Composite fiber having favorable post-treatment processibility and method for producing the same
The present invention provides a polytrimethylene terephthalate composite fiber characterized in that the composite fiber is a plurality of single filament which comprises two kinds of polyester components laminated to each other in a side-by-side manner or an eccentric sheath-core manner, at least one polyester component is polytrimethylene terephthalate and the composite fiber satisfies the following conditions: the content of trimethylene terephthalate cyclic dimer in polytrimethylene terephthalate is 2.5 wt % or less, the fiber-fiber dynamic friction coefficient is from 0.2 to 0.4, the degree of intermingling is from 2 to 60 point/m and/or the number of twists is from 2 to 60 T/m and the fiber size fluctuation U % is 1.5% or less.
1. In a method for producing a polytrimethylene terephthalate composite fiber by a melt-spinning method, wherein the composite fiber is a plurality of single filaments which comprise two kinds of polyester components laminated to each other in a side-by-side manner or an eccentric sheath-core manner, at least one of which is polytrimethylene terephthalate, the improvement comprising conducting the melt-spinning method under the following conditions (a) to (d):
(a) the melting temperature is from 240 to 280° C. and the melting time is 20 minutes or less,
(b) after the two kinds of polyester components have been joined together, an extrusion condition per one spinning orifice is such that the product of a average intrinsic viscosity [η] (dl/g) and an extrusion linear speed V (m/min) is from 3 to 15 (dl/g)·(m/min),
(c) after the polyester has been extruded, cooled and solidified, a finishing agent containing 10 to 80 wt % of a fatty ester and/or a mineral oil, or a finishing agent containing 50 to 98 wt % of a polyether is imparted to the fiber at a ratio from 0.3 to 1.5 wt %, and
(d) at any of the steps before the fiber has been finally wound, an interlacing and/or twist is imparted to the fiber.
2. In a method for producing a polytrimethylene terephthalate composite fiber by a melt-spinning method, wherein the composite fiber is a plurality of single filaments which comprise two kinds of polyester components laminated to each other in a side-by-side manner, the improvement comprising conducting the melt-spinning method under the following conditions (a) to (f):
(a) polytrimethylene terephthalate having a content of trimethylene terephthalate cyclic dimmer of 1.1 wt % or less is used as both of the components,
(b) the melting temperature is from 255 to 270° C. and the melting time is 20 minutes or less,
(c) after the two kinds of polyester components have been joined together, an extrusion condition per one spinning orifice is such that a ratio (L/D) of length L to a diameter D of a spinning orifice is 2 or more and the spinning orifice has an inclination, relative to the vertical direction, from 15 to 35 degrees,
(d) after the two kinds of polyester components have been joined together, an extrusion condition per one spinning orifice is such that the product of an average intrinsic viscosity [θ] (dl/g) and an extrusion linear speed V (m/min) is from 5 to 10 (dl/g)·(m/min),
(e) after the polyester has been extruded, cooled and solidified, a finishing agent containing 10 to 80 wt % of a fatty ester and/or a mineral oil, or a finishing agent containing 50 to 98 wt % of a polyether imparted to the fiber at a ratio from 0.3 to 1.5 wt %, and
(f) at any of the steps before the fiber has been finally wound, an interlacing and/or twist is imparted to the fiber.
3. A method for producing a polytrimethylene terephthalate composite fiber as defined by claim 1 , wherein both of the two kinds of polyester components forming the single filament comprise 90 mol % or more of polytrimethylene terephthalate, and the composite fiber has an average intrinsic viscosity from 0.7 to 1 .2 dl/g.
4. A method for producing a polytrimethylene terephthalate composite fiber as defined by claim 2 , wherein both of the two kinds of polyester components forming the single filament comprise 90 mol % or more of polytrimethylene terephthalate, and the composite fiber has an average intrinsic viscosity from 0.7 to 1.2 dl/g.