 to x2500, and

in a rolling direction crystal orientation,

F1 that is given by Formula (iii) shown below and is a ratio between a total area S <00> of grains having orientations parallel to a <001> direction and a total area S 111> of grains having orientations parallel to a <111> direction is 5.0 or more:

F1=S <001> /S <111>   (iii)

2 . The ferritic stainless steel sheet according to claim 1 , wherein the chemical composition contains, in mass %,

Si: 0.60% or less.

3 . The ferritic stainless steel sheet according to claim 1 , wherein the chemical composition contains one or more elements selected from, in mass %:

Ni: 0.05 to 0.50%,

Cu: 0.01% or more to less than 0.1%,

Zr: 0.01 to 1.0%,

V: 0.01 to 1.0%,

REM: 0.005 to 0.05%, and

B: 0.0002 to 0.01%.

4 . The ferritic stainless steel sheet according to claim 1 , wherein

a pitting resistance equivalent number PREN that is calculated by Formula (ii) shown below is 20.0 or more:

PREN=Cr+3.3Mo+16N  (ii)

where symbols of elements in Formula (ii) shown above indicate contents (mass %) of the elements contained in the steel, and when an element is not contained, zero will be set to the corresponding symbol.

5 . The ferritic stainless steel sheet according to claim 1 , wherein a maximum grain size of grains observed is 500 μm or more.

6 . The ferritic stainless steel sheet according to claim 2 , wherein the chemical composition contains one or more elements selected from, in mass %:

Ni: 0.05 to 0.50%,

Cu: 0.01% or more to less than 0.1%,

Zr: 0.01 to 1.0%,

V: 0.01 to 1.0%,

REM: 0.005 to 0.05%, and

B: 0.0002 to 0.01%.

7 . The ferritic stainless steel sheet according to claim 2 , wherein

a pitting resistance equivalent number PREN that is calculated by Formula (ii) shown below is 20.0 or more:

PREN=Cr+3.3Mo+16N  (ii)

where symbols of elements in Formula (ii) shown above indicate contents (mass %) of the elements contained in the steel, and when an element is not contained, zero will be set to the corresponding symbol.

8 . The ferritic stainless steel sheet according to claim 3 , wherein

a pitting resistance equivalent number PREN that is calculated by Formula (ii) shown below is 20.0 or more:

PREN=Cr+3.3Mo+16N  (ii)

where symbols of elements in Formula (ii) shown above indicate contents (mass %) of the elements contained in the steel, and when an element is not contained, zero will be set to the corresponding symbol.

9 . The ferritic stainless steel sheet according to claim 6 , wherein

a pitting resistance equivalent number PREN that is calculated by Formula (ii) shown below is 20.0 or more:

PREN=Cr+3.3Mo+16N  (ii)

where symbols of elements in Formula (ii) shown above indicate contents (mass %) of the elements contained in the steel, and when an element is not contained, zero will be set to the corresponding symbol.

Assignments (1)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded May 17, 2023
From: KOBAYASHI, RYO; HATANO, MASAHARU
To: NIPPON STEEL STAINLESS STEEL CORPORATION
Reel/Frame 063665/0821 →
Priority Claims (1)
JP 2020-203100 · Dec 8, 2020 · national
Continuity (1)
Related Publication 20230407431A1 · Dec 21, 2023
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