Lubricant compositions
A lubricant composition containing an anti-deposition component having an anti-deposition effect which is especially useful for the lubrication of refrigeration compressors and in reducing or removal of unwanted deposits in constricted areas in a refrigeration system.
1. A refrigeration lubricant composition suitable for use in a refrigeration system with a refrigerant containing a hydrofluorocarbon and/or a hydrochlorofluorocarbon, consisting essentially of a synthetic lubricant consisting essentially of a polyol ester and/or a polyalkylene glycol and an amphiphilic anti-deposition component which is anionic and contains a non-polar part to the molecule which contains a fluorocarbon group.
2. A composition according to claim 1 in which the amphiphilic anti-deposition component is such that in the Dispersibility Test described herein, the phases of R134a and the total oil mixture separate after at least 10 seconds.
3. A composition according to claim 1 or claim 4 in which the anti-deposition component is present at a level of 0.001 to 5% based on the weight of the lubricant.
4. A composition according to claim 1 in which the polyol ester and/or polyalkylene glycol is a compound of the general formula (II):
R(OC(O)R 1 ) n (II)
wherein R is a hydrocarbon radical remaining after removing the hydroxyl groups from pentaerythritol, dipentaerythritol, tripentaerythritol, trimethylol ethane, trimethylol propane or neopentyl glycol, or the hydroxyl containing hydrocarbon radical remaining after removing a proportion of the hydroxyl groups from pentaerythritol, dipentaerythritol, tripentaerythritol, trimethylol ethane, trimethylol propane or neopentyl glycol; each R 1 is, independently, H, a straight chain aliphatic hydrocarbyl group, a branched chain aliphatic hydrocarbyl group, an aliphatic hydrocarbyl group containing a carboxylic acid or carboxylic acid ester substituent, provided that at least one group is a linear aliphatic hydrocarbyl group or branched aliphatic hydrocarbyl group; and n is an integer.
5. A composition according to claim 4 in which the ester comprises an ester of pentaerythritol, dipentaerythritol and/or tri pentaerythritol and each R 1 is selected from a straight chain aliphatic hydrocarbyl group and a branched chain aliphatic hydrocarbyl group.
6. A refrigerant composition comprising the refrigeration lubricant composition according to claim 1 , and a refrigerant, in which the refrigerant comprises 1,1,1,2-tetrafluoroethane.
7. A refrigerant composition comprising the refrigeration lubricant composition according to claim 1 , and a refrigerant, in which the refrigerant comprises a blend of 2 or more hydrofluorocarbon refrigerants.
8. A refrigeration system comprising a compressor, a condenser, an expansion device and an evaporator linked to form a loop in which a refrigerant circulates and is successively condensed and evaporated so as to provide a refrigeration effect the refrigerant comprising a hydrofluorocarbon and/or a hydrochlorofluorocarbon refrigerant, and the system further containing a refrigeration lubricant composition as defined in claim 1 .
9. A method of inhibiting the deposition of or removing unwanted residues in a refrigeration system which comprises operating a refrigeration system when charged with a hydrogen-containing refrigerant and a refrigeration lubricant composition as defined in claim 1 .
10. A method according to claim 9 including the steps of operating the refrigeration system containing a refrigerant and a lubricant, adding the anti-deposition component to the system, and operating the system further so as to inhibit deposition or remove deposits of unwanted residues.
11. A refrigeration lubricant composition consisting essentially of a synthetic lubricant consisting of a polyol ester and/or a polyalkylene glycol and an amphiphilic anti-deposition component which is an alkyl alkoxylate derived from an alkylene oxide and a moiety derived from a compound having an active hydrogen atom and an oleophilic moiety, an ester of a polyalkylene glycol or a fluorinated polyether.
12. A refrigeration lubricant composition consisting essentially of a synthetic lubricant consisting of a polyol ester and/or a polyalkylene glycol and an amphiphilic anti-deposition component which is a dialkylsulphonsuccinate, a salt thereof, a fluoroaliphatic polymeric ester, a comb graft copolymer of methyl methacrylate/methacrylic acid/methoxy polyethyleneoxide methacrylate, or a solution of an acrylic graft copolymer.